File name: Pandora183s1_LondonderryNH_20220818_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20251125T183227.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20220818_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20220818 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220818T114143.5Z 8265.487309 247 1 23.43 2 71.66 89.09 34.33 228.43 0.00 1 0.00 1 0 17 1.657e-01 1.021e-02 1.478e-01 7.355e-03 4.189970e-01 3.760067e-03 5.027296e-03 -6.000000e+00 9.525445e-02 231.65 -2.00 3.55 -2.00 319.81 0.00e+00 1.792027e-03 1.165906e-03 1.615252e-03 -6.000000e+00 4.242687e-03 288.26 -2.00 20.00 -2.00 319.04 0.00e+00 3.136 0.001 302.00 328.00 3 3.8703e+00 1.1060e-02 3.8827e-02 -6.0000e+00 2.3849e-01 4.1660e-02 1.3243e-02 2.3931e-02 -6.0000e+00 2.5816e-01 -2.0395e-03 1.0575e-02 1.1623e-02 -6.0000e+00 1.5384e-01 -9.6686e-03 5.4978e-03 3.1303e-03 -6.0000e+00 6.4936e-02 2.9332e-04 -3.0108e-04 2.1358e-04 3.7639e-05 -6.0000e+00 4.3756e-03 -2.5215e-03 -3.0694e-05 12 9 9 12 1 1 -4.91 23.04 0.25 -0.00252 -0.00478 6 3 1 5 0 3320.600 26.62 19.99 23.04 20.82 18.1 972.91 -51852 -19823 -28050 5907 -73362 -6437 -75775 -23198 106325 -23660 -60248 11007 32740 35914 7421 5676 3257 -11341 -18259 7770 -21348 28829 -9574 -6743 6399 24559 8387 -5613 5446 -14233 -3224 3514 5916 359 -3427 -6490 10195 6931 -10219 1375 -3673 8374 -493 818 -2990 -1216 -4213 -3513 3189 4478 1559 2193 -2454 1530 5220 -961 2178 658 -834 1363 -939 543 2971 6247 -531 -567 -868 525 807 3345 1277 2530 -2005 1193 -627 449 398 -5008 -447 -677 -1600 -1804 -969 -2053 29 726 -384 -172 209 589 -528 503 538 -583 164 -602 1149 305 56 -949 461 -965 -139 -1791 -1992 -1380 -922 -310 748 737 871 621 260 170 -389 -1302 694 -44 1229 -187 9 764 605 911 141 -181 670 -28 -29 295 201 -673 -769 -420 -147 -268 474 511 -378 573 27 -281 -715 -1054 -344 -570 85 -2105 -97 -2372 -484 763 -617 -2318 215 598 773 256 233 151 -651 -1202 415 -1587 1297 -643 -470 421 1425 585 -436 359 -1142 -254 296 548 38 -398 -745 1060 870 -1854 266 -843 1820 -122 205 -785 -317 -1136 -940 803 1140 438 673 -852 546 1887 -381 861 265 -333 525 -379 233 1383 3092 -291 -296 -428 252 413 1910 826 1700 -1412 781 -388 247 199 -2547 -231 -403 -1104 -1401 -810 -1826 27 719 -407 -188 228 620 -523 453 449 -484 146 -606 1287 388 70 -1192 588 -1136 -151 -2013 -2431 -1775 -1237 -437 1011 1084 1377 1016 418 259 -605 -1932 1008 -68 1986 -295 14 1178 996 1437 213 -262 921 -40 -45 497 363 -1159 -1365 -781 -290 -556 1002 1101 -824 1197 53 -538 -1345 SS 20220818T114707.2Z 8265.491055 250 1 49.32 2 70.67 90.01 35.05 230.25 0.00 1 0.00 1 0 25 7.052e-02 7.235e-03 3.353e-02 2.322e-03 3.988673e-01 1.191331e-03 4.703322e-03 -6.000000e+00 4.055610e-02 231.65 -2.00 3.55 -2.00 319.65 0.00e+00 9.769557e-04 3.429622e-04 1.093456e-03 -6.000000e+00 1.806252e-03 288.26 -2.00 20.00 -2.00 318.84 0.00e+00 2.986 0.000 302.00 328.00 3 2.7639e+00 3.4517e-03 3.6665e-02 -6.0000e+00 1.0154e-01 1.9788e-02 4.0909e-03 2.2001e-02 -6.0000e+00 1.0990e-01 5.8820e-03 3.1657e-03 1.0662e-02 -6.0000e+00 6.5495e-02 -1.2195e-02 1.6470e-03 2.8958e-03 -6.0000e+00 2.7653e-02 1.0645e-03 -3.1823e-04 6.7991e-05 3.1265e-05 -6.0000e+00 1.8624e-03 -3.1386e-03 1.3439e-05 11 8 0 10 0 