File name: Pandora183s1_LondonderryNH_20220222_L2Fit_fwvt1c1d20210421p1-8.txt File generation date: 20251125T173818.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20220222_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20220222 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1612 1761 Nominal wavelengths inside fitting window [nm]: 492.0175 492.1392 492.2609 492.3825 492.5042 492.6258 492.7474 492.8690 492.9906 493.1121 493.2337 493.3552 493.4767 493.5982 493.7197 493.8411 493.9626 494.0840 494.2054 494.3268 494.4482 494.5695 494.6909 494.8122 494.9335 495.0548 495.1761 495.2973 495.4186 495.5398 495.6610 495.7822 495.9033 496.0245 496.1456 496.2668 496.3879 496.5090 496.6300 496.7511 496.8721 496.9932 497.1142 497.2351 497.3561 497.4771 497.5980 497.7189 497.8398 497.9607 498.0816 498.2024 498.3233 498.4441 498.5649 498.6857 498.8065 498.9272 499.0479 499.1687 499.2894 499.4100 499.5307 499.6514 499.7720 499.8926 500.0132 500.1338 500.2544 500.3749 500.4954 500.6159 500.7364 500.8569 500.9774 501.0978 501.2183 501.3387 501.4591 501.5794 501.6998 501.8201 501.9405 502.0608 502.1811 502.3013 502.4216 502.5418 502.6621 502.7823 502.9025 503.0226 503.1428 503.2629 503.3830 503.5032 503.6232 503.7433 503.8634 503.9834 504.1034 504.2234 504.3434 504.4634 504.5833 504.7032 504.8232 504.9431 505.0629 505.1828 505.3026 505.4225 505.5423 505.6621 505.7819 505.9016 506.0214 506.1411 506.2608 506.3805 506.5002 506.6198 506.7395 506.8591 506.9787 507.0983 507.2178 507.3374 507.4569 507.5764 507.6959 507.8154 507.9349 508.0543 508.1738 508.2932 508.4126 508.5320 508.6513 508.7707 508.8900 509.0093 509.1286 509.2479 509.3671 509.4864 509.6056 509.7248 509.8440 509.9632 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20220222T141353.7Z 8088.592982 331 1 1.56 2 64.94 134.19 88.05 244.95 0.00 1 0.00 1 0 15 2.935e-03 2.933e-03 6.524e-04 6.516e-04 8.572574e+02 3.600091e+01 6.259038e+01 -6.000000e+00 1.593855e+02 273.57 -2.00 20.00 -2.00 505.26 0.00e+00 4.603778e-04 1.758622e-05 2.304793e-05 -6.000000e+00 8.099573e-05 273.57 -2.00 20.00 -2.00 500.47 0.00e+00 1.346545e-01 1.287833e-02 8.239603e-03 -6.000000e+00 5.851918e-02 225.02 -2.00 3.55 -2.00 502.06 0.00e+00 2.346 0.000 489.00 513.00 1 3.0385e+00 9.8521e-04 3.4252e-03 -6.0000e+00 4.4792e-03 1.0691e-02 2.5380e-04 2.5385e-04 -6.0000e+00 1.1533e-03 6.6441e-02 4.8830e-04 6.6437e-05 1.1645e-05 -6.0000e+00 3.0637e-04 -3.1163e-03 4.9784e-05 12 1 1 12 1 1 90.22 22.79 0.82 -0.00312 0.00027 16 127 1 4 0 81.370 26.41 20.01 22.79 11.00 13.1 959.12 -509 -475 -364 -281 -218 272 461 462 440 287 293 39 -130 -272 -271 -479 -298 -70 -57 -208 -25 324 177 446 494 458 409 231 -221 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76 167 282 466 547 514 362 200 249 104 90 209 74 -21 151 238 189 304 50 -153 -261 -189 -306 -39 -5 -113 -41 11 50 151 311 382 213 218 -257 -492 -507 -311 -234 SQ 20220222T141801.4Z 8088.595850 334 1 3.89 2 64.40 135.15 88.73 245.63 0.00 1 0.00 1 0 15 2.750e-03 2.740e-03 4.247e-04 4.241e-04 8.876450e+02 2.349945e+01 6.778244e+01 -6.000000e+00 1.493176e+02 273.57 -2.00 20.00 -2.00 505.26 0.00e+00 4.304722e-04 1.143913e-05 2.043238e-05 -6.000000e+00 7.589064e-05 273.57 -2.00 20.00 -2.00 500.43 0.00e+00 1.386593e-01 8.389036e-03 7.511370e-03 -6.000000e+00 5.485847e-02 225.02 -2.00 3.55 -2.00 502.03 0.00e+00 2.301 0.000 489.00 513.00 1 3.2045e+00 6.4184e-04 