File name: Pandora107s1_LynnMA_20240614_L2Fit_fout2c8d20240424p1-8.txt File generation date: 20241009T175303.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 107 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora107_OF_v1d20230601.txt Instrument calibration file used: Pandora107s1_CF_v8d20240424.txt Level 1 file used: Pandora107s1_LynnMA_20240614_L1_smca1c8d20240424p1-8.txt Full location name: Lynn Massachusetts Department of Environmental Protection Short location name: LynnMA Country of location: United States Location latitude [deg]: 42.4746 Location longitude [deg]: -70.9708 Location altitude [m]: 52 Local noon date: 20240614 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: AnaFld based on session 7 "OOB session based on clearance session 6, absolute calibration done with an uncalibrated lamp, certificate of FEL1441 (GSFC) used" First and last pixel inside fitting window: 221 362 Nominal wavelengths inside fitting window [nm]: 305.1394 305.2803 305.4212 305.5621 305.7030 305.8438 305.9847 306.1255 306.2663 306.4071 306.5479 306.6887 306.8295 306.9702 307.1110 307.2517 307.3925 307.5332 307.6739 307.8146 307.9553 308.0959 308.2366 308.3773 308.5179 308.6585 308.7991 308.9397 309.0803 309.2209 309.3615 309.5021 309.6426 309.7832 309.9237 310.0642 310.2047 310.3452 310.4857 310.6262 310.7666 310.9071 311.0475 311.1880 311.3284 311.4688 311.6092 311.7496 311.8899 312.0303 312.1706 312.3110 312.4513 312.5916 312.7319 312.8722 313.0125 313.1528 313.2930 313.4333 313.5735 313.7137 313.8540 313.9942 314.1344 314.2745 314.4147 314.5549 314.6950 314.8352 314.9753 315.1154 315.2555 315.3956 315.5357 315.6757 315.8158 315.9558 316.0959 316.2359 316.3759 316.5159 316.6559 316.7959 316.9358 317.0758 317.2157 317.3557 317.4956 317.6355 317.7754 317.9153 318.0552 318.1950 318.3349 318.4747 318.6145 318.7544 318.8942 319.0340 319.1738 319.3135 319.4533 319.5930 319.7328 319.8725 320.0122 320.1519 320.2916 320.4313 320.5710 320.7106 320.8503 320.9899 321.1295 321.2691 321.4087 321.5483 321.6879 321.8275 321.9670 322.1066 322.2461 322.3856 322.5251 322.6646 322.8041 322.9436 323.0831 323.2225 323.3619 323.5014 323.6408 323.7802 323.9196 324.0590 324.1983 324.3377 324.4771 324.6164 324.7557 324.8950 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240614T104131.8Z 8931.445507 114 1 29.96 2 75.00 71.96 135.19 353.59 0.00 1 0.00 1 0 25 1.671e-01 8.353e-03 4.241e-02 1.633e-03 5.500048e-01 8.806857e-04 6.484026e-03 -6.000000e+00 9.942858e-02 232.94 -2.00 3.54 -2.00 320.25 0.00e+00 4.693044e-03 3.146633e-04 1.581796e-03 -6.000000e+00 4.354757e-03 285.52 -2.00 20.00 -2.00 319.58 0.00e+00 3.788 0.001 302.00 328.00 3 1.7074e+00 2.6565e-03 4.8326e-02 -6.0000e+00 2.4984e-01 2.8516e-02 3.2948e-03 3.0157e-02 -6.0000e+00 2.6957e-01 -6.4350e-02 2.9165e-03 1.6542e-02 -6.0000e+00 1.6009e-01 1.3566e-02 1.4743e-03 6.3799e-03 -6.0000e+00 6.7867e-02 1.1759e-03 -5.3361e-04 4.7302e-05 7.4577e-05 -6.0000e+00 4.7097e-03 7.6338e-03 0.0000e+00 11 8 0 10 0 0 19.35 21.96 0.44 0.00763 0.00362 126 126 1 5 0 237.720 26.11 20.00 21.96 26.80 0.0 950.87 -39736 -70720 -45031 -76654 -59814 -10244 -75513 -30856 -64268 -48100 -42461 -39028 -16676 -26663 -12673 -15988 -7438 -7436 -9962 2063 -12619 -5370 -15295 -1331 -10436 -17727 -9075 -14310 -2798 -9823 -1468 3066 -3292 -2573 -3140 2044 -3721 105 -1251 -3041 -745 -1588 1907 -1935 2792 1816 874 2732 1619 4055 3006 2575 2535 1924 1581 -287 -14 -393 157 1269 1931 2732 1592 1220 562 1980 2182 2044 1460 -269 174 -1095 -256 -827 -1004 -577 -739 76 -950 -890 -1142 -2169 -1151 -660 124 -174 -122 117 210 414 387 982 887 803 233 105 673 -616 -1226 -1232 -312 827 421 -1342 -2457 -1385 -624 590 631 275 -78 -204 247 550 1475 1569 1111 770 -643 -816 -440 350 105 -149 -231 505 1893 845 -378 -733 -672 285 93 14 -589 -103 143 -294 -480 -382 153 917 -386 -1036 -516 -1135 -705 -75 -1190 -354 -1115 -743 -669 -708 -308 -688 -343 -512 -242 -263 -385 74 -530 -213 -706 -58 -528 -985 -457 -749 -135 -566 -93 216 -269 -209 -250 161 -361 12 -173 -444 -116 -264 317 -342 481 323 160 506 318 839 697 661 703 568 489 -94 -5 -127 50 405 659 1037 683 562 260 866 942 949 775 -149 102 -658 -147 -445 -536 -280 -348 38 -548 -550 -807 -1709 -962 -583 107 -161 -117 112 198 369 347 817 729 710 217 112 811 -770 -1596 -1537 -377 905 456 -1560 -2869 -1689 -796 802 945 424 -128 -338 395 826 2228 2333 1715 1181 -1054 -1365 -720 547 159 -234 -347 723 2683 1313 -621 -1326 -1207 529 182 30 -1233 -222 314 -651 -1046 -796 317 1815 SS 20240614T105153.5Z 8931.452703 117 1 30.00 2 73.18 73.54 135.38 357.12 0.00 1 0.00 1 0 25 9.636e-02 7.749e-03 1.825e-02 1.079e-03 4.963742e-01 5.743306e-04 5.846474e-03 -6.000000e+00 5.735837e-02 232.94 -2.00 3.54 -2.00 319.77 0.00e+00 3.756493e-03 1.732916e-04 9.974568e-04 -6.000000e+00 2.511961e-03 285.52 -2.00 20.00 -2.00 319.04 0.00e+00 3.401 0.001 302.00 328.00 3 1.4230e+00 1.6675e-03 4.3318e-02 -6.0000e+00 1.4413e-01 1.5859e-02 1.9910e-03 2.6750e-02 -6.0000e+00 1.5551e-01 -5.1379e-02 1.6225e-03 1.4023e-02 -6.0000e+00 9.2352e-02 1.1098e-02 8.3938e-04 5.1963e-03 -6.0000e+00 3.9154e-02 2.4045e-03 -5.0031e-04 3.1606e-05 5.7843e-05 -6.0000e+00 2.7167e-03 7.1517e-03 0.0000e+00 11 8 0 10 0 0 1.99 21.98 0.34 0.00715 0.00339 194 194 1 5 0 154.610 26.11 20.01 21.98 27.30 0.0 953.16 -31062 -28774 -31885 -24213 -43751 -44294 -37975 -36434 -23068 -22244 -18373 -18469 -16953 -4938 -7332 -378 -4677 1705 -2119 -3132 -1949 -1634 -1250 -6172 -3939 -7065 -7094 -5423 -5757 26 1284 2738 -1786 -4109 -2254 -1811 -1250 -718 -780 -2313 -2640 -1968 -1449 575 494 654 125 431 2112 2254 2467 2044 2434 1688 1216 332 -548 -96 -230 2183 2189 2163 1578 -96 426 1415 2003 2163 794 -182 -327 -333 -391 -665 -514 -548 -354 96 -307 -911 -1289 -1903 -1355 -512 -157 -134 -102 257 311 170 343 1120 1282 824 170 348 444 -727 -1533 -1192 -388 953 659 -1217 -2039 -1463 -377 579 684 237 -244 -52 201 561 1354 1532 1140 630 -428 -757 -295 358 56 -125 -434 479 1522 821 -425 -588 -591 195 183 -92 -420 -134 250 -202 -527 -305 -7 745 -510 -506 -581 -382 -787 -816 -735 -790 -473 -471 -398 -468 -528 -169 -306 -17 -235 87 -119 -185 -115 -97 -78 -437 -290 -546 -538 -396 -428 2 114 277 -205 -480 -251 -209 -166 -105 -137 -467 -581 -454 -343 136 119 159 31 109 544 621 747 682 870 641 483 137 -230 -40 -94 881 948 957 778 -51 224 699 966 1110 468 -121 -232 -239 -272 -432 -303 -294 -182 52 -190 -658 -979 -1598 -1210 -482 -146 -133 -106 266 314 163 328 986 1103 758 165 384 516 -936 -2057 -1527 -481 1071 735 -1460 -2464 -1855 -498 811 982 373 -407 -88 322 844 2035 2259 1633 963 -698 -1269 -484 564 86 -184 -656 685 2153 1259 -688 -980 -1037 352 349 -176 -853 -282 533 -412 -1120 -620 -14 1445 SS 20240614T105859.4Z 8931.457632 121 1 29.99 2 71.92 74.63 135.44 359.55 0.00 1 0.00 1 0 25 6.856e-02 8.123e-03 1.169e-02 8.697e-04 4.652035e-01 4.617915e-04 5.504978e-03 -6.000000e+00 4.080782e-02 232.94 -2.00 3.54 -2.00 319.45 0.00e+00 2.778631e-03 1.260790e-04 7.703950e-04 -6.000000e+00 1.787052e-03 285.52 -2.00 20.00 -2.00 318.73 0.00e+00 3.179 0.001 302.00 328.00 3 1.2872e+00 1.3147e-03 4.0545e-02 -6.0000e+00 1.0254e-01 4.8143e-03 1.5362e-03 2.5062e-02 -6.0000e+00 1.1064e-01 -4.0449e-02 1.1837e-03 1.2709e-02 -6.0000e+00 6.5704e-02 8.2960e-03 6.1884e-04 4.2819e-03 -6.0000e+00 2.7857e-02 3.5486e-03 -3.8681e-04 2.5656e-05 4.7760e-05 -6.0000e+00 1.9327e-03 6.8678e-03 0.0000e+00 11 8 0 10 0 0 -6.94 22.00 0.39 0.00687 0.00396 245 245 1 5 0 122.350 26.11 20.00 22.00 27.84 0.0 955.56 -25073 -23815 -15167 -24442 -16419 -33291 -24977 -19519 -25840 -10600 -24155 -7614 -15115 -2765 -5636 -3119 1262 -1634 3854 -2145 740 139 -1740 -920 -4567 -2111 -5194 -2790 -2396 330 1344 -201 -1016 -4764 -1656 -1910 -1136 -125 -2817 -1491 -1993 -995 -917 -185 1083 -203 1056 26 1728 2177 1843 2107 983 1689 954 337 -535 -409 728 1211 2691 2062 1732 87 -242 1172 1616 2390 713 100 -388 -599 -434 -916 -159 -601 -121 214 -563 -909 -1565 -1643 -1461 -488 -203 -87 -216 151 357 207 578 1074 1251 1177 146 417 386 -682 -1544 -1413 -404 846 870 -1286 -2140 -1348 -502 619 554 339 -309 -63 216 626 1451 1462 1262 518 -480 -821 -491 373 -12 75 -440 670 1836 925 -349 -875 -368 172 200 -5 -436 -15 160 -133 -625 -416 -36 767 -544 -555 -324 -535 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