0 98.65 23.06 0.21 -0.00314 -0.00553 51 11 1 5 0 966.880 26.73 20.00 23.06 20.91 18.1 973.37 -34585 -16068 5485 -17787 6001 -43807 -2554 -29695 -25042 -7992 -11672 -12955 -12798 -6151 -16404 2301 -14386 135 571 -2934 -1158 -4017 1459 -9131 -523 -6171 -4779 -558 -119 1170 -7014 1241 -2358 -929 -6220 -5597 -1245 -3813 -357 -3081 2258 -1913 -515 -417 1691 -230 583 519 -1317 565 -921 847 2395 1571 368 1986 749 297 1019 -493 1600 3179 2391 4107 1377 1041 -940 -1164 208 521 685 982 906 869 71 -217 -1239 -1834 -1188 -1364 -1254 -472 -2383 -1291 -1075 -724 83 496 1178 720 662 -2 -1051 -30 -308 -244 577 1160 175 -539 -640 -1363 -1408 -508 -1113 -1186 -602 -1041 138 535 644 559 587 197 -455 -159 87 265 276 341 89 539 787 372 530 -286 223 621 141 -8 -562 -130 -313 -156 -237 -104 273 632 250 17 -8 -777 -525 -711 -321 104 -421 101 -1136 -46 -789 -727 -214 -332 -384 -435 -236 -834 113 -912 8 36 -199 -80 -286 100 -744 -42 -558 -436 -47 -9 100 -643 130 -288 -121 -821 -702 -160 -586 -65 -687 538 -508 -141 -116 465 -65 164 145 -376 162 -285 283 849 601 150 820 322 129 429 -208 675 1422 1194 2208 787 567 -489 -598 112 321 468 704 652 602 46 -127 -665 -949 -646 -851 -896 -375 -2095 -1182 -1048 -687 82 509 1206 788 674 -2 -925 -25 -283 -252 666 1359 223 -690 -770 -1653 -1590 -579 -1385 -1567 -754 -1379 192 806 1041 933 958 304 -654 -215 129 373 415 543 143 850 1200 548 817 -424 314 886 220 -13 -938 -224 -557 -290 -471 -218 582 1371 547 36 -17 -1517 -999 SS 20220818T115246.0Z 8265.494977 253 1 21.44 2 69.64 90.97 35.83 232.11 0.00 1 0.00 1 0 25 5.491e-02 7.192e-03 2.004e-02 2.004e-03 3.797899e-01 1.016929e-03 4.520197e-03 -6.000000e+00 3.157553e-02 231.65 -2.00 3.55 -2.00 319.13 0.00e+00 1.204318e-03 2.485471e-04 9.418982e-04 -6.000000e+00 1.406325e-03 288.25 -2.00 20.00 -2.00 318.30 0.00e+00 2.844 0.000 302.00 328.00 3 2.3371e+00 2.8599e-03 3.4831e-02 -6.0000e+00 7.9055e-02 1.6987e-02 3.3219e-03 2.0642e-02 -6.0000e+00 8.5571e-02 7.7761e-04 2.3943e-03 1.0002e-02 -6.0000e+00 5.0994e-02 -8.4467e-03 1.2561e-03 2.7182e-03 -6.0000e+00 2.1528e-02 1.9193e-03 -4.2182e-04 5.7864e-05 2.8595e-05 -6.0000e+00 1.4502e-03 -2.8921e-03 -8.8531e-06 12 9 1 12 1 1 84.42 23.06 0.26 -0.00289 -0.00606 32 16 1 5 0 644.370 26.73 20.00 23.06 21.03 18.1 974.53 -19896 -23934 -21094 -20843 -19064 -27374 -19396 -8120 -13450 -5395 -6463 -8680 -356 -8561 -206 2785 -3946 -2950 -1663 -1760 -1589 1086 697 407 -1162 -364 -3117 -4627 -6012 -1405 -695 -344 970 -1953 -3541 -7314 -3637 -2842 -1421 -661 -1748 -581 480 -425 -1008 928 -11 -1024 -213 -138 1606 901 1931 1407 1280 1632 1570 1138 199 347 1387 2125 2341 2647 1113 176 477 -400 392 770 1079 1007 742 1028 -80 -175 -1791 -1820 -960 -961 -1262 -1265 -2243 -1384 -1006 -346 -16 503 1216 716 448 -59 -902 -507 -872 -431 -56 848 180 -435 -721 -1449 -869 -132 -1289 -1292 -947 -606 90 816 723 521 313 36 -289 300 138 21 765 389 104 798 610 403 645 -156 -53 804 78 -85 12 -589 -235 -231 -110 -272 458 563 53 9 -298 -496 -586 -548 -799 -735 -715 -579 -841 -572 -241 -480 -194 -239 -370 -16 -499 -13 200 -330 -259 -154 -171 -160 106 69 43 -135 -44 -398 -579 -718 -158 -84 -47 146 -324 -574 -1176 -602 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