File name: Pandora183s1_LondonderryNH_20220131_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20251125T173715.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20220131_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20220131 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220131T131837.9Z 8066.554606 67 1 48.84 2 78.56 126.98 80.47 137.53 0.00 1 0.00 1 0 17 5.530e-01 2.531e-02 3.582e-01 1.501e-02 6.695289e-01 8.258802e-03 7.649794e-03 -6.000000e+00 3.128381e-01 224.14 -2.00 3.55 -2.00 321.62 0.00e+00 5.749205e-03 3.925621e-03 2.143866e-03 -6.000000e+00 1.456098e-02 273.01 -2.00 20.00 -2.00 321.18 0.00e+00 4.876 0.002 302.00 328.00 3 3.1730e+00 2.7604e-02 5.9721e-02 -6.0000e+00 7.7536e-01 2.9138e-01 3.7774e-02 3.6270e-02 -6.0000e+00 8.4856e-01 -4.6866e-01 3.8578e-02 2.1353e-02 -6.0000e+00 5.0473e-01 1.9577e-01 1.8504e-02 9.1506e-03 -6.0000e+00 2.1575e-01 8.8344e-05 -7.4302e-04 4.4615e-04 1.2633e-04 -6.0000e+00 1.5074e-02 -5.9337e-03 4.9147e-05 12 8 8 10 0 0 -53.38 22.91 0.81 -0.00593 -0.01152 18 4 1 5 0 2712.920 26.51 20.00 22.91 -6.47 12.0 812.60 900000 -160783 900000 -222365 900000 -64020 115543 -107149 -46755 -150369 -185244 900000 -110476 900000 -31429 -40347 900000 -80991 900000 -38303 203228 -55767 12919 900000 -72531 -65737 -67342 87726 -43129 144112 -34969 247963 -13697 53507 62221 -63306 16484 -28363 76620 3972 4441 56039 37468 69864 28040 93150 16669 57381 -5320 18864 43544 16733 56749 8235 44742 15321 7693 36250 4578 24168 -6839 11519 424 28131 8312 19937 23695 4161 2067 254 8754 5021 11193 -5377 5657 -19353 -4926 -1142 -6268 6087 524 7452 -2856 44 -3907 -3265 6577 1785 4392 -3094 1738 -1366 -1548 -4751 742 3752 -2268 -310 -1449 135 -1558 -3511 -429 -524 -1690 -5237 -995 -3398 -169 -1349 -1702 -204 -702 127 -1962 1742 1563 -935 669 -86 1940 807 2288 2746 1618 1830 2329 2547 -1409 2198 -303 1007 -1159 938 -525 -889 916 30 391 -488 730 -2218 -946 900000 -3255 900000 -9003 900000 -936 1689 -1567 -684 -3298 -5868 900000 -2154 900000 -460 -787 900000 -2960 900000 -1027 2971 -1767 205 900000 -3005 -2643 -2790 1283 -1314 2107 -1193 3625 -583 1280 1323 -4460 548 -1696 1935 248 313 2532 2141 2971 1826 3219 1263 2974 -537 1580 3125 1757 4375 1116 4460 2118 1176 4144 694 2923 -1145 1745 82 4674 1812 3816 4252 924 508 73 2583 1615 3362 -1801 1549 -6071 -1231 -275 -1758 1796 193 2942 -1382 22 -2155 -1909 3672 1080 2851 -2094 1047 -791 -858 -2779 459 2622 -1960 -303 -1578 146 -1617 -3336 -358 -435 -1524 -5199 -998 -3741 -197 -1799 -2540 -321 -1115 194 -2892 2367 2134 -1370 1025 -138 3035 1228 3298 3815 2185 2378 2907 3306 -2157 3683 -573 2004 -2477 2083 -1265 -2261 2337 78 1012 -1222 1691 -4957 -2018 SS 20220131T132605.6Z 8066.559787 70 1 50.31 2 77.48 128.43 79.58 138.93 0.00 1 0.00 1 0 17 5.587e-01 1.604e-02 3.542e-01 1.022e-02 6.332968e-01 5.507880e-03 7.620399e-03 -6.000000e+00 3.164911e-01 224.14 -2.00 3.55 -2.00 321.39 0.00e+00 5.372834e-03 2.543424e-03 3.939419e-03 -6.000000e+00 1.399372e-02 273.01 -2.00 20.00 -2.00 320.94 0.00e+00 4.485 0.002 302.00 328.00 3 3.1212e+00 1.8016e-02 5.7125e-02 -6.0000e+00 7.8345e-01 1.5637e-01 2.5339e-02 3.8704e-02 -6.0000e+00 8.5615e-01 -2.3308e-01 2.7224e-02 2.4567e-02 -6.0000e+00 5.0769e-01 8.8562e-02 1.3033e-02 9.8757e-03 -6.0000e+00 2.1486e-01 1.4005e-04 -2.1183e-04 2.9927e-04 1.3923e-04 -6.0000e+00 1.4955e-02 -6.0951e-03 3.1347e-05 12 8 8 10 0 0 14.64 22.91 0.23 -0.00610 -0.00769 23 5 1 5 0 2185.810 26.51 20.00 22.91 -5.08 12.0 824.51 -210118 -198198 900000 900000 -193243 -192309 900000 -114923 -94977 -124539 46195 -200400 -144940 -59544 236125 -80125 -12968 900000 49262 -66644 33631 56640 -32274 32842 10878 -31132 78081 -24328 64621 8622 172619 39073 112020 45291 23282 34553 -27106 70309 -4089 31423 -14228 16556 -5111 14345 40699 21582 40958 13388 20682 28434 22505 14904 13726 869 3972 8659 8660 -419 8277 -7765 -4629 -1236 7103 2390 5548 -3264 4243 -5531 7221 5844 4145 2394 623 8573 1438 1104 149 -4116 6526 -1441 -520 -1153 -796 -1139 -1544 -229 9 176 289 -1615 -2070 990 -1289 -3043 -1233 -1931 -1335 432 640 465 -1141 -2677 -1354 1846 -1011 -2512 -2474 -2331 1405 -289 1054 -92 1045 486 -90 62 -870 407 706 26 706 1582 260 1261 671 -1257 2260 933 29 -1062 1525 -513 -235 272 -747 -642 417 235 427 -244 -624 -698 433 -3865 -3949 900000 900000 -3702 -3672 900000 -1145 -946 -1654 460 -6322 -3249 -741 2352 -1929 -183 900000 491 -2047 391 564 -723 409 181 -827 778 -661 702 172 1720 814 1319 1149 717 908 -1399 1592 -237 1537 -1250 1155 -468 1117 2470 1622 2597 1152 1723 2318 2140 1714 1753 137 644 1388 1427 -76 1327 -1428 -843 -237 1428 572 1377 -869 1018 -1488 1857 1757 1412 872 230 2764 456 345 43 -1247 1963 -557 -234 -544 -413 -690 -1000 -156 7 130 213 -1176 -1413 610 -773 -1892 -838 -1531 -1219 445 721 529 -1238 -2648 -1201 1583 -961 -2570 -2665 -2680 1701 -398 1592 -149 1675 755 -132 87 -1236 597 1098 43 1137 2431 389 1809 930 -1709 2862 1247 44 -1843 2824 -1029 -492 601 -1786 -1611 1057 606 1096 -605 -1458 -1533 913 SS 20220131T133338.3Z 8066.565027 73 1 50.27 2 76.40 129.91 78.70 140.36 0.00 1 0.00 1 0 25 3.961e-01 1.140e-02 2.459e-01 7.272e-03 5.970420e-01 3.894930e-03 6.918935e-03 -6.000000e+00 2.253317e-01 224.14 -2.00 3.55 -2.00 321.18 0.00e+00 4.501745e-03 1.701822e-03 2.111140e-03 -6.000000e+00 9.874286e-03 273.01 -2.00 20.00 -2.00 320.71 0.00e+00 4.154 0.001 302.00 328.00 3 3.0519e+00 1.2384e-02 5.1691e-02 -6.0000e+00 5.5800e-01 9.9680e-02 1.6876e-02 3.2443e-02 -6.0000e+00 6.1010e-01 -1.1721e-01 1.7946e-02 2.0214e-02 -6.0000e+00 3.6054e-01 3.3320e-02 8.7458e-03 8.9692e-03 -6.0000e+00 1.5138e-01 2.1229e-04 1.0240e-04 2.1506e-04 1.0870e-04 -6.0000e+00 1.0753e-02 -6.0897e-03 2.5511e-05 12 8 8 10 0 0 9.14 22.91 0.51 -0.00609 -0.00532 28 6 1 5 0 1795.160 26.51 19.98 22.91 -3.93 12.0 832.68 -202790 -149864 -169454 900000 -133680 900000 -67004 900000 -96701 -113727 129921 -106843 -61466 -76072 900000 -48618 -35115 900000 35870 -10444 -15752 62077 84467 58942 -18296 11422 -18974 -53952 3643 -46009 -23951 35862 -13757 -6699 -19658 -4836 -26712 9984 11054 1042 -14287 11182 -17176 5002 8472 8767 1397 17684 1337 -4160 1639 6245 2861 7391 11354 3747 3301 2661 3214 4951 3112 -3307 6442 7570 3952 4468 -1628 2228 713 5682 795 2593 3942 -303 -211 1510 -1081 -3508 -1513 -620 -1222 -2054 -558 -1893 -764 123 -329 174 875 885 -1200 -2142 -1941 -1019 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