File name: Pandora183s1_LondonderryNH_20221105_L2Fit_fout2c1d20210421p1-8.txt File generation date: 20251125T185104.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 183 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora183_OF_v3d20201222.txt Instrument calibration file used: Pandora183s1_CF_v1d20210421.txt Level 1 file used: Pandora183s1_LondonderryNH_20221105_L1_smca1c1d20210421p1-8.txt Full location name: MOOSEHILL SCHOOL - Londonderry NH Short location name: LondonderryNH Country of location: United States Location latitude [deg]: 42.8625 Location longitude [deg]: -71.3801 Location altitude [m]: 108 Local noon date: 20221105 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0158 305.1571 305.2983 305.4395 305.5807 305.7219 305.8631 306.0043 306.1454 306.2866 306.4277 306.5689 306.7100 306.8511 306.9922 307.1333 307.2743 307.4154 307.5565 307.6975 307.8385 307.9796 308.1206 308.2616 308.4026 308.5435 308.6845 308.8255 308.9664 309.1073 309.2483 309.3892 309.5301 309.6710 309.8119 309.9527 310.0936 310.2344 310.3753 310.5161 310.6569 310.7977 310.9385 311.0793 311.2201 311.3608 311.5016 311.6423 311.7830 311.9237 312.0645 312.2051 312.3458 312.4865 312.6272 312.7678 312.9084 313.0491 313.1897 313.3303 313.4709 313.6115 313.7520 313.8926 314.0332 314.1737 314.3142 314.4547 314.5952 314.7357 314.8762 315.0167 315.1571 315.2976 315.4380 315.5785 315.7189 315.8593 315.9997 316.1401 316.2804 316.4208 316.5611 316.7015 316.8418 316.9821 317.1224 317.2627 317.4030 317.5433 317.6835 317.8238 317.9640 318.1042 318.2444 318.3846 318.5248 318.6650 318.8052 318.9453 319.0855 319.2256 319.3657 319.5058 319.6459 319.7860 319.9261 320.0662 320.2062 320.3463 320.4863 320.6263 320.7663 320.9063 321.0463 321.1863 321.3262 321.4662 321.6061 321.7461 321.8860 322.0259 322.1658 322.3057 322.4455 322.5854 322.7252 322.8651 323.0049 323.1447 323.2845 323.4243 323.5641 323.7039 323.8436 323.9834 324.1231 324.2628 324.4025 324.5422 324.6819 324.8216 324.9612 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221105T115852.5Z 8344.499219 185 1 50.08 2 85.15 116.78 127.78 314.34 0.00 1 0.00 1 0 17 6.767e-01 9.368e-02 5.415e-01 9.135e-02 7.115301e-01 5.010867e-02 7.455324e-03 -6.000000e+00 3.915513e-01 223.70 -2.00 3.55 -2.00 321.55 0.00e+00 -1.112067e-02 1.557573e-02 2.443604e-03 -6.000000e+00 1.881257e-02 279.61 -2.00 20.00 -2.00 320.91 0.00e+00 10.054 0.019 302.00 328.00 3 -5.5928e-02 1.5702e-01 1.0770e-01 -6.0000e+00 9.6172e-01 1.6267e+00 1.8215e-01 4.6630e-02 -6.0000e+00 1.0507e+00 -1.6925e+00 1.0080e-01 1.6761e-02 -6.0000e+00 6.2976e-01 5.8176e-01 5.6817e-02 9.9139e-03 -6.0000e+00 2.7233e-01 1.4002e-05 7.2676e-03 2.7373e-03 1.2382e-04 -6.0000e+00 1.8521e-02 