File name: Pandora183s1_LondonderryNH_20220918_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20251125T183958.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20220918_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20220918 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220918T113356.8Z 8296.481908 254 1 50.45 2 78.88 98.02 17.07 203.81 0.00 1 0.00 1 0 17 4.487e-01 1.604e-02 3.142e-01 1.096e-02 5.898426e-01 5.954092e-03 7.125008e-03 -6.000000e+00 2.565473e-01 228.79 -2.00 3.55 -2.00 321.40 0.00e+00 7.809603e-03 2.969076e-03 2.916815e-03 -6.000000e+00 1.209642e-02 285.60 -2.00 20.00 -2.00 320.80 0.00e+00 5.003 0.002 302.00 328.00 3 2.5727e+00 2.1038e-02 5.9285e-02 -6.0000e+00 6.3770e-01 2.3045e-01 2.8162e-02 3.3756e-02 -6.0000e+00 6.9265e-01 -2.7886e-01 2.5988e-02 2.0351e-02 -6.0000e+00 4.1194e-01 9.5272e-02 1.2356e-02 8.7009e-03 -6.0000e+00 1.7581e-01 1.5124e-04 -1.5953e-03 3.2675e-04 1.2183e-04 -6.0000e+00 1.1983e-02 -2.8160e-03 3.1548e-05 12 8 8 10 0 0 37.97 22.94 0.68 -0.00282 -0.01480 31 6 1 5 0 1626.940 26.51 20.05 22.94 23.01 19.3 983.83 900000 -100285 -46183 -158954 164486 900000 -143151 -202171 -109417 -123954 -100890 900000 -129061 -103020 -50956 -82873 83616 17745 -51778 74790 -4244 -62138 21476 125853 -35502 29886 -1760 15915 -39642 12914 125658 2626 5237 -2354 33613 37492 60130 -2485 -13010 49452 9582 2039 2252 10081 -4684 6110 -3553 -2902 17947 12941 17910 17838 22030 -231 9857 -345 6778 6103 4481 12861 14632 751 1114 13679 9113 3647 7892 -1007 4186 4581 1976 -2608 -1782 3982 -1556 1744 1495 -835 -9435 3041 -3071 -1335 -3380 -3100 508 -3862 2958 2030 385 1138 397 -543 -1612 -2173 -1319 -1619 -1007 578 -1120 -395 33 -3191 -52 -690 -1146 -2656 -1804 -288 212 1424 891 -132 -967 2165 -1684 448 -108 -178 1041 258 369 673 641 812 308 -128 2029 740 -534 317 139 -631 471 -400 -336 -760 869 1248 -81 101 -667 -459 -883 900000 -1154 -493 -3658 1758 900000 -2353 -7021 -1656 -2318 -1527 900000 -3333 -2660 -998 -2730 893 269 -1706 799 -94 -2435 363 1345 -1170 532 -44 326 -1377 301 1343 94 214 -114 1110 1129 1519 -135 -948 2306 754 186 217 930 -510 611 -400 -333 1726 1370 1966 2183 2825 -40 1628 -65 1218 1103 801 2074 2374 152 255 3123 2328 964 1924 -270 1147 1437 710 -1033 -699 1404 -533 518 408 -230 -3098 1040 -1310 -640 -1819 -1762 297 -2521 1905 1503 291 830 272 -349 -988 -1349 -895 -1272 -909 589 -1277 -453 36 -3195 -46 -613 -1102 -2759 -1957 -328 261 1936 1345 -214 -1576 3290 -2501 620 -151 -261 1605 421 602 1061 975 1194 436 -175 2617 997 -817 541 259 -1261 973 -883 -795 -1902 2191 3195 -210 253 -1589 -1030 -1931 SS 20220918T113959.2Z 8296.486102 257 1 49.58 2 77.79 99.08 17.55 207.94 0.00 1 0.00 1 0 17 3.180e-01 1.083e-02 2.668e-01 6.636e-03 5.466596e-01 3.540629e-03 6.701002e-03 -6.000000e+00 1.817188e-01 228.79 -2.00 3.55 -2.00 321.18 0.00e+00 4.549278e-03 1.678161e-03 3.841337e-03 -6.000000e+00 8.109608e-03 285.60 -2.00 20.00 -2.00 320.55 0.00e+00 4.589 0.002 302.00 328.00 3 2.4470e+00 1.2121e-02 5.6218e-02 -6.0000e+00 4.5327e-01 5.3606e-02 1.6294e-02 3.6374e-02 -6.0000e+00 4.9229e-01 -8.2087e-02 1.5477e-02 1.9582e-02 -6.0000e+00 2.9235e-01 2.0261e-02 7.4039e-03 6.0237e-03 -6.0000e+00 1.2343e-01 