File name: Pandora127s1_Mainz-MPIC_20250323_L2Fit_fout2c4d20250305p1-8.txt
File generation date: 20250904T065118.3Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c4p1-8
Local principal investigator: Thomas Wagner
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 127
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora127_OF_v4d20210611.txt
Instrument calibration file used: Pandora127s1_CF_v4d20250305.txt
Level 1 file used: Pandora127s1_Mainz-MPIC_20250323_L1_smca1c4d20250305p1-8.txt
Full location name: Max-Planck-Institute for Chemistry, Mainz
Short location name: Mainz-MPIC
Country of location: Germany
Location latitude [deg]: 49.9910
Location longitude [deg]: 8.2280
Location altitude [m]: 125
Local noon date: 20250323
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 223 365
Nominal wavelengths inside fitting window [nm]: 305.0725 305.2131 305.3536 305.4941 305.6347 305.7752 305.9156 306.0561 306.1966 306.3370 306.4775 306.6179 306.7583 306.8988 307.0392 307.1795 307.3199 307.4603 307.6006 307.7410 307.8813 308.0216 308.1619 308.3022 308.4425 308.5828 308.7230 308.8633 309.0035 309.1438 309.2840 309.4242 309.5644 309.7046 309.8447 309.9849 310.1250 310.2652 310.4053 310.5454 310.6855 310.8256 310.9657 311.1058 311.2458 311.3859 311.5259 311.6659 311.8059 311.9459 312.0859 312.2259 312.3659 312.5058 312.6457 312.7857 312.9256 313.0655 313.2054 313.3453 313.4852 313.6250 313.7649 313.9047 314.0445 314.1844 314.3242 314.4639 314.6037 314.7435 314.8833 315.0230 315.1627 315.3025 315.4422 315.5819 315.7216 315.8612 316.0009 316.1406 316.2802 316.4198 316.5594 316.6991 316.8386 316.9782 317.1178 317.2574 317.3969 317.5365 317.6760 317.8155 317.9550 318.0945 318.2340 318.3734 318.5129 318.6523 318.7918 318.9312 319.0706 319.2100 319.3494 319.4888 319.6281 319.7675 319.9068 320.0461 320.1855 320.3248 320.4641 320.6033 320.7426 320.8819 321.0211 321.1604 321.2996 321.4388 321.5780 321.7172 321.8564 321.9955 322.1347 322.2738 322.4129 322.5521 322.6912 322.8303 322.9693 323.1084 323.2475 323.3865 323.5256 323.6646 323.8036 323.9426 324.0816 324.2206 324.3595 324.4985 324.6374 324.7763 324.9153
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Spectrometer control temperature [°C], 999=no temperature signal
Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 96: Temperature in head sensor [°C], 999=no temperature signal
Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal
Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20250323T090822.8Z 9213.380819 214 1 49.70 2 57.74 135.56 86.90 215.72 0.00 1 0.00 1 0 17 1.306e-02 6.547e-03 8.714e-03 2.236e-03 2.690387e-01 1.103771e-03 3.465674e-03 -6.000000e+00 7.315332e-03 225.87 -2.00 3.76 -2.00 317.85 0.00e+00 5.096926e-04 1.751506e-04 1.509723e-04 -6.000000e+00 3.100453e-04 270.98 -2.00 20.00 -2.00 317.32 0.00e+00 1.867 0.000 302.00 328.00 3 5.0840e+00 2.9256e-03 2.3548e-02 -6.0000e+00 1.8175e-02 9.7415e-03 3.2973e-03 1.4671e-02 -6.0000e+00 1.9790e-02 -3.6308e-03 2.0873e-03 7.3311e-03 -6.0000e+00 1.1721e-02 -3.9834e-03 1.0700e-03 2.1482e-03 -6.0000e+00 4.9972e-03 3.7797e-04 -1.4767e-04 6.3038e-05 2.2275e-05 -6.0000e+00 3.3926e-04 1.2000e-03 0.0000e+00 11 8 0 10 0 0 74.97 25.58 0.19 0.00120 0.00009 21 5 1 8 0 2366.490 20.01 162.77 22.11 25.58 25.47 0.0 962.39 -641 263 -2560 -3499 -2121 -4500 -4610 -235 523 -3259 -3626 -1871 -307 -3027 1621 -2114 -432 1757 