File name: Pandora153s1_LynnMA_20210623_L2Fit_fout2c1d20210519p1-8.txt File generation date: 20260323T025026.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Jeff Geddes Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 153 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora153_OF_v2d20200209.txt Instrument calibration file used: Pandora153s1_CF_v1d20210519.txt Level 1 file used: Pandora153s1_LynnMA_20210623_L1_smca1c1d20210519p1-8.txt.bz2 Full location name: Lynn Massachusetts Department of Environmental Protection Short location name: LynnMA Country of location: United States Location latitude [deg]: 42.4746 Location longitude [deg]: -70.9708 Location altitude [m]: 52 Local noon date: 20210623 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 231 373 Nominal wavelengths inside fitting window [nm]: 305.0497 305.1907 305.3316 305.4726 305.6135 305.7544 305.8953 306.0362 306.1771 306.3179 306.4588 306.5997 306.7405 306.8813 307.0221 307.1629 307.3037 307.4445 307.5853 307.7261 307.8668 308.0075 308.1483 308.2890 308.4297 308.5704 308.7111 308.8517 308.9924 309.1331 309.2737 309.4143 309.5549 309.6955 309.8361 309.9767 310.1173 310.2578 310.3984 310.5389 310.6795 310.8200 310.9605 311.1010 311.2415 311.3819 311.5224 311.6628 311.8033 311.9437 312.0841 312.2245 312.3649 312.5053 312.6456 312.7860 312.9264 313.0667 313.2070 313.3473 313.4876 313.6279 313.7682 313.9085 314.0487 314.1890 314.3292 314.4694 314.6096 314.7498 314.8900 315.0302 315.1704 315.3105 315.4507 315.5908 315.7309 315.8710 316.0111 316.1512 316.2913 316.4314 316.5714 316.7115 316.8515 316.9915 317.1315 317.2715 317.4115 317.5515 317.6914 317.8314 317.9713 318.1112 318.2512 318.3911 318.5310 318.6708 318.8107 318.9506 319.0904 319.2303 319.3701 319.5099 319.6497 319.7895 319.9293 320.0690 320.2088 320.3485 320.4883 320.6280 320.7677 320.9074 321.0471 321.1868 321.3264 321.4661 321.6057 321.7454 321.8850 322.0246 322.1642 322.3038 322.4433 322.5829 322.7225 322.8620 323.0015 323.1410 323.2805 323.4200 323.5595 323.6990 323.8384 323.9779 324.1173 324.2567 324.3962 324.5356 324.6749 324.8143 324.9537 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210623T103236.2Z 7844.439308 216 1 18.03 2 76.81 70.20 118.17 263.34 0.00 1 0.00 1 0 17 2.121e-01 7.558e-03 1.553e-01 4.700e-03 5.688471e-01 2.507446e-03 6.485482e-03 -6.000000e+00 1.253171e-01 232.96 -2.00 3.54 -2.00 320.45 0.00e+00 2.154197e-03 9.571467e-04 7.731585e-04 -6.000000e+00 5.513678e-03 286.26 -2.00 20.00 -2.00 319.77 0.00e+00 4.269 0.001 302.00 328.00 3 2.2978e+00 7.7555e-03 5.2503e-02 -6.0000e+00 3.1482e-01 1.0894e-01 9.7261e-03 3.0813e-02 -6.0000e+00 3.4019e-01 -4.7011e-02 8.6619e-03 1.5582e-02 -6.0000e+00 2.0229e-01 4.1156e-03 4.3384e-03 4.9514e-03 -6.0000e+00 