3.3439e-03 -6.0000e+00 4.1985e-03 1.2008e-02 1.6543e-04 2.4693e-04 -6.0000e+00 1.0819e-03 5.6640e-02 1.5479e-03 4.3212e-05 1.1695e-05 -6.0000e+00 2.8699e-04 -1.1343e-04 -1.9350e-05 12 1 1 12 1 1 99.84 22.80 0.84 -0.00011 0.01062 46 130 1 4 0 78.940 26.41 20.00 22.80 11.09 13.1 959.38 -491 -505 -401 -286 -258 144 503 327 326 297 245 64 -272 -263 -241 -404 -237 -131 -2 -226 50 152 185 364 452 455 451 176 -176 -157 -150 -173 -65 329 27 -87 188 144 -51 -123 19 17 49 214 249 219 276 210 72 -303 -414 -544 -623 -332 -133 -154 -80 -39 104 312 408 348 318 354 250 257 109 89 -139 -236 -139 -165 -72 25 -73 -291 -246 -140 -304 -373 -350 -476 -337 -75 -89 -132 -104 -81 -45 81 275 458 412 229 405 381 52 -133 -442 -473 -439 -244 -193 -159 -405 -310 -183 -134 6 30 46 95 213 270 427 556 569 340 151 99 62 22 254 161 -83 137 225 116 239 151 -131 -183 -290 -320 -164 -5 -87 -241 67 108 176 323 389 244 41 -262 -363 -463 -403 -303 -483 -500 -398 -293 -265 151 522 344 343 310 252 66 -279 -267 -242 -407 -241 -133 -2 -239 53 161 192 377 470 472 466 184 -181 -161 -151 -173 -67 336 28 -91 194 150 -52 -126 19 18 51 220 258 227 284 213 73 -304 -413 -530 -602 -322 -132 -154 -82 -40 107 320 418 358 321 357 256 260 108 87 -138 -232 -135 -162 -72 25 -72 -284 -242 -135 -292 -359 -338 -464 -331 -74 -87 -130 -103 -80 -45 80 275 452 412 230 402 380 51 -127 -426 -450 -418 -236 -188 -156 -404 -308 -180 -133 6 30 46 95 216 269 427 557 571 341 150 99 61 22 248 157 -81 135 220 114 233 146 -126 -178 -278 -305 -157 -5 -84 -237 67 106 173 319 385 242 41 -256 -357 -445 -383 -288 SQ 20220222T142309.4Z 8088.599414 337 1 16.97 2 63.75 136.34 89.57 246.47 0.00 1 0.00 1 0 15 3.200e-03 3.181e-03 3.243e-04 3.237e-04 8.389263e+02 1.789921e+01 5.767279e+01 -6.000000e+00 1.737546e+02 273.57 -2.00 20.00 -2.00 505.25 0.00e+00 5.059504e-04 8.757791e-06 2.420065e-05 -6.000000e+00 8.831103e-05 273.57 -2.00 20.00 -2.00 500.42 0.00e+00 1.089060e-01 6.410102e-03 8.676288e-03 -6.000000e+00 6.383823e-02 225.02 -2.00 3.55 -2.00 502.02 0.00e+00 2.248 0.000 489.00 513.00 1 4.1016e+00 4.9087e-04 3.3024e-03 -6.0000e+00 4.8857e-03 1.3435e-02 1.2649e-04 2.5003e-04 -6.0000e+00 1.2590e-03 2.3296e-02 1.6272e-03 3.2891e-05 1.1247e-05 -6.0000e+00 3.3396e-04 3.9542e-04 -2.4728e-05 12 1 1 12 1 1 99.99 22.80 0.82 0.00040 0.01168 132 82 1 4 0 126.260 26.41 19.99 22.80 11.09 13.1 959.36 -669 -649 -533 -312 -195 229 517 377 398 325 254 73 -260 -277 -404 -472 -300 -28 -10 -158 81 215 226 447 530 470 375 288 -127 -294 -176 -223 -116 286 42 -100 118 124 -43 -69 -4 35 137 173 341 294 300 271 88 -257 -512 -630 -684 -382 -171 -225 -66 -33 152 312 534 448 461 426 315 282 203 51 -171 -323 -181 -175 -122 52 -72 -338 -386 -280 -330 -455 -474 -468 -466 -118 -178 -230 -108 -38 -4 31 292 475 387 304 379 375 12 -217 -422 -592 -564 -355 -128 -92 -360 -289 -211 -225 -55 73 -45 120 301 417 548 661 614 450 287 192 53 67 266 159 3 137 226 148 250 161 -152 -212 -308 -390 -231 36 -169 -176 79 135 186 263 376 258 134 -218 -445 -515 -518 -420 -646 -632 -532 -322 -199 238 545 403 425 345 265 75 -265 -279 -403 -473 -303 -29 -11 -164 84 223 234 464 552 490 389 306 -132 -298 -175 -222 -118 298 43 -104 123 127 -45 -72 -5 37 140 178 354 306 310 276 91 -261 -507 -610 -656 -368 -169 -228 -69 -33 154 313 535 452 465 430 316 289 205 51 -169 -315 -176 -170 -120 52 -72 -336 -378 -270 -315 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