2794 790 970 -594 451 757 2320 -1050 -942 -1678 713 -808 477 -247 1716 -3637 -2688 -2149 -2562 -1752 -112 -797 -551 184 -591 -153 360 -484 -417 -229 -41 370 1052 327 1294 609 356 1324 26 523 364 512 1067 1485 2178 2177 460 -336 -691 -821 736 991 273 862 -200 1010 123 -149 -518 -2209 -1142 -1475 -1303 -1609 -2244 -1842 -421 -608 200 26 701 382 838 95 -466 -144 -83 -229 303 1063 223 -3 88 -705 -252 -233 -1006 -971 -754 -999 131 717 772 393 413 -67 -302 -143 -147 -32 175 77 -148 153 782 447 559 -2 -502 604 393 145 220 -461 -243 -175 94 190 146 499 7 -72 -127 -580 -530 -55 24 -247 -318 -169 -355 -389 -21 53 -356 -393 -205 -38 -438 257 -379 -79 331 542 162 202 -124 95 169 540 -262 -234 -396 154 -175 109 -62 455 -1046 -717 -554 -723 -571 -43 -355 -266 92 -305 -79 185 -252 -212 -114 -20 182 543 182 749 372 223 840 17 342 233 324 690 1021 1612 1704 368 -253 -484 -562 526 790 238 782 -182 889 102 -114 -363 -1492 -793 -1145 -1118 -1503 -2246 -1905 -456 -700 241 33 865 460 951 101 -459 -136 -82 -245 356 1349 301 -5 113 -851 -286 -269 -1257 -1273 -1023 -1405 189 1091 1231 640 656 -102 -429 -192 -195 -44 253 117 -232 238 1181 661 793 -2 -661 781 536 210 333 -720 -384 -282 159 335 264 911 14 -132 -227 -1002 -899
SS 20250323T091328.8Z 9213.384361 216 1 48.33 2 57.17 136.91 87.37 216.71 0.00 1 0.00 1 0 17 1.310e-02 6.690e-03 4.616e-03 1.289e-03 2.633435e-01 6.360436e-04 3.397942e-03 -6.000000e+00 7.342895e-03 225.87 -2.00 3.76 -2.00 317.66 0.00e+00 7.851664e-04 9.616891e-05 1.497144e-04 -6.000000e+00 3.112040e-04 270.98 -2.00 20.00 -2.00 317.13 0.00e+00 1.838 0.000 302.00 328.00 3 4.1615e+00 1.6800e-03 2.3126e-02 -6.0000e+00 1.8243e-02 4.3162e-03 1.8904e-03 1.4356e-02 -6.0000e+00 1.9865e-02 -2.0567e-03 1.1796e-03 7.1728e-03 -6.0000e+00 1.1765e-02 -5.1105e-03 5.9969e-04 2.1462e-03 -6.0000e+00 5.0163e-03 9.8800e-04 -1.9293e-05 3.6219e-05 2.1997e-05 -6.0000e+00 3.4051e-04 8.2452e-04 0.0000e+00 11 8 0 10 0 0 33.61 25.58 0.18 0.00082 0.00068 55 13 1 8 0 878.660 20.01 162.77 22.26 25.58 25.47 0.0 962.66 -2602 -1343 -2823 -4893 -5108 662 -3928 456 -1549 -3006 -3670 -3392 -1696 -732 1229 -790 556 -138 1247 1858 532 592 1438 1194 -256 331 -998 -254 -863 610 47 469 310 -1974 -3342 -3290 -2726 -983 -605 -754 -485 -451 -277 -448 -16 -204 -642 -108 -522 458 665 1157 954 1123 776 1292 599 275 376 301 1240 1570 2285 2330 486 -143 -378 -867 997 890 424 940 288 881 -124 -290 -934 -1570 -690 -1332 -1746 -1796 -2472 -1899 -591 -497 -5 -18 535 278 569 64 -438 105 -145 -128 112 899 304 92 -129 -685 -419 -286 -912 -1397 -480 -755 169 426 645 340 307 -23 -198 -1 228 177 342 290 -409 187 463 573 588 321 67 963 574 71 117 -464 -228 -116 232 -197 45 505 124 -184 -261 -548 -595 -249 -139 -301 -493 -461 55 -362 45 -174 -357 -435 -413 -228 -113 210 -152 110 -29 264 405 120 131 323 284 -65 87 -264 -63 -202 140 12 124 89 -597 -952 -911 -818 -336 -246 -350 -246 -236 -149 -244 -8 -111 -343 -57 -269 237 358 661 578 708 506 855 403 184 250 198 831 1116 1742 1882 401 -111 -272 -614 728 727 379 865 267 791 -106 -227 -676 -1089 -488 -1059 -1526 -1705 -2505 -1998 -649 -575 -6 -23 662 338 650 68 -435 100 -144 -138 131 1145 410 123 -166 -828 -481 -331 -1138 -1846 -650 -1063 245 646 1016 545 481 -35 -279 -2 302 241 490 439 -636 286 694 843 828 436 88 1247 780 103 176 -716 -355 -186 384 -341 79 908 225 -331 -457 -933 -999
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