File name: Pandora153s1_LynnMA_20210608_L2Fit_fout2c1d20210519p1-8.txt File generation date: 20260323T024727.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Jeff Geddes Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 153 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora153_OF_v2d20200209.txt Instrument calibration file used: Pandora153s1_CF_v1d20210519.txt Level 1 file used: Pandora153s1_LynnMA_20210608_L1_smca1c1d20210519p1-8.txt.bz2 Full location name: Lynn Massachusetts Department of Environmental Protection Short location name: LynnMA Country of location: United States Location latitude [deg]: 42.4746 Location longitude [deg]: -70.9708 Location altitude [m]: 52 Local noon date: 20210608 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 231 373 Nominal wavelengths inside fitting window [nm]: 305.0497 305.1907 305.3316 305.4726 305.6135 305.7544 305.8953 306.0362 306.1771 306.3179 306.4588 306.5997 306.7405 306.8813 307.0221 307.1629 307.3037 307.4445 307.5853 307.7261 307.8668 308.0075 308.1483 308.2890 308.4297 308.5704 308.7111 308.8517 308.9924 309.1331 309.2737 309.4143 309.5549 309.6955 309.8361 309.9767 310.1173 310.2578 310.3984 310.5389 310.6795 310.8200 310.9605 311.1010 311.2415 311.3819 311.5224 311.6628 311.8033 311.9437 312.0841 312.2245 312.3649 312.5053 312.6456 312.7860 312.9264 313.0667 313.2070 313.3473 313.4876 313.6279 313.7682 313.9085 314.0487 314.1890 314.3292 314.4694 314.6096 314.7498 314.8900 315.0302 315.1704 315.3105 315.4507 315.5908 315.7309 315.8710 316.0111 316.1512 316.2913 316.4314 316.5714 316.7115 316.8515 316.9915 317.1315 317.2715 317.4115 317.5515 317.6914 317.8314 317.9713 318.1112 318.2512 318.3911 318.5310 318.6708 318.8107 318.9506 319.0904 319.2303 319.3701 319.5099 319.6497 319.7895 319.9293 320.0690 320.2088 320.3485 320.4883 320.6280 320.7677 320.9074 321.0471 321.1868 321.3264 321.4661 321.6057 321.7454 321.8850 322.0246 322.1642 322.3038 322.4433 322.5829 322.7225 322.8620 323.0015 323.1410 323.2805 323.4200 323.5595 323.6990 323.8384 323.9779 324.1173 324.2567 324.3962 324.5356 324.6749 324.8143 324.9537 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210608T112603.3Z 7829.476427 848 1 48.87 2 67.08 79.32 54.34 98.77 0.00 1 0.00 1 0 17 4.776e-02 7.208e-03 4.081e-02 5.523e-03 3.403262e-01 2.866458e-03 3.985932e-03 -6.000000e+00 2.814091e-02 232.50 -2.00 3.54 -2.00 319.04 0.00e+00 8.781029e-04 6.587471e-04 3.981722e-04 -6.000000e+00 1.233932e-03 284.82 -2.00 20.00 -2.00 318.26 0.00e+00 2.547 0.000 302.00 328.00 3 4.9552e+00 7.9787e-03 3.1239e-02 -6.0000e+00 7.0646e-02 7.8278e-02 9.1745e-03 1.8092e-02 -6.0000e+00 7.6410e-02 -1.9504e-02 6.2972e-03 8.8182e-03 -6.0000e+00 4.5410e-02 2.5408e-04 3.2418e-03 2.4936e-03 -6.0000e+00 