File name: Pandora186s1_MadisonCT_20220825_L2Fit_fout2c2d20210922p1-8.txt File generation date: 20251203T183308.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 186 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora186_OF_v4d20210803.txt Instrument calibration file used: Pandora186s1_CF_v2d20210922.txt Level 1 file used: Pandora186s1_MadisonCT_20220825_L1_smca1c2d20210922p1-8.txt Full location name: Madison - Hammonasset State Park CTDEEP (USEPA AQS ID 09-009-9002) Short location name: MadisonCT Country of location: USA Location latitude [deg]: 41.2568 Location longitude [deg]: -72.5533 Location altitude [m]: 3 Local noon date: 20220825 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0092 305.1504 305.2917 305.4329 305.5741 305.7153 305.8565 305.9977 306.1389 306.2800 306.4212 306.5623 306.7034 306.8445 306.9856 307.1267 307.2678 307.4089 307.5499 307.6909 307.8320 307.9730 308.1140 308.2550 308.3960 308.5369 308.6779 308.8189 308.9598 309.1007 309.2416 309.3825 309.5234 309.6643 309.8052 309.9460 310.0869 310.2277 310.3685 310.5093 310.6501 310.7909 310.9317 311.0724 311.2132 311.3539 311.4946 311.6354 311.7761 311.9167 312.0574 312.1981 312.3387 312.4794 312.6200 312.7606 312.9012 313.0418 313.1824 313.3230 313.4636 313.6041 313.7447 313.8852 314.0257 314.1662 314.3067 314.4472 314.5876 314.7281 314.8685 315.0090 315.1494 315.2898 315.4302 315.5706 315.7109 315.8513 315.9917 316.1320 316.2723 316.4126 316.5529 316.6932 316.8335 316.9738 317.1140 317.2543 317.3945 317.5347 317.6749 317.8151 317.9553 318.0955 318.2356 318.3758 318.5159 318.6560 318.7961 318.9362 319.0763 319.2164 319.3565 319.4965 319.6366 319.7766 319.9166 320.0566 320.1966 320.3366 320.4765 320.6165 320.7565 320.8964 321.0363 321.1762 321.3161 321.4560 321.5959 321.7357 321.8756 322.0154 322.1552 322.2950 322.4348 322.5746 322.7144 322.8542 322.9939 323.1337 323.2734 323.4131 323.5528 323.6925 323.8322 323.9719 324.1115 324.2512 324.3908 324.5304 324.6700 324.8096 324.9492 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220825T105234.4Z 8272.453176 113 1 51.07 2 82.94 81.97 61.99 84.65 0.00 1 0.00 1 0 25 5.212e-01 2.567e-02 4.428e-01 1.784e-02 8.780523e-01 1.058080e-02 9.506688e-03 -6.000000e+00 3.148419e-01 231.03 -2.00 3.52 -2.00 322.25 0.00e+00 -2.806677e-04 6.885538e-03 2.649011e-03 -6.000000e+00 1.513865e-02 289.34 -2.00 20.00 -2.00 321.75 0.00e+00 7.466 0.008 302.00 328.00 3 1.5547e+00 4.5825e-02 8.9885e-02 -6.0000e+00 7.8640e-01 9.2824e-01 6.1650e-02 5.2150e-02 -6.0000e+00 8.5204e-01 -1.2107e+00 4.8996e-02 2.5824e-02 -6.0000e+00 5.0859e-01 4.7886e-01 2.2047e-02 7.2687e-03 -6.0000e+00 2.1521e-01 2.6456e-05 -1.5999e-04 5.3165e-04 1.1123e-04 -6.0000e+00 1.5795e-02 -8.2200e-04 2.2078e-04 12 8 8 10 0 0 12.31 20.05 0.64 -0.00082 -0.00202 37 7 1 5 0 1379.950 22.80 15.00 20.05 28.72 16.7 1051.61 900000 900000 -159216 900000 30052 129176 -66911 -123196 -20720 -132461 147445 -53377 -99124 -173169 103485 -103494 -58858 900000 -42124 74045 900000 7479 177069 900000 -20662 19547 900000 -84304 -70799 -27127 24465 25443 -8565 54481 105754 12418 35353 63347 29771 51624 53532 134309 147740 38034 29277 125368 32462 -3222 -10000 24448 68119 22733 70596 27705 26366 103593 67825 54257 5399 54818 42242 26604 10374 37489 34758 15573 18503 14978 13055 224 17348 11150 30037 10945 8169 14310 3199 3410 1946 4360 7269 1635 -5954 -284 -4063 1834 637 1127 2223 4912 2607 -571 -190 1282 -4040 -2887 -4047 -1039 -3031 -1895 -2820 -5055 -4967 -6585 -2598 -2480 -3596 -2509 -2608 688 -210 -1604 357 -1339 678 934 1643 -1497 -2530 735 2001 1101 2397 3738 1792 -140 -587 2391 -273 977 1623 1856 338 439 -116 -555 -436 194 139 132 557 -1570 -1928 900000 900000 -6037 900000 522 2245 -1163 -2530 -360 -3348 2562 -928 -2349 -10669 1798 -4578 -1860 900000 -1264 1287 900000 130 3077 900000 -522 340 900000 -3862 -2684 -686 468 575 -284 1136 1838 367 860 1321 1035 1705 1954 2334 2567 1785 1475 2397 1580 -230 -727 1487 2959 1738 3680 2407 2474 4681 4479 4054 571 3715 3230 2543 1316 4104 4228 2327 2701 2369 2104 47 3371 2413 5846 2196 1675 2462 573 622 406 1061 2046 514 -2257 -110 -1733 782 288 520 1011 2103 1075 -253 -83 579 -1991 -1660 -2781 -805 -2648 -1674 -2392 -3977 -3547 -4671 -1863 -1889 -2948 -2212 -2575 753 -263 -2224 502 -1904 915 1226 2162 -2124 -3816 1105 2927 1556 3208 5255 2486 -192 -801 3361 -410 1672 3102 3865 768 1071 -306 -1542 -1241 555 395 357 1394 -3743 -4450 SS 20220825T110326.3Z 8272.460722 116 1 50.69 2 80.92 83.73 60.02 86.32 0.00 1 0.00 1 0 25 5.271e-01 1.145e-02 2.762e-01 4.834e-03 7.210656e-01 2.727744e-03 8.289320e-03 -6.000000e+00 3.168080e-01 231.03 -2.00 3.52 -2.00 321.74 0.00e+00 5.131332e-03 1.626275e-03 3.958679e-03 -6.000000e+00 1.425765e-02 289.34 -2.00 20.00 -2.00 321.18 0.00e+00 6.003 0.004 302.00 328.00 3 1.3461e+00 1.0890e-02 7.3693e-02 -6.0000e+00 7.9256e-01 2.1698e-01 1.5552e-02 4.5173e-02 -6.0000e+00 8.5687e-01 -3.2375e-01 1.4922e-02 2.3692e-02 -6.0000e+00 5.0962e-01 1.2803e-01 6.7730e-03 7.1865e-03 -6.0000e+00 2.1308e-01 1.6984e-04 2.2537e-04 1.4506e-04 1.4593e-04 -6.0000e+00 1.5785e-02 -7.0434e-04 1.8692e-04 12 8 8 10 0 0 1.24 20.05 0.36 -0.00070 0.00099 116 22 1 5 0 436.880 22.80 14.99 20.05 29.68 16.8 1059.43 103667 -234575 -26549 -186014 -126848 -255877 -128791 -133796 900000 -92352 -177585 12614 -178505 112103 -102404 -14967 -49404 -51059 -97714 -74161 -73004 15146 -56596 93354 -40666 -7374 -42059 -78206 -18318 -50952 