File name: Pandora186s1_MadisonCT_20220713_L2Fit_fout2c2d20210922p1-8.txt File generation date: 20251203T182140.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 186 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora186_OF_v4d20210803.txt Instrument calibration file used: Pandora186s1_CF_v2d20210922.txt Level 1 file used: Pandora186s1_MadisonCT_20220713_L1_smca1c2d20210922p1-8.txt Full location name: Madison - Hammonasset State Park CTDEEP (USEPA AQS ID 09-009-9002) Short location name: MadisonCT Country of location: USA Location latitude [deg]: 41.2568 Location longitude [deg]: -72.5533 Location altitude [m]: 3 Local noon date: 20220713 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0092 305.1504 305.2917 305.4329 305.5741 305.7153 305.8565 305.9977 306.1389 306.2800 306.4212 306.5623 306.7034 306.8445 306.9856 307.1267 307.2678 307.4089 307.5499 307.6909 307.8320 307.9730 308.1140 308.2550 308.3960 308.5369 308.6779 308.8189 308.9598 309.1007 309.2416 309.3825 309.5234 309.6643 309.8052 309.9460 310.0869 310.2277 310.3685 310.5093 310.6501 310.7909 310.9317 311.0724 311.2132 311.3539 311.4946 311.6354 311.7761 311.9167 312.0574 312.1981 312.3387 312.4794 312.6200 312.7606 312.9012 313.0418 313.1824 313.3230 313.4636 313.6041 313.7447 313.8852 314.0257 314.1662 314.3067 314.4472 314.5876 314.7281 314.8685 315.0090 315.1494 315.2898 315.4302 315.5706 315.7109 315.8513 315.9917 316.1320 316.2723 316.4126 316.5529 316.6932 316.8335 316.9738 317.1140 317.2543 317.3945 317.5347 317.6749 317.8151 317.9553 318.0955 318.2356 318.3758 318.5159 318.6560 318.7961 318.9362 319.0763 319.2164 319.3565 319.4965 319.6366 319.7766 319.9166 320.0566 320.1966 320.3366 320.4765 320.6165 320.7565 320.8964 321.0363 321.1762 321.3161 321.4560 321.5959 321.7357 321.8756 322.0154 322.1552 322.2950 322.4348 322.5746 322.7144 322.8542 322.9939 323.1337 323.2734 323.4131 323.5528 323.6925 323.8322 323.9719 324.1115 324.2512 324.3908 324.5304 324.6700 324.8096 324.9492 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220713T101340.1Z 8229.426159 203 1 49.81 2 83.31 66.78 104.12 245.96 0.00 1 0.00 1 0 25 6.814e-01 4.320e-02 4.911e-01 3.452e-02 8.764700e-01 2.082610e-02 9.342044e-03 -6.000000e+00 4.286520e-01 232.95 -2.00 3.52 -2.00 322.19 0.00e+00 -1.934989e-02 1.182741e-02 7.125672e-03 -6.000000e+00 2.160120e-02 289.13 -2.00 20.00 -2.00 321.65 0.00e+00 7.802 0.009 302.00 328.00 3 2.2033e+00 8.5249e-02 1.0900e-01 -6.0000e+00 1.0883e+00 1.2248e+00 1.0810e-01 1.0015e-01 -6.0000e+00 1.1884e+00 -1.6538e+00 6.9540e-02 2.7784e-02 -6.0000e+00 6.8926e-01 6.5604e-01 3.2640e-02 1.8018e-02 -6.0000e+00 2.8220e-01 1.0161e-05 2.4166e-03 1.0465e-03 1.8592e-04 -6.0000e+00 2.1930e-02 -2.4709e-03 2.5660e-04 12 8 8 10 0 0 70.05 20.02 1.02 -0.00247 0.01569 16 3 1 5 0 3112.410 22.80 15.00 20.02 28.92 15.7 1087.42 900000 -17934 205356 97346 900000 1506 -45158 900000 -95922 900000 -41487 900000 -59818 900000 -76355 302213 22 39817 900000 -17192 121723 116557 105683 -36177 142661 101135 900000 -55626 240 59251 -21949 -59939 900000 900000 900000 51394 105699 900000 36771 147786 283013 900000 68371 17184 14332 214245 2546 131182 -52272 98152 95355 78347 115185 900000 106712 -3758 93575 47110 120450 40410 36556 -16570 156496 5997 42908 28087 20435 21161 60469 35394 218 16333 14544 37126 4886 111367 -29447 -22890 -13115 8980 -2519 14517 1374 2564 -6727 5491 -58 10709 7343 -5125 6919 -4069 13790 -8019 -8875 -2681 462 -10943 2709 -6131 -872 -5823 1332 -1394 -1808 -1516 7361 -7448 -1004 -376 -1192 6656 176 1471 -5737 -1419 -255 3164 3 -2670 -1681 1036 8955 -642 1398 -239 7206 -3480 380 1371 1661 -1933 986 -2261 3082 -997 1018 700 322 1611 -2568 -680 -1879 900000 -799 6893 3268 900000 51 -1739 900000 -7689 900000 -2153 900000 -4119 900000 -7333 10145 1 1373 900000 -1002 4086 3913 3548 -2631 4789 3395 900000 -4929 11 1989 -1239 -5451 900000 900000 900000 1725 3548 900000 1953 4961 9500 900000 3681 1453 1166 7192 212 4403 -7542 3451 3779 4069 4550 900000 5316 -579 5779 4521 5317 3621 3292 -2606 5253 917 4844 3644 2864 3092 6669 5658 54 3599 3212 6152 1000 7224 -6999 -5198 -3013 1958 -721 4046 484 961 -2949 2264 -26 4470 3144 -2380 2692 -1680 4746 -3634 -4606 -1527 297 -9010 2131 -5330 -684 -4372 861 -923 -1272 -1131 5366 -6812 -964 -410 -1477 8277 240 1972 -8014 -1862 -335 4194 4 -4046 -2486 1434 11080 -848 1759 -298 8308 -4769 571 2333 3145 -4112 2190 -5565 7736 -2729 2793 1941 885 4167 -6457 -1574 -4287 SS 20220713T102437.0Z 8229.433762 206 1 50.48 2 81.41 68.48 105.92 247.50 0.00 1 0.00 1 0 17 5.840e-01 1.717e-02 3.383e-01 8.383e-03 7.820415e-01 4.857495e-03 9.321098e-03 -6.000000e+00 3.520852e-01 232.95 -2.00 3.52 -2.00 322.00 0.00e+00 9.445653e-03 3.025541e-03 6.118377e-03 -6.000000e+00 1.581503e-02 289.13 -2.00 20.00 -2.00 321.46 0.00e+00 6.302 0.005 302.00 328.00 3 1.7790e+00 2.0190e-02 8.0141e-02 -6.0000e+00 8.8301e-01 5.0052e-01 2.7736e-02 5.0566e-02 -6.0000e+00 9.5315e-01 -6.9108e-01 2.4941e-02 2.7257e-02 -6.0000e+00 5.6787e-01 2.7109e-01 1.1333e-02 9.7695e-03 -6.0000e+00 2.3862e-01 7.2602e-05 2.2877e-05 2.5080e-04 2.4114e-04 -6.0000e+00 1.7525e-02 -1.3042e-03 1.5429e-04 12 8 8 10 0 0 89.08 20.03 0.39 -0.00130 -0.00113 62 12 1 5 0 814.090 22.80 15.00 20.03 29.63 15.6 1092.96 900000 -235052 107460 -174431 -19519 -214580 64097 -221378 -189572 -124136 -160018 -96947 -77549 900000 -75470 135560 -96400 42308 -96023 20529 -86363 -11968 -35202 48654 -52294 