1.8989e-02 1.8828e-04 -2.4156e-04 1.6960e-04 2.8697e-05 -6.0000e+00 1.3487e-03 2.1105e-03 -2.2383e-05 11 8 0 10 0 0 86.33 18.50 0.26 0.00211 0.00030 13 2 1 5 0 3757.070 21.69 15.01 18.50 34.65 33.6 1010.58 17088 -6154 -16373 -18220 494 -7537 -14825 -31568 3406 1369 -5831 -13041 7394 809 -4134 984 10277 1633 2555 5222 -3701 2654 5963 4073 8806 540 -1221 -6454 -4387 2303 -1876 4393 -2321 6323 -3517 -1004 -7971 2923 3163 51 -1607 -2103 -1773 330 246 -1112 -901 -1131 1147 -678 520 309 1809 649 1251 1572 -1634 -580 1318 508 1089 1464 1687 785 348 -2216 -122 -1263 1722 129 881 1050 684 548 -903 1691 -1188 871 -2311 -914 -1054 -662 -1722 -1094 301 -588 942 22 661 676 673 335 -575 582 -720 634 231 921 -67 -126 -419 -1174 -159 -1291 -1076 -1158 -847 -648 18 657 78 513 77 4 -688 473 -99 433 567 171 -72 -2 883 275 662 -474 344 980 125 146 -551 -698 -152 268 -5 -198 71 194 -31 116 302 -459 -443 552 -280 -858 -928 19 -329 -668 -1886 160 70 -323 -811 427 59 -366 93 946 173 281 583 -462 311 692 511 1117 78 -179 -948 -597 293 -268 652 -403 1046 -613 -184 -1549 595 773 15 -533 -739 -642 119 89 -408 -326 -405 399 -245 197 127 781 300 598 768 -840 -294 643 248 545 786 989 498 224 -1373 -77 -790 1118 88 649 807 526 405 -691 1136 -748 518 -1497 -661 -864 -545 -1538 -1024 297 -626 1040 25 754 742 685 314 -554 544 -726 637 261 1148 -89 -167 -522 -1352 -189 -1440 -1291 -1471 -1124 -902 26 1027 130 867 128 7 -992 637 -134 607 847 271 -117 -3 1352 406 927 -639 485 1391 175 220 -887 -1164 -259 474 -9 -391 145 401 -65 234 582 -857 -810 SS 20210608T115516.2Z 7829.496715 901 1 52.13 2 61.75 83.87 49.12 104.33 0.00 1 0.00 1 0 17 1.561e-02 5.945e-03 1.569e-02 3.612e-03 2.837766e-01 1.869541e-03 3.367903e-03 -6.000000e+00 9.197248e-03 232.51 -2.00 3.54 -2.00 318.02 0.00e+00 8.470080e-04 3.202591e-04 1.640116e-04 -6.000000e+00 4.033482e-04 284.82 -2.00 20.00 -2.00 317.21 0.00e+00 2.102 0.000 302.00 328.00 3 5.0595e+00 5.0565e-03 2.5867e-02 -6.0000e+00 2.3089e-02 7.5325e-02 5.7099e-03 1.5032e-02 -6.0000e+00 2.4974e-02 -1.5477e-02 3.5443e-03 7.2891e-03 -6.0000e+00 1.4842e-02 -5.4019e-04 1.7652e-03 2.0768e-03 -6.0000e+00 6.2054e-03 2.8456e-04 -3.1249e-04 1.0970e-04 2.3518e-05 -6.0000e+00 4.4086e-04 3.0890e-03 -2.2255e-05 10 0 0 10 0 0 99.76 18.49 0.30 0.00309 0.00074 15 3 1 5 0 3474.350 21.69 15.00 18.49 34.09 34.0 1010.68 8742 -5647 3351 6738 -1651 2327 -1339 -2097 -937 -2755 -520 -2585 -4954 -2592 -130 155 -2238 -1675 1388 -359 879 -482 1056 -119 -440 -1392 -1566 464 -2196 3757 932 1761 947 -695 -2833 -527 -924 -1966 -232 -582 -1546 1107 -111 -578 -1694 629 -122 -1007 -1711 500 463 -411 730 497 139 814 1092 333 1462 90 844 992 1874 1718 328 -184 634 -443 162 760 470 234 786 95 -178 -108 -503 -473 -900 -1312 -902 -1375 -1780 -922 -470 -509 84 283 241 514 361 467 -637 75 232 425 542 769 152 -533 28 -1242 -451 226 -898 -1029 -1104 -720 -37 483 526 178 -16 173 -634 -166 45 -174 516 -5 -278 227 696 718 845 21 61 1014 111 50 -253 -255 115 226 80 -169 265 481 -229 16 -266 -238 -796 607 -454 279 513 -123 158 -99 -174 -85 -270 -50 -260 -572 -338 -19 25 -389 -302 253 -69 170 -94 207 -25 -97 -322 -362 99 -454 723 195 398 234 -180 -710 -126 -241 -602 -83 -245 -722 529 -55 -293 -867 314 -60 -492 -828 239 233 -224 417 300 87 517 702 215 916 57 545 686 1396 1363 263 -139 441 -305 118 618 419 199 663 86 -149 -81 -345 -310 -619 -1017 -783 -1325 -1675 -904 -490 -569 99 340 290 594 387 503 -638 73 237 477 616 964 202 -706 34 -1432 -538 251 -1085 -1317 -1481 -1009 -54 751 860 296 -26 259 -881 -216 59 -235 742 -8 -437 351 1040 1028 1147 28 83 1384 148 72 -383 -397 182 373 140 -310 498 922 -444 31 -483 -417 -1372 SS 20210608T115730.9Z 7829.498274 903 1 50.71 2 61.34 84.23 48.73 104.78 0.00 1 0.00 1 0 25 1.240e-02 5.811e-03 1.496e-02 3.510e-03 2.817284e-01 1.814712e-03 3.362133e-03 -6.000000e+00 7.304731e-03 232.51 -2.00 3.54 -2.00 317.99 0.00e+00 1.611442e-04 3.071428e-04 1.845389e-04 -6.000000e+00 3.202742e-04 284.82 -2.00 20.00 -2.00 317.18 0.00e+00 2.075 0.000 302.00 328.00 3 4.9981e+00 4.9053e-03 2.5609e-02 -6.0000e+00 1.8338e-02 6.9042e-02 5.5379e-03 1.4972e-02 -6.0000e+00 1.9834e-02 -1.2643e-02 3.4303e-03 7.2377e-03 -6.0000e+00 1.1787e-02 -1.1499e-03 1.7063e-03 1.9794e-03 -6.0000e+00 4.9293e-03 3.1308e-04 -1.1301e-04 1.0686e-04 2.3628e-05 -6.0000e+00 3.5004e-04 1.6426e-03 -2.1520e-05 10 0 0 10 0 0 -17.40 18.49 0.23 0.00164 0.00079 16 3 1 5 0 3168.840 21.69 15.01 18.49 34.17 34.1 1010.97 -2917 1687 -1182 -1551 -3308 -2104 -2980 -3472 -1433 129 265 -27 2193 -79 234 -136 -1758 -2676 3739 -249 1404 -862 -972 1111 -877 -126 -1610 -1665 -3894 1806 4929 2374 -36 -2527 -3087 -1759 -1417 -345 -934 -230 -892 -763 -203 76 404 228 -674 28 -1678 -41 -10 -262 578 1259 1132 602 544 262 659 475 624 990 1965 1658 561 -296 -762 325 1416 575 -249 530 909 216 -122 -38 -910 -310 430 -1278 -1098 -1697 -1286 -1089 -886 -890 -229 274 614 491 397 287 -816 60 404 1 754 145 375 -435 -498 -379 -718 -660 -1129 -898 -683 -318 243 672 491 548 214 -104 -150 40 -26 -239 -20 -128 -467 282 662 402 26 511 -9 884 297 234 152 -420 186 341 47 -156 362 111 94 -452 13 -366 -634 -211 128 -95 -130 -254 -152 -229 -300 -135 13 26 -3 242 -10 35 -22 -309 -494 675 -48 274 -171 -198 234 -199 -29 -381 -373 -835 360 1006 540 -9 -672 -784 -432 -375 -105 -344 -98 -421 -377 -103 39 205 116 -339 14 -819 -20 -5 -144 333 760 708 387 356 171 420 302 408 691 1473 1326 453 -225 -541 223 1023 471 -204 452 770 196 -103 -29 -632 -204 293 -995 -960 -1648 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