51655 -23906 11614 -31888 25911 -50227 24607 -9014 16828 -17930 6732 3666 29927 12580 12423 21386 344 11087 6060 8717 5340 13047 3970 17909 5266 12780 8766 13228 2297 8492 6269 6946 9570 3907 9522 2711 9044 2345 8243 1484 6619 1021 3959 1210 1482 -1448 -1076 2018 -552 -1298 -1903 118 -3144 -238 -3368 -283 -920 1766 206 2214 -783 263 -931 -221 -1492 -1195 -249 -748 301 -778 -175 -1278 -479 -2072 -1174 -2514 -1255 -1229 59 -486 327 359 268 535 -365 535 194 705 -50 317 -511 438 -154 1114 -107 724 288 1018 563 941 646 -157 113 -322 -244 -565 194 -50 -37 -224 263 -128 -378 489 -3618 -125 -1992 -707 -4933 -717 -860 900000 -522 -2283 59 -3212 528 -1448 -120 -652 -700 -2344 -1493 -1501 143 -1018 440 -786 -108 -892 -2144 -302 -1249 536 -642 257 -1093 550 -2044 557 -301 579 -953 320 196 1308 679 687 1109 23 684 415 627 442 1124 415 1780 636 1500 1104 1598 303 1037 803 964 1472 720 1787 549 1717 493 1790 394 1855 319 1201 359 403 -366 -253 466 -146 -409 -712 50 -1526 -121 -1882 -164 -564 1087 129 1321 -454 142 -492 -120 -918 -853 -206 -714 312 -828 -176 -1183 -404 -1755 -1042 -2406 -1260 -1330 70 -648 481 566 430 836 -550 774 283 1068 -81 528 -853 701 -238 1646 -155 1000 393 1443 901 1698 1295 -341 238 -728 -590 -1440 504 -132 -96 -568 624 -287 -903 SS 20220825T111416.4Z 8272.468246 121 1 50.46 2 78.89 85.48 58.05 88.01 0.00 1 0.00 1 0 25 3.320e-01 5.123e-03 1.129e-01 2.135e-03 6.224375e-01 1.180466e-03 7.118689e-03 -6.000000e+00 1.986346e-01 231.03 -2.00 3.52 -2.00 321.28 0.00e+00 2.556860e-03 6.126132e-04 2.601640e-03 -6.000000e+00 8.927375e-03 289.34 -2.00 20.00 -2.00 320.66 0.00e+00 5.005 0.002 302.00 328.00 3 1.1667e+00 4.2784e-03 6.1182e-02 -6.0000e+00 4.9581e-01 3.1831e-02 5.9312e-03 3.6884e-02 -6.0000e+00 5.3566e-01 -5.2699e-02 5.6774e-03 1.9162e-02 -6.0000e+00 3.1990e-01 1.1713e-02 2.6579e-03 5.6468e-03 -6.0000e+00 1.3418e-01 5.8818e-04 4.8035e-04 6.5646e-05 9.6188e-05 -6.0000e+00 9.8585e-03 -5.1406e-04 1.7337e-04 10 0 0 10 0 0 4.32 19.97 0.35 -0.00051 0.00310 239 45 1 5 0 211.080 22.71 14.99 19.97 30.72 16.8 1069.53 -153988 -142130 -104850 -117920 -61765 -107084 -86949 -105657 -83150 -72768 -74595 -113838 -74138 -32961 -48998 3260 -33101 9934 -32757 -13524 -11581 -18085 -32351 -2568 -14738 -5987 -31235 -21513 -19133 -22162 -6215 -15402 -786 -12419 -4069 -3053 -4912 -7692 -3740 -3562 -2020 -4513 -1240 120 1660 8735 -2147 2621 2154 3484 1205 2908 5249 3250 1320 2210 286 978 858 1966 888 1900 2574 1670 2617 1332 2503 1380 2000 2436 1112 883 696 22 175 -847 -1421 -2128 -834 -882 -886 -1206 -1390 -1402 -1123 -268 -228 524 -45 534 820 282 144 255 77 132 462 328 -125 -349 -234 -903 -456 -323 -717 -1208 -833 -576 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