File name: Pandora153s1_LynnMA_20210802_L2Fit_fout2c1d20210519p1-8.txt File generation date: 20260323T025511.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Jeff Geddes Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 153 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora153_OF_v2d20200209.txt Instrument calibration file used: Pandora153s1_CF_v1d20210519.txt Level 1 file used: Pandora153s1_LynnMA_20210802_L1_smca1c1d20210519p1-8.txt.bz2 Full location name: Lynn Massachusetts Department of Environmental Protection Short location name: LynnMA Country of location: United States Location latitude [deg]: 42.4746 Location longitude [deg]: -70.9708 Location altitude [m]: 52 Local noon date: 20210802 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 231 373 Nominal wavelengths inside fitting window [nm]: 305.0497 305.1907 305.3316 305.4726 305.6135 305.7544 305.8953 306.0362 306.1771 306.3179 306.4588 306.5997 306.7405 306.8813 307.0221 307.1629 307.3037 307.4445 307.5853 307.7261 307.8668 308.0075 308.1483 308.2890 308.4297 308.5704 308.7111 308.8517 308.9924 309.1331 309.2737 309.4143 309.5549 309.6955 309.8361 309.9767 310.1173 310.2578 310.3984 310.5389 310.6795 310.8200 310.9605 311.1010 311.2415 311.3819 311.5224 311.6628 311.8033 311.9437 312.0841 312.2245 312.3649 312.5053 312.6456 312.7860 312.9264 313.0667 313.2070 313.3473 313.4876 313.6279 313.7682 313.9085 314.0487 314.1890 314.3292 314.4694 314.6096 314.7498 314.8900 315.0302 315.1704 315.3105 315.4507 315.5908 315.7309 315.8710 316.0111 316.1512 316.2913 316.4314 316.5714 316.7115 316.8515 316.9915 317.1315 317.2715 317.4115 317.5515 317.6914 317.8314 317.9713 318.1112 318.2512 318.3911 318.5310 318.6708 318.8107 318.9506 319.0904 319.2303 319.3701 319.5099 319.6497 319.7895 319.9293 320.0690 320.2088 320.3485 320.4883 320.6280 320.7677 320.9074 321.0471 321.1868 321.3264 321.4661 321.6057 321.7454 321.8850 322.0246 322.1642 322.3038 322.4433 322.5829 322.7225 322.8620 323.0015 323.1410 323.2805 323.4200 323.5595 323.6990 323.8384 323.9779 324.1173 324.2567 324.3962 324.5356 324.6749 324.8143 324.9537 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20210802T141140.6Z 7884.591442 2229 1 50.65 2 41.78 114.17 35.85 241.03 0.00 1 0.00 1 0 17 8.699e-03 6.033e-03 3.067e-04 1.597e-04 1.972547e-01 8.286451e-05 2.386480e-03 -6.000000e+00 5.128079e-03 232.38 -2.00 3.54 -2.00 316.04 0.00e+00 3.306894e-04 8.956657e-06 3.162942e-05 -6.000000e+00 2.284653e-04 288.72 -2.00 20.00 -2.00 315.27 0.00e+00 1.339 0.000 302.00 328.00 3 2.9298e-01 2.1682e-04 1.7033e-02 -6.0000e+00 1.2853e-02 2.7357e-02 2.4158e-04 1.0409e-02 -6.0000e+00 1.3889e-02 -4.9596e-03 1.3798e-04 5.0313e-03 -6.0000e+00 8.2756e-03 -2.6082e-03 6.2446e-05 1.3808e-03 -6.0000e+00 