2.7830e-04 -6.9647e-04 1.9741e-04 1.0109e-04 -6.0000e+00 8.4647e-03 -1.6780e-03 1.7565e-05 12 8 8 10 0 0 5.59 22.97 0.31 -0.00168 -0.00691 44 9 1 5 0 1126.490 26.62 19.99 22.97 23.42 19.3 987.13 -124796 -140524 -64810 -39735 -86052 -148395 -5907 -94559 900000 26666 -124887 -86602 30908 -77392 -19312 -28821 90785 -60628 26883 -18970 15484 -57055 -10850 -27787 -44230 -14758 -31050 -5808 -32856 -3394 -37582 13893 -6712 -9346 -2257 4363 21485 -14262 7650 -948 5666 -1196 1418 -6373 5450 7803 1600 14124 194 4351 2168 -644 10228 200 6021 738 8341 3871 -1338 4821 1214 5885 1001 7771 3582 569 2426 782 -2640 451 4101 3321 3048 787 1526 360 -5137 -4744 -2718 587 -1980 -1771 -2288 -1814 -1217 -953 455 643 2111 1753 788 -772 -2578 -938 -1256 -686 923 748 -377 -602 -665 -1400 -461 -2112 -512 -1861 -1160 -372 -36 1149 1285 1155 166 -373 -1279 -47 -168 119 1196 43 -145 1453 628 695 815 -953 -104 665 -810 -168 -401 -435 -677 155 -202 -675 909 938 289 -41 121 -606 -737 -1180 -2046 -489 -257 -742 -2240 -38 -969 900000 173 -2222 -1121 200 -1419 -250 -497 587 -1798 362 -430 259 -1969 -262 -850 -1717 -451 -1151 -164 -1179 -94 -1680 441 -304 -478 -105 182 809 -898 473 -77 490 -120 146 -735 567 812 181 1437 23 527 293 -100 1558 36 1098 147 1590 774 -275 919 246 1243 251 2043 1041 166 666 220 -831 158 1551 1334 1228 341 605 130 -1795 -1627 -995 244 -987 -1003 -1429 -1194 -850 -712 354 517 1681 1358 575 -530 -1702 -612 -904 -564 858 795 -443 -711 -738 -1416 -424 -1993 -514 -2012 -1311 -445 -46 1625 1991 1880 272 -586 -1903 -66 -237 175 1855 71 -240 2298 969 1035 1161 -1328 -139 906 -1250 -288 -747 -856 -1391 334 -468 -1655 2249 2365 734 -100 282 -1346 -1596 SS 20220918T114531.3Z 8296.489946 260 1 49.99 2 76.79 100.06 18.04 211.55 0.00 1 0.00 1 0 25 2.701e-01 8.889e-03 1.770e-01 4.986e-03 5.126856e-01 2.629975e-03 6.063920e-03 -6.000000e+00 1.536792e-01 228.79 -2.00 3.55 -2.00 320.95 0.00e+00 1.221533e-03 1.158567e-03 2.602800e-03 -6.000000e+00 6.840493e-03 285.60 -2.00 20.00 -2.00 320.29 0.00e+00 4.265 0.001 302.00 328.00 3 2.4256e+00 8.6733e-03 5.1652e-02 -6.0000e+00 3.8244e-01 1.6767e-02 1.1349e-02 3.2244e-02 -6.0000e+00 4.1508e-01 -4.9678e-02 1.0574e-02 1.5304e-02 -6.0000e+00 2.4754e-01 9.2984e-03 5.1493e-03 4.0217e-03 -6.0000e+00 1.0483e-01 4.0696e-04 -5.9389e-04 1.4896e-04 5.7774e-05 -6.0000e+00 7.1292e-03 -1.6201e-03 7.9379e-07 11 8 0 10 0 0 99.51 22.99 0.42 -0.00162 -0.00608 61 13 1 5 0 819.290 26.62 20.00 22.99 23.96 19.4 991.13 -93427 -119960 -21828 -77545 107939 -72862 -90809 -40640 -114035 -42884 -102368 -33293 -81389 -44279 319 -58441 -14891 -8218 32371 -17424 15503 -14418 -2883 -5358 -23930 -4721 -2986 1893 -27017 4371 -340 1117 9095 -9419 3587 -8481 7710 -13196 9186 1865 653 3836 2146 -278 3429 1616 2081 1699 2057 -2842 994 -2565 3776 741 3690 4169 191 3233 -788 4451 2339 1022 642 3862 1722 1600 -455 179 457 1688 3433 1468 -515 998 459 849 -4241 -2174 -2091 -17 -3021 -549 -384 -3146 -873 -355 1141 295 2042 1257 408 -253 -1593 -649 -2083 -148 274 1841 104 -24 -832 -2132 -1106 -1816 -1783 -1811 -678 -228 220 952 1244 342 338 323 -447 -79 -178 -757 698 139 775 127 1036 232 183 -162 -18 874 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