1.2024e-03 -8.6095e-05 12 8 8 10 0 0 70.48 22.53 0.68 0.00120 0.05581 16 3 1 5 0 3129.240 26.11 20.01 22.53 20.72 20.5 984.00 900000 257116 33868 -10978 -37216 18627 31615 -45434 -13090 900000 -17814 26220 900000 -43971 900000 92357 117010 -48081 -6509 107471 900000 -26526 -44388 900000 12821 900000 153619 -12500 6550 900000 900000 100013 -43691 -6 -37495 900000 900000 289085 50485 210653 55939 43992 -12518 13327 241801 1587 900000 -39879 -16823 166684 900000 101664 -22297 3363 106290 160081 68626 63867 216677 111958 -54093 900000 32632 81268 56179 40406 -1688 78716 105557 22762 83510 -11504 13295 23097 -26332 -5003 -37061 62001 -36790 -1352 -12329 1780 32609 -12492 36774 -8587 50541 20643 -22906 48184 -817 7000 21458 76946 -24132 2365 -9713 28983 24030 -5758 -3415 296 -3895 -8283 12661 -11770 -14415 2074 17553 6792 -14301 -3449 -3847 6012 -3471 159 -3950 -3111 5422 3652 1104 2268 12711 -2557 -2867 -1562 5053 -1735 5998 9604 -1025 4344 3974 -3660 -2316 -3946 1364 1686 -1870 4283 -1502 344 -2630 900000 22840 3653 -1532 -5431 1655 2809 -7496 -1661 900000 -2435 2329 900000 -9315 900000 8204 10394 -11828 -1023 9547 900000 -4169 -8493 900000 1577 900000 13647 -1538 630 900000 900000 8885 -8733 -1 -6107 900000 900000 25680 4859 18713 6212 5536 -2687 2072 21480 247 900000 -8856 -2989 14807 900000 9031 -5447 672 9442 14221 7620 7092 19248 9946 -16818 900000 5534 9188 8166 6526 -409 8900 10229 5698 12139 -4366 3758 5409 -8931 -1212 -11673 7511 -13667 -415 -4879 690 10007 -6356 12176 -4716 15918 8835 -14799 14398 -370 2770 7278 16156 -15981 1394 -7452 17087 15719 -4929 -2620 196 -2548 -5953 7975 -9981 -13387 1775 14459 7076 -20326 -4596 -5126 6991 -4233 184 -4912 -4071 6918 4837 1462 2857 14063 -3201 -3846 -1998 6060 -2466 9112 15869 -2057 8798 8615 -9235 -6194 -11148 3732 4657 -5249 10692 -3724 795 -6308 SS 20221105T121043.2Z 8344.507445 188 1 49.48 2 83.24 118.89 129.18 317.49 0.00 1 0.00 1 0 17 4.966e-01 2.434e-02 3.909e-01 1.369e-02 6.905711e-01 7.513437e-03 8.783623e-03 -6.000000e+00 2.771606e-01 223.70 -2.00 3.55 -2.00 322.02 0.00e+00 1.953322e-02 4.256468e-03 2.751921e-03 -6.000000e+00 1.244952e-02 279.61 -2.00 20.00 -2.00 321.55 0.00e+00 7.751 0.009 302.00 328.00 3 2.5475e-02 2.8358e-02 8.5117e-02 -6.0000e+00 6.8313e-01 7.2755e-01 3.8043e-02 4.2182e-02 -6.0000e+00 7.4490e-01 -8.8871e-01 3.4642e-02 2.3912e-02 -6.0000e+00 4.4468e-01 3.4695e-01 1.6189e-02 1.9267e-02 -6.0000e+00 1.8994e-01 1.2613e-04 -1.6039e-03 4.0248e-04 2.7256e-04 -6.0000e+00 1.3230e-02 -2.7614e-03 6.5526e-06 12 8 8 10 0 0 -23.30 22.55 0.35 -0.00276 -0.01481 63 13 1 5 0 785.200 26.21 20.00 22.55 21.52 20.5 990.33 16081 -79781 -86485 900000 -123302 -97551 -193108 -28172 -125431 38191 -22038 -153096 -139868 -142082 11327 -87422 38686 -4802 116368 42545 104515 127094 5661 900000 -39313 -22228 -4729 177384 9616 -4668 -44237 40924 94797 42213 25691 116971 35557 103001 -26802 61936 28309 113775 -3192 59489 25374 30734 40525 -4141 44147 -2834 43594 35255 43200 32690 51765 45003 28000 49870 24279 38185 2754 22757 13738 22299 23855 3411 13402 7791 18637 7802 5748 13804 2036 16575 1607 10951 -7422 6639 810 396 3076 -402 -380 -3450 2181 -1693 3046 1640 521 1170 -2773 -1047 -7121 -111 -5624 -4252 -2669 -1997 150 -1221 -894 -4066 -1753 -4254 -2137 -1937 -3115 -112 -1415 1855 -1502 567 229 -1715 -388 -2638 1424 -2566 2119 -1191 2444 3517 128 3325 909 3356 -121 2021 -854 929 691 -222 556 -194 71 -313 1312 519 -116 679 -1757 -305 -2102 215 -1557 -1954 900000 -3419 -1803 -8528 -376 -2705 510 -294 -4599 -4668 -6639 151 -3890 560 -118 1554 710 1395 1697 120 900000 -1225 -569 -100 2368 171 -104 -1772 944 1496 1230 842 1562 993 1625 -1789 1954 1374 2486 -236 2455 1509 1791 2213 -367 2518 -272 2857 2781 3408 3055 4147 3878 2855 3995 2416 3244 344 2569 1951 3329 3793 658 2277 1418 3280 1752 1458 3367 551 3641 373 2060 -1549 1217 177 105 941 -147 -152 -1511 1054 -824 1490 926 299 648 -1496 -517 -3575 -53 -3221 -2833 -2063 -1786 146 -1226 -844 -3556 -1350 -3328 -1761 -1696 -2923 -110 -1558 2246 -2113 838 345 -2558 -543 -3634 1905 -3769 3168 -1926 3785 5183 188 4600 1244 4341 -158 2701 -1344 1645 1358 -472 1241 -465 181 -850 3579 1452 -326 1821 -4531 -727 -4933 SS 20221105T122137.2Z 8344.515013 191 1 49.50 2 81.51 120.88 130.40 320.50 0.00 1 0.00 1 0 17 4.500e-01 9.777e-03 1.603e-01 4.334e-03 5.980690e-01 2.328011e-03 7.275098e-03 -6.000000e+00 2.530175e-01 223.69 -2.00 3.55 -2.00 321.58 0.00e+00 4.383779e-03 1.213706e-03 4.904851e-03 -6.000000e+00 1.122414e-02 279.61 -2.00 20.00 -2.00 321.06 0.00e+00 6.377 0.005 302.00 328.00 3 5.9876e-02 8.2883e-03 7.3483e-02 -6.0000e+00 6.2339e-01 1.1798e-01 1.1714e-02 4.2997e-02 -6.0000e+00 6.8044e-01 -1.6228e-01 1.2186e-02 2.3494e-02 -6.0000e+00 4.0419e-01 5.7324e-02 5.7087e-03 7.3528e-03 -6.0000e+00 1.7257e-01 5.6361e-04 -6.5746e-04 1.3074e-04 1.3199e-04 -6.0000e+00 1.2052e-02 -2.0649e-03 -7.9403e-06 12 8 8 10 0 0 1.99 22.56 0.38 -0.00206 -0.00701 152 32 1 5 0 325.580 26.21 20.00 22.56 22.57 20.6 997.50 900000 -157800 -179807 -162702 -148639 -124940 900000 -159679 -134249 -65945 -171865 -129813 -105888 -106392 -46045 -15362 -38548 -55213 -57377 -8218 -49404 -59576 -20255 -40505 -390 -41266 -22138 -63938 -48603 -51025 -31593 -16979 12911 4960 19079 -22829 -11791 -5085 1607 4977 6655 8435 5495 5315 284 5361 -2932 7666 4967 6941 9287 7674 6122 4635 791 7004 4470 789 4696 3984 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