File name: Pandora183s1_LondonderryNH_20220721_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20251125T182311.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20220721_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20220721 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220721T102119.2Z 8237.431472 211 1 49.79 2 81.62 69.85 32.14 155.01 0.00 1 0.00 1 0 25 6.541e-01 4.118e-02 4.614e-01 3.061e-02 7.680383e-01 1.743953e-02 1.053278e-02 -6.000000e+00 3.848894e-01 232.82 -2.00 3.55 -2.00 322.04 0.00e+00 1.691633e-02 9.653571e-03 1.185242e-02 -6.000000e+00 1.970992e-02 287.93 -2.00 20.00 -2.00 321.49 0.00e+00 6.445 0.005 302.00 328.00 3 2.0032e+00 6.9537e-02 9.2518e-02 -6.0000e+00 9.6873e-01 1.1410e+00 8.4320e-02 6.8217e-02 -6.0000e+00 1.0538e+00 -1.3591e+00 5.6513e-02 2.9475e-02 -6.0000e+00 6.2039e-01 4.9856e-01 2.8168e-02 8.5177e-03 -6.0000e+00 2.6212e-01 4.6230e-05 -6.6873e-04 8.8022e-04 3.6452e-04 -6.0000e+00 1.8105e-02 -3.0388e-03 6.7142e-05 12 8 8 10 0 0 71.84 22.78 0.71 -0.00304 -0.00806 21 4 1 5 0 2370.320 26.41 20.00 22.78 30.33 17.8 1059.69 900000 -85068 900000 -37872 24060 -91671 -3908 900000 -55508 -52395 128366 900000 900000 -82186 -22749 220634 105990 43011 241426 32951 900000 -63451 289813 124944 33373 900000 204339 900000 -99256 62194 -99255 900000 7760 900000 16289 21939 132283 112829 77840 3689 91252 -12248 78775 253995 107372 116428 48500 50777 31670 -2347 120011 98908 24255 72772 19708 8146 74806 24021 30435 26783 12184 39326 33667 14049 21064 67904 31434 21069 15216 2697 32227 16410 12934 1221 8445 38373 -18311 20520 8539 -4562 -7003 10060 -5062 5550 -3480 -7786 -5293 -4603 17394 1251 4839 -8881 7781 -9540 -2631 -6803 -6407 102 -6502 -1193 2569 -8066 -510 -1227 -4342 -4077 -5807 1922 -1252 -2520 3141 653 -1011 -1966 -6870 1831 1137 1409 2262 72 5249 1861 3418 -336 4468 713 1230 4363 -2583 1874 -988 810 -2388 2401 -974 -61 1933 702 629 -1553 1441 -3539 -1270 900000 -6435 900000 -1736 717 -5043 -116 900000 -1781 -1561 3825 900000 900000 -5086 -991 6575 3158 1495 7194 1309 900000 -5830 8636 3723 994 900000 6089 900000 -9366 1853 -11831 900000 443 900000 849 981 3942 3362 2513 284 3172 -1247 3628 7569 3781 3785 3153 3301 2574 -280 4551 5091 2825 5520 2616 1214 5674 2928 3298 2902 1551 4155 4286 2474 3709 7358 4769 3596 2968 680 6635 4090 3259 321 1853 5509 -4266 3280 1735 -1273 -2371 3298 -2125 2210 -1603 -3965 -2753 -2444 7398 603 2097 -4114 2930 -4419 -1290 -4110 -4548 79 -5971 -1053 2053 -6402 -371 -889 -3481 -3463 -5313 1758 -1314 -3057 4062 932 -1491 -2858 -10010 2363 1498 1952 3310 113 7649 2684 4665 -461 5645 905 1510 5487 -4009 3200 -1931 1676 -5408 5545 -2499 -162 5178 1934 1725 -4166 3499 -8425 -2854 SS 20220721T103640.6Z 8237.442137 216 1 49.19 2 78.96 72.30 31.06 161.72 0.00 1 0.00 1 0 17 4.579e-01 1.155e-02 2.987e-01 6.379e-03 6.358415e-01 3.522660e-03 7.623754e-03 -6.000000e+00 2.644416e-01 232.82 -2.00 3.55 -2.00 321.59 0.00e+00 4.015045e-03 1.897139e-03 5.060327e-03 -6.000000e+00 1.210796e-02 287.93 -2.00 20.00 -2.00 320.99 0.00e+00 5.033 0.002 302.00 328.00 3 1.7981e+00 1.3187e-02 6.5497e-02 -6.0000e+00 6.6418e-01 1.0958e-01 1.8643e-02 4.7791e-02 -6.0000e+00 7.1827e-01 -2.1602e-01 