69583 -43661 249902 -10998 4738 -26299 33486 74158 -38740 75606 -40758 -16425 -14121 30856 16249 47484 20810 62166 24589 44979 34014 24686 30345 25699 44235 18038 43772 21306 37289 2748 27491 11884 21187 4531 11529 12766 16625 17083 6954 15308 2634 12621 351 17608 7949 11535 1755 5307 5994 -251 -2243 5023 128 -3578 3766 860 292 -1016 766 -3588 1687 443 1845 -1500 1716 -1316 -1276 -2320 -2302 -2564 -2423 -207 -408 -623 -764 -689 -2089 -853 -2453 35 -3084 -1254 -1715 -1045 -1508 -349 -315 -1331 -980 -297 61 265 707 482 298 268 2887 1302 1609 573 1995 -214 707 197 243 1906 26 39 -478 -66 -88 469 4 81 -330 -112 -701 -910 900000 -6711 878 -3028 -160 -4676 524 -5329 -3568 -1302 -2458 -891 -733 900000 -1175 1108 -2603 346 -3098 226 -2684 -180 -659 418 -1232 569 -979 2042 -177 71 -629 550 963 -1612 1046 -1670 -560 -534 898 636 1554 945 2005 1174 1803 1550 1268 1537 1437 2228 1287 2726 1806 2937 319 2607 1335 2168 529 1237 1388 1898 2202 1119 2457 483 2107 68 3175 1784 2770 485 1410 1498 -61 -503 986 27 -873 1017 282 111 -434 345 -1792 851 238 1007 -848 915 -682 -625 -1120 -1158 -1455 -1603 -157 -356 -599 -751 -646 -1813 -672 -1933 28 -2735 -1162 -1722 -1154 -1883 -481 -466 -2035 -1470 -428 85 373 1035 743 476 427 4326 1908 2281 794 2650 -286 986 311 433 3697 55 89 -1150 -167 -236 1278 11 222 -879 -282 -1676 -2120 SS 20220713T103831.7Z 8229.443422 211 1 50.58 2 78.96 70.62 108.22 249.44 0.00 1 0.00 1 0 17 4.045e-01 6.082e-03 1.540e-01 2.716e-03 6.576917e-01 1.526311e-03 7.558457e-03 -6.000000e+00 2.438928e-01 232.95 -2.00 3.52 -2.00 321.42 0.00e+00 3.742643e-03 8.265912e-04 3.420224e-03 -6.000000e+00 1.089829e-02 289.13 -2.00 20.00 -2.00 320.83 0.00e+00 5.031 0.002 302.00 328.00 3 1.4814e+00 5.6805e-03 6.3539e-02 -6.0000e+00 6.1174e-01 4.8328e-02 8.0173e-03 4.0865e-02 -6.0000e+00 6.6028e-01 -8.9187e-02 7.8094e-03 2.1689e-02 -6.0000e+00 3.9326e-01 2.7121e-02 3.6123e-03 6.6014e-03 -6.0000e+00 1.6517e-01 4.0076e-04 6.2583e-04 8.2905e-05 1.2041e-04 -6.0000e+00 1.2101e-02 -2.2202e-03 1.7812e-04 10 0 0 10 0 0 15.26 20.00 0.33 -0.00222 0.00248 180 34 1 5 0 280.970 22.71 15.00 20.00 30.56 15.6 1100.00 900000 -114094 -84303 -59307 -145184 -182489 -150542 -111433 -174575 -122862 -124620 -60307 -113371 -77447 -85979 -34444 -56939 -44983 -41816 26670 -16159 2186 -43789 -6454 -36845 -17158 -10789 -28416 -18574 -34049 -749 -21256 19385 -12470 -793 -15998 7752 -2243 2106 2213 4894 1655 1522 3212 -1714 680 -1179 5155 -1521 6093 2887 2896 687 4886 3208 6151 1291 1162 738 -195 774 1463 3359 2643 3099 216 2423 1369 2473 1528 2036 102 2206 714 479 -902 -2499 -1360 -1665 -101 -1229 -216 -1865 -825 -1462 -250 -478 815 546 1014 294 881 -426 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