8.4713e-02 3.8519e-04 -7.0502e-04 1.3774e-04 5.7668e-05 -6.0000e+00 5.9903e-03 -3.8085e-03 -8.8722e-06 12 9 1 12 1 1 99.98 18.83 0.33 -0.00381 -0.00911 18 10 1 5 0 939.470 21.88 15.00 18.83 21.24 32.3 1010.74 -97300 -34460 -47414 16208 -104081 -62954 -24097 -95017 -38917 -97417 -25037 -60693 1338 -31950 -47738 -11349 -28494 1377 -34338 -1837 -33372 -19323 -11636 -9410 -5863 -15114 -6126 -2384 -7666 -9437 11700 -2781 3704 -3427 -9938 2838 -5572 -565 -7547 8958 3690 690 1278 2217 5272 1138 6409 3688 6819 -2240 2443 582 4381 1010 698 2453 489 648 -1524 3106 2043 -325 2530 2745 70 -800 711 -854 2553 1114 1351 874 1642 -276 -358 -1847 -2215 -790 -2450 533 -348 -1619 -2391 -1690 -503 -1236 -109 -244 437 220 1606 -38 -8 919 -44 616 429 1488 159 -323 -492 -396 -103 -465 -988 -1508 -602 -1121 0 150 495 -9 72 -145 -271 423 45 599 362 -46 -166 12 585 343 1032 54 196 930 351 -133 -508 -269 -173 -244 54 -433 -93 609 162 -75 -64 -203 -261 -1204 -269 -456 82 -1622 -635 -177 -1611 -428 -2099 -275 -1057 15 -644 -1400 -276 -927 37 -1417 -58 -1499 -762 -443 -380 -247 -741 -281 -103 -341 -450 520 -168 241 -258 -779 194 -452 -47 -821 989 486 101 195 345 808 185 1007 609 1128 -429 491 133 1050 271 199 717 150 199 -468 898 615 -109 929 1116 28 -344 293 -364 1147 532 711 485 901 -147 -176 -903 -1006 -351 -1213 273 -209 -1118 -1820 -1358 -426 -1128 -104 -239 425 207 1392 -31 -6 716 -38 603 445 1733 203 -415 -597 -436 -113 -515 -1086 -1767 -737 -1467 0 216 772 -16 117 -227 -401 640 68 943 563 -76 -271 19 890 543 1551 79 276 1337 561 -221 -918 -514 -344 -479 113 -956 -211 1388 371 -165 -135 -404 -541 SS 20210623T104201.2Z 7844.445847 219 1 25.82 2 75.17 71.64 119.82 264.75 0.00 1 0.00 1 0 17 1.651e-01 6.276e-03 5.558e-02 3.000e-03 5.157094e-01 1.579573e-03 5.941105e-03 -6.000000e+00 9.752310e-02 232.96 -2.00 3.54 -2.00 320.12 0.00e+00 2.004011e-03 5.368673e-04 7.276444e-04 -6.000000e+00 4.291546e-03 286.26 -2.00 20.00 -2.00 319.40 0.00e+00 3.827 0.001 302.00 328.00 3 2.2668e+00 4.7402e-03 4.7234e-02 -6.0000e+00 2.4499e-01 9.8995e-02 5.7697e-03 2.7813e-02 -6.0000e+00 2.6476e-01 -5.6076e-02 4.8133e-03 1.3907e-02 -6.0000e+00 1.5743e-01 1.0306e-02 2.4486e-03 4.3236e-03 -6.0000e+00 6.5914e-02 6.4719e-04 -5.0371e-04 8.8654e-05 5.0084e-05 -6.0000e+00 4.6626e-03 -2.6984e-03 -1.6175e-05 12 1 1 12 1 1 99.59 18.83 0.33 -0.00270 -0.00648 34 13 1 5 0 732.480 21.88 15.00 18.83 21.49 31.9 1010.75 -65779 -57537 -47134 -72187 -36351 -60348 -60540 -65848 -35963 -61961 -40330 -1305 -16988 -20889 -23512 4619 -16563 -3244 -8346 1447 -5820 -2253 -1563 -7220 -2887 -4274 -3065 -2388 -8614 -7798 -448 7763 -3230 -892 -11984 -1392 -5109 2035 -1021 -1262 1092 -776 1886 -1920 2909 -1051 1747 1440 854 1633 2551 1223 2006 2460 1449 1966 341 942 -298 -117 1448 1673 2495 1907 1281 266 1136 508 1576 336 315 1487 560 834 -335 -474 -1596 -1264 -1439 -1120 -968 -1736 -2039 -1367 -12 -1207 9 442 575 528 93 504 -595 25 -545 194 327 1001 -117 -219 -794 -1163 -96 -101 -905 -1004 -283 -761 -104 227 152 288 35 539 -134 523 101 107 147 -72 -110 256 602 66 372 88 325 889 389 46 -127 -204 -215 104 -101 -206 45 295 -26 -216 41 -377 -154 -1078 -1010 -800 -1542 -500 -1024 -1098 -1426 -652 -1577 -861 -21 -378 -599 -846 147 -727 -136 -396 66 -293 -110 -79 -414 -171 -270 -195 -146 -544 -509 -31 570 -273 -79 -1144 -130 -491 214 -135 -199 189 -147 364 -394 576 -220 359 301 184 366 617 331 585 769 483 676 122 336 -105 -41 513 643 1062 899 630 128 522 238 791 178 185 902 342 484 -181 -253 -793 -617 -765 -687 -627 -1279 -1641 -1158 -11 -1166 9 456 592 525 87 433 -488 21 -489 196 348 1193 -152 -284 -975 -1305 -107 -114 -1020 -1200 -354 -1014 -148 353 238 472 57 830 -209 775 151 166 243 -115 -177 401 978 104 558 127 451 1259 608 74 -221 -374 -410 209 -201 -432 97 643 -56 -459 83 -774 -308 SS 20210623T105118.4Z 7844.452296 222 1 7.40 2 73.53 73.07 121.45 266.16 0.00 1 0.00 1 0 17 8.937e-02 6.631e-03 4.419e-02 3.483e-03 4.744185e-01 1.818537e-03 5.505129e-03 -6.000000e+00 5.280811e-02 232.96 -2.00 3.54 -2.00 319.33 0.00e+00 1.194967e-03 4.850798e-04 3.514999e-04 -6.000000e+00 2.322668e-03 286.26 -2.00 20.00 -2.00 318.58 0.00e+00 3.470 0.001 302.00 328.00 3 2.0743e+00 5.1422e-03 4.2989e-02 -6.0000e+00 1.3266e-01 7.0167e-02 6.0144e-03 2.5363e-02 -6.0000e+00 1.4334e-01 -3.0006e-02 4.5794e-03 1.2391e-02 -6.0000e+00 8.5238e-02 2.1548e-03 2.3892e-03 3.6411e-03 -6.0000e+00 3.5708e-02 1.1651e-03 -6.6109e-05 1.0146e-04 3.9437e-05 -6.0000e+00 2.5232e-03 -4.6970e-03 4.5386e-05 12 9 1 12 1 1 69.08 18.84 0.18 -0.00470 -0.00519 12 17 1 5 0 555.090 21.88 15.00 18.84 21.41 31.8 1010.95 -28465 -22999 -34716 -21647 -50163 -2652 -48033 -7079 -37699 579 -22224 -7170 -19247 -9929 -2054 -2660 10659 -5549 6521 -434 6603 1668 -1623 3417 -5637 1313 -7399 3798 -1612 -2165 2070 1061 -1408 -1998 321 -7181 -2610 -3481 -306 -538 -302 915 -2073 2107 -1405 2451 -1248 674 -1174 -5 1573 1013 1829 -183 1683 1175 1689 -278 166 -402 1509 1202 1856 1869 189 774 605 362 1359 745 776 69 656 -331 -218 -781 -893 -583 -716 -580 -1617 -874 -2307 -893 -1575 -811 -404 426 690 756 476 530 -21 552 -30 178 1121 825 122 -273 -1157 -910 -242 650 -677 -1514 -699 -730 80 65 -90 73 450 213 226 422 766 100 267 -462 -441 148 458 521 -18 532 306 882 369 237 -1 -254 -9 -183 -29 -327 -47 289 -108 -72 -328 -221 -2 -619 -547 -990 -529 -1499 -48 -1452 -161 -1319 15 -747 -224 -804 -462 -107 -147 626 -377 421 -32 463 124 -129 278 -540 124 -772 342 -148 -205 210 125 -191 -290 44 -1049 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