1.8128e-02 2.3424e-02 -6.0000e+00 4.2778e-01 8.1542e-02 8.3760e-03 5.9136e-03 -6.0000e+00 1.8079e-01 3.1786e-04 -6.7618e-04 1.8732e-04 1.1278e-04 -6.0000e+00 1.2233e-02 -3.1653e-03 1.8367e-05 12 8 8 10 0 0 97.24 22.78 0.54 -0.00317 -0.00825 72 15 1 5 0 683.010 26.41 20.00 22.78 31.91 17.9 1070.72 -156915 140270 -132781 900000 -210106 -43098 -67836 -78840 -153791 -144843 -106321 -124680 900000 -94920 -116191 -61348 -93760 50889 13982 14878 -21825 -25402 30764 -61933 21630 -68458 182876 12182 5575 6335 301 -9502 -38170 18770 -17424 44848 -30187 8983 11459 15437 -4799 -21937 14838 -4039 2555 -7808 10235 -8403 11244 12747 -7378 12518 2347 11838 6442 5783 -194 -4689 6622 1105 6473 3088 7359 6557 6180 3919 1922 4864 2889 7070 1145 6869 529 7140 -910 -1437 3918 -5840 2959 623 362 -3183 -3493 -550 -953 1827 916 2428 470 605 -232 -11 -1333 -3050 -1126 -2429 128 293 -601 30 -2312 -1652 -2309 -188 -2624 -1531 -667 -176 235 -227 1077 278 945 -691 -416 191 1067 -12 407 289 -523 1909 816 921 -126 -462 538 503 157 -871 221 177 -643 168 -172 -31 -57 578 91 -24 344 -839 -432 -1201 872 -1170 900000 -3702 -268 -422 -490 -1913 -1801 -937 -1421 900000 -1279 -2469 -922 -2235 316 138 154 -339 -408 287 -1716 281 -2322 1137 186 88 104 6 -258 -1618 499 -650 862 -1314 310 473 742 -323 -1898 940 -320 192 -667 746 -760 871 1031 -805 1260 288 1439 881 830 -31 -777 955 165 937 504 1310 1334 1352 862 419 1156 764 1887 362 2167 178 2349 -298 -424 1011 -1656 848 217 149 -1556 -1892 -308 -572 1143 611 1652 327 408 -147 -6 -760 -1802 -726 -1840 110 288 -655 33 -2434 -1558 -2002 -160 -2472 -1516 -691 -194 282 -307 1594 440 1492 -1069 -606 265 1475 -17 633 472 -858 2948 1229 1340 -178 -631 702 683 241 -1526 420 357 -1376 379 -417 -80 -150 1529 243 -61 828 -1922 -958 SS 20220721T104243.2Z 8237.446333 219 1 49.21 2 77.90 73.27 30.73 164.46 0.00 1 0.00 1 0 17 3.746e-01 9.452e-03 2.400e-01 4.207e-03 5.891267e-01 2.268317e-03 7.048138e-03 -6.000000e+00 2.163223e-01 232.82 -2.00 3.55 -2.00 321.29 0.00e+00 2.165183e-03 1.127657e-03 4.037908e-03 -6.000000e+00 9.580626e-03 287.93 -2.00 20.00 -2.00 320.65 0.00e+00 4.627 0.002 302.00 328.00 3 1.6967e+00 8.0310e-03 5.9356e-02 -6.0000e+00 5.4325e-01 2.7415e-02 1.0992e-02 4.1736e-02 -6.0000e+00 5.8750e-01 -9.4706e-02 1.0579e-02 1.9333e-02 -6.0000e+00 3.4969e-01 2.7723e-02 4.9951e-03 4.7187e-03 -6.0000e+00 1.4723e-01 5.4830e-04 -4.9927e-04 1.2240e-04 8.2632e-05 -6.0000e+00 9.8947e-03 -3.0784e-03 7.0051e-06 12 8 8 10 0 0 85.82 22.81 0.34 -0.00308 -0.00683 87 18 1 5 0 565.550 26.41 19.99 22.81 32.29 17.8 1072.56 174482 -89305 -52240 -71840 -143173 -28228 -192221 -46536 -75498 -105956 -122277 -120277 17174 -99148 18751 -96427 -15333 -63265 -34147 -20080 -53490 -113 -35616 -33348 -9940 -37923 -28356 3175 -24420 -30656 -27445 -22685 -6281 -18407 490 -16451 -10015 1254 -14051 948 -1910 14532 5664 1635 9843 1457 2187 6563 6571 523 1751 3606 6647 4598 2854 269 3734 4613 1644 3589 -601 3760 3720 3669 7299 2293 4021 -2728 2319 1382 1442 3015 748 2436 -985 276 -4467 -2103 -2804 -2967 -150 -1691 -2306 -1880 158 448 431 1170 811 2326 428 -339 -2110 -1193 -2021 -832 -22 961 179 -749 -277 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