File name: Pandora183s1_LondonderryNH_20220127_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20251125T173426.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20220127_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20220127 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220127T124038.7Z 8062.528225 193 1 49.93 2 85.07 120.79 65.04 184.80 0.00 1 0.00 1 0 25 7.930e-01 1.118e-01 5.631e-01 8.425e-02 9.697284e-01 4.766708e-02 1.116985e-02 -6.000000e+00 4.516612e-01 223.99 -2.00 3.55 -2.00 321.56 0.00e+00 -2.060639e-02 1.184933e-02 7.648137e-03 -6.000000e+00 2.186819e-02 273.01 -2.00 20.00 -2.00 320.95 0.00e+00 9.945 0.019 302.00 328.00 3 -5.0358e-01 1.4725e-01 1.2639e-01 -6.0000e+00 1.1215e+00 2.4091e+00 1.6878e-01 1.0073e-01 -6.0000e+00 1.2274e+00 -2.3032e+00 9.1157e-02 2.4434e-02 -6.0000e+00 7.2331e-01 7.2050e-01 5.1802e-02 2.3270e-02 -6.0000e+00 3.0442e-01 1.4730e-05 6.0720e-04 2.2056e-03 2.5506e-04 -6.0000e+00 2.1200e-02 -1.8564e-03 -1.1632e-04 12 8 8 10 0 0 14.88 22.91 1.07 -0.00186 0.00271 23 5 1 5 0 2170.610 26.51 19.99 22.91 -11.16 11.5 771.72 34355 151525 41763 132231 -59191 900000 -28202 212896 48990 900000 900000 -23196 900000 47664 169016 900000 103739 900000 136453 10657 -16731 900000 -15177 7325 5844 28372 81118 16956 152573 900000 110028 105209 -29237 59926 77374 91724 -97413 92414 -52213 -13752 -18567 207937 147313 222613 251848 -68523 75219 46255 109206 128847 45591 95374 171433 119109 -14331 900000 -8931 96578 155208 -39140 135687 -11889 70939 29008 342721 50759 29432 -3814 30781 226685 32887 97429 -10618 50594 -18307 25907 26 -54524 36313 -43800 3064 -1312 10837 23037 -3678 58559 -19596 42220 21101 -7344 -17086 -10486 2887 51912 7388 2842 63293 32561 19552 -5095 29703 -7532 2907 13579 -33403 1555 -30125 16835 -7592 9504 20110 -1218 -2094 4331 1471 1155 -9616 -4931 6079 6105 20 13980 9242 -48 -4065 -908 5503 -14687 1748 -1498 8912 -6722 5327 581 1121 -4920 -876 6179 -6149 -952 -2263 3299 9254 6642 12427 6606 10845 -16297 900000 -5338 17461 5254 900000 900000 -5122 900000 5713 13862 900000 8508 900000 11191 1748 -3272 900000 -2585 1109 995 4266 6653 2202 12513 900000 9024 8629 -5795 4915 6346 7523 -31292 7579 -14631 -3102 -4822 17054 12082 18258 20655 -21075 6169 4110 8957 10567 4674 7822 14060 9769 -3526 900000 -2397 8641 12729 -10797 11128 -2393 6876 4758 28108 6812 4828 -910 5738 18592 7356 11623 -3563 8299 -5187 4056 5 -17887 5415 -17308 891 -460 3717 7386 -1618 14408 -10812 12592 7552 -3285 -7771 -4222 1012 11999 3085 1462 20764 16751 12537 -4179 15946 -5166 1604 6682 -28143 974 -27402 10418 -6793 8362 18292 -1498 -2686 5166 1744 1468 -13801 -7078 8226 8412 28 16166 10764 -59 -5134 -1080 6047 -21561 2581 -2679 16227 -15658 11884 1478 3072 -15051 -2623 17432 -19367 -2686 -5958 7603 19582 SS 20220127T125312.1Z 8062.536946 196 1 49.59 2 83.11 123.05 65.32 187.91 0.00 1 0.00 1 0 25 5.134e-01 2.126e-02 3.932e-01 1.310e-02 9.262042e-01 7.532675e-03 9.848971e-03 -6.000000e+00 2.900242e-01 223.99 -2.00 3.55 -2.00 322.41 0.00e+00 5.788350e-03 4.202340e-03 1.582187e-03 -6.000000e+00 1.275711e-02 273.01 -2.00 20.00 -2.00 322.00 0.00e+00 7.644 0.008 302.00 328.00 3 -1.8037e-01 2.8503e-02 9.1094e-02 -6.0000e+00 7.1689e-01 1.1304e+00 4.0426e-02 5.4250e-02 -6.0000e+00 7.8313e-01 -1.4802e+00 3.9572e-02 2.9454e-02 -6.0000e+00 4.6279e-01 5.8192e-01 1.8517e-02 1.1025e-02 -6.0000e+00 1.9523e-01 1.3287e-04 -1.3877e-03 3.6657e-04 1.4789e-04 -6.0000e+00 1.3930e-02 -2.7985e-03 -4.8004e-05 12 8 8 10 0 0 5.69 22.91 0.44 -0.00280 -0.01323 87 18 1 5 0 569.770 26.51 20.00 22.91 -10.45 11.5 777.67 -50558 -87988 -27337 900000 -93678 900000 189570 900000 -170179 -119477 -121636 -181904 -71882 -27815 900000 44676 12126 53586 -27401 21519 -3810 35824 -70829 -39819 3063 14543 -5643 -35991 -28758 -29145 68077 19594 63671 53070 -4083 78530 14807 99770 -2318 82784 82815 47494 280298 -4955 131588 6864 17165 42142 38683 39987 6120 69748 49095 46556 19221 88266 31467 43475 42548 56987 30224 6481 32660 31231 18141 33459 13535 16874 15800 13584 15229 16899 8747 11505 8238 -1772 8301 7228 13774 -2249 2496 3369 -396 -1250 2360 180 1150 7852 587 2667 2506 1080 -839 -2442 -2289 -6815 -408 -2272 -1283 -586 -5689 -546 -1574 -2297 -5810 -5217 -2687 -3115 -922 67 -39 -372 260 -1028 -812 -932 284 -1404 -326 592 1666 3326 1961 2197 1963 502 2031 1407 635 50 355 -735 -112 -237 302 187 412 1914 -464 -130 -872 -1195 -1438 -745 -2160 -376 900000 -1931 900000 2420 900000 -6349 -2698 -2976 -8513 -1376 -444 900000 570 219 684 -816 389 -85 495 -2712 -1143 59 247 -114 -919 -642 -682 869 417 1108 1108 -142 1093 395 1273 -97 1729 1922 1653 3577 -299 1985 358 817 1614 1616 1763 419 2832 2677 2809 1606 3789 2410 2875 2666 2909 1999 587 2615 2935 2126 3378 1665 2095 2182 2207 2686 3039 1665 1962 1290 -269 1165 1061 2180 -511 591 923 -126 -469 904 74 492 3217 257 1100 966 398 -311 -979 -1063 -3975 -266 -1775 -1110 -514 -4938 -399 -1030 -1481 -4145 -3928 -2092 -2652 -868 73 -49 -514 370 -1469 -1117 -1247 380 -2011 -489 903 2446 4534 2591 2818 2450 618 2411 1803 966 89 716 -1640 -266 -607 829 539 1205 5568 -1368 -361 -2249 -2846 -3292 SS 20220127T130454.3Z 8062.545073 199 1 49.68 2 81.34 125.20 65.69 190.79 0.00 1 0.00 1 0 17 6.621e-01 1.302e-02 2.520e-01 4.249e-03 8.070753e-01 2.348907e-03 9.003773e-03 -6.000000e+00 3.698098e-01 223.99 -2.00 3.55 -2.00 322.04 0.00e+00 6.018543e-03 1.260753e-03 3.245953e-03 -6.000000e+00 1.591218e-02 273.01 -2.00 20.00 -2.00 321.61 0.00e+00 6.272 0.005 302.00 328.00 3 -1.7350e-01 8.4638e-03 7.6037e-02 -6.0000e+00 9.1406e-01 3.8603e-01 1.3236e-02 4.6529e-02 -6.0000e+00 9.9762e-01 -5.0362e-01 1.5077e-02 2.9100e-02 -6.0000e+00 5.9276e-01 1.9286e-01 6.9079e-03 1.2509e-02 -6.0000e+00 2.5072e-01 5.9124e-04 -5.2767e-04 1.1868e-04 1.8050e-04 -6.0000e+00 1.7447e-02 -3.6308e-03 -2.3680e-05 12 8 8 10 0 0 -7.24 22.92 0.38 -0.00363 -0.00760 200 42 1 5 0 248.320 26.51 20.01 22.92 -9.39 11.5 785.30 -163613 -215545 -108338 -205146 -127165 -163672 -242465 -105457 -247889 -179521 -232033 -199078 -167920 -164162 129872 -128701 -71503 -112797 -26877 -76803 -96712 -22217 -66995 16806 -102269 -38244 -91047 -64431 -74098 -45211 5537 -23487 13529 -22983 8704 -28796 -3671 -5021 21093 29215 -7646 19751 -3893 17588 9722 27202 24621 11316 21802 500 22362 7834 21350 12793 13789 15775 8007 12415 -504 10471 1900 4729 16194 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