3.4781e-03 8.3201e-02 -4.9219e-05 4.6952e-06 1.7459e-05 -6.0000e+00 2.4564e-04 -3.0857e-03 -9.8301e-06 10 0 0 10 0 0 12.13 18.66 0.30 -0.00309 -0.00346 2018 382 1 5 0 24.500 21.79 15.01 18.66 33.21 34.9 1004.14 -496 -1278 -1462 -3380 -3168 -1784 -891 319 -9 -1241 -2057 -1056 -503 -160 386 -142 -149 367 711 971 414 468 1461 1197 987 778 44 -315 139 945 1479 1820 1607 -863 -2185 -1483 -1570 -719 -143 -627 -971 -767 -651 -605 -113 -280 -500 -313 -588 192 721 652 952 876 657 910 611 113 334 512 959 1250 1496 1152 -198 -401 -354 -133 955 462 88 136 71 259 29 -123 -94 -137 217 -480 -1020 -1438 -2080 -1497 -1000 -800 -440 -73 88 53 293 179 247 808 689 380 686 650 -139 -407 -413 -627 11 275 -700 -1069 -711 -748 -167 297 224 114 71 92 67 404 457 367 320 -116 -340 -6 340 377 681 501 662 1340 673 294 45 -166 56 217 -26 -243 39 120 -224 -270 -298 -470 -549 -105 -296 -345 -763 -635 -332 -170 67 -2 -306 -505 -258 -133 -47 127 -51 -56 139 277 388 169 190 594 509 400 326 19 -137 56 363 583 759 715 -402 -973 -637 -725 -346 -82 -416 -647 -532 -463 -433 -80 -198 -345 -227 -415 134 517 496 697 671 518 728 496 92 267 406 779 1079 1386 1127 -195 -365 -295 -107 794 432 91 135 71 270 29 -108 -74 -111 181 -408 -973 -1511 -2163 -1624 -1152 -987 -531 -91 109 64 350 194 264 822 730 407 809 842 -178 -515 -529 -745 12 319 -884 -1437 -924 -1015 -235 439 324 166 106 127 92 514 578 483 420 -163 -494 -8 476 505 929 651 815 1635 871 405 60 -228 78 313 -39 -389 60 189 -356 -420 -481 -735 -844 SU 20210802T141453.2Z 7884.593671 2232 1 50.61 2 41.24 114.99 36.35 241.95 0.00 1 0.00 1 0 17 8.283e-03 5.986e-03 2.961e-04 1.556e-04 1.959047e-01 8.093016e-05 2.377537e-03 -6.000000e+00 4.883332e-03 232.38 -2.00 3.54 -2.00 316.01 0.00e+00 2.711904e-04 8.672077e-06 2.924515e-05 -6.000000e+00 2.175374e-04 288.72 -2.00 20.00 -2.00 315.25 0.00e+00 1.328 0.000 302.00 328.00 3 2.4981e-01 2.1169e-04 1.6912e-02 -6.0000e+00 1.2239e-02 2.6533e-02 2.3570e-04 1.0349e-02 -6.0000e+00 1.3226e-02 -6.0226e-03 1.3451e-04 5.0089e-03 -6.0000e+00 7.8804e-03 1.2547e-05 6.0789e-05 1.3740e-03 -6.0000e+00 3.3125e-03 8.8044e-02 -8.6687e-05 4.5757e-06 1.7442e-05 -6.0000e+00 2.3389e-04 -3.9822e-03 -1.0710e-05 10 0 0 10 0 0 88.57 18.67 0.30 -0.00398 -0.00463 2147 406 1 5 0 23.000 21.79 15.01 18.67 33.19 34.9 1004.20 -299 -798 -1228 -2954 -2987 -1477 -559 590 249 -1024 -1621 -612 -152 -34 627 -41 52 386 788 1057 459 510 1450 1111 990 799 4 -302 49 885 1430 1648 1465 -1065 -2192 -1498 -1597 -783 -314 -764 -1144 -867 -790 -720 -296 -424 -697 -468 -701 51 625 502 841 766 560 862 603 135 345 530 986 1261 1442 1147 -239 -354 -230 -9 1105 574 120 212 130 296 121 -6 48 36 374 -372 -908 -1327 -2002 -1380 -939 -722 -385 -63 114 99 314 233 337 900 734 367 656 629 -190 -457 -460 -598 28 277 -760 -1134 -775 -806 -174 191 129 17 17 47 66 435 447 356 306 -164 -416 -36 286 318 641 508 726 1385 698 301 67 -132 93 236 5 -215 26 137 -217 -229 -291 -455 -548 -64 -187 -294 -676 -608 -278 -108 125 59 -256 -402 -151 -40 -10 208 -15 20 148 310 426 189 209 594 476 404 337 2 -133 20 343 567 692 656 -499 -981 -646 -740 -378 -179 -509 -766 -604 -564 -517 -211 -300 -483 -341 -495 35 449 383 616 588 442 690 491 110 276 421 801 1088 1337 1122 -235 -322 -191 -7 917 536 123 210 129 308 118 -5 42 29 310 -315 -863 -1390 -2076 -1491 -1079 -887 -463 -78 141 128 374 252 360 912 774 391 770 812 -242 -576 -588 -708 31 320 -957 -1520 -1004 -1090 -245 282 199 26 25 65 90 551 561 467 399 -230 -603 -52 399 425 870 657 889 1680 898 412 90 -180 128 338 8 -343 40 214 -342 -353 -466 -706 -835 SU 20210802T141805.2Z 7884.595894 2235 1 50.69 2 40.71 115.82 36.86 242.84 0.00 1 0.00 1 0 17 8.234e-03 5.721e-03 4.527e-04 2.198e-04 1.941980e-01 1.139808e-04 2.357197e-03 -6.000000e+00 4.856173e-03 232.38 -2.00 3.54 -2.00 316.31 0.00e+00 3.440294e-04 1.293473e-05 3.018303e-05 -6.000000e+00 2.162516e-04 288.72 -2.00 20.00 -2.00 315.50 0.00e+00 1.318 0.000 302.00 328.00 3 7.4861e-01 2.9945e-04 1.6780e-02 -6.0000e+00 1.2171e-02 3.2639e-02 3.3377e-04 1.0280e-02 -6.0000e+00 1.3151e-02 -5.0238e-03 1.9148e-04 4.9750e-03 -6.0000e+00 7.8360e-03 -2.2139e-03 8.7611e-05 1.3762e-03 -6.0000e+00 3.2950e-03 5.4074e-02 2.0036e-04 6.5402e-06 1.7591e-05 -6.0000e+00 2.3248e-04 -4.8662e-03 4.6787e-05 10 0 0 10 0 0 99.99 18.67 0.31 -0.00487 -0.00336 2229 421 1 5 0 22.130 21.79 14.99 18.67 33.15 34.9 1004.31 -489 -1304 -1311 -3335 -2744 -1399 -507 533 27 -1056 -2048 -664 -666 -100 179 -66 -57 346 688 871 516 421 1490 985 886 593 -23 -319 37 983 1289 1810 1379 -921 -2105 -1295 -1488 -658 -162 -701 -952 -795 -601 -630 -123 -295 -561 -376 -585 252 663 672 877 868 591 867 607 153 365 452 1052 1200 1495 1079 -235 -404 -249 -25 1019 466 26 146 -6 265 -32 -159 -82 -143 292 -542 -971 -1451 -2026 -1436 -963 -743 -386 4 131 139 294 254 262 896 646 410 695 656 -103 -450 -391 -601 78 284 -708 -1063 -695 -674 -127 323 212 155 53 105 47 422 419 341 312 -166 -410 -54 244 270 587 409 599 1285 574 248 -25 -178 59 230 18 -204 83 144 -175 -251 -236 -411 -465 -96 -279 -286 -697 -507 -239 -89 102 6 -239 -463 -148 -161 -27 54 -22 -19 120 245 318 193 156 552 382 360 249 -9 -127 14 344 462 685 557 -389 -850 -503 -621 -314 -92 -420 -625 -544 -420 -444 -86 -205 -381 -247 -372 158 428 460 630 652 457 680 483 122 286 351 836 1013 1355 1034 -226 -359 -203 -20 825 425 26 153 -6 269 -31 -137 -63 -114 216 -448 -899 -1482 -2217 -1502 -1070 -883 -482 5 169 173 338 290 272 883 663 460 787 817 -136 -589 -482 -687 92 344 -859 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