File name: Pandora127s1_Mainz-MPIC_20250422_L2Fit_fnvh3c4d20250305p1-8.txt File generation date: 20250904T070246.2Z Data description: Level 2 spectral fitting results file Data file version: fnvh3c4p1-8 Local principal investigator: Thomas Wagner Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 127 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora127_OF_v4d20210611.txt Instrument calibration file used: Pandora127s1_CF_v4d20250305.txt Level 1 file used: Pandora127s1_Mainz-MPIC_20250422_L1_smca1c4d20250305p1-8.txt Full location name: Max-Planck-Institute for Chemistry, Mainz Short location name: Mainz-MPIC Country of location: Germany Location latitude [deg]: 49.9910 Location longitude [deg]: 8.2280 Location altitude [m]: 125 Local noon date: 20250422 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1190 1631 Nominal wavelengths inside fitting window [nm]: 435.1065 435.2342 435.3619 435.4896 435.6173 435.7450 435.8726 436.0003 436.1279 436.2555 436.3831 436.5107 436.6382 436.7658 436.8933 437.0208 437.1483 437.2758 437.4033 437.5307 437.6582 437.7856 437.9130 438.0404 438.1678 438.2951 438.4225 438.5498 438.6771 438.8045 438.9317 439.0590 439.1863 439.3135 439.4407 439.5680 439.6951 439.8223 439.9495 440.0766 440.2038 440.3309 440.4580 440.5851 440.7122 440.8392 440.9663 441.0933 441.2203 441.3473 441.4743 441.6013 441.7282 441.8551 441.9821 442.1090 442.2359 442.3627 442.4896 442.6164 442.7433 442.8701 442.9969 443.1236 443.2504 443.3772 443.5039 443.6306 443.7573 443.8840 444.0107 444.1373 444.2640 444.3906 444.5172 444.6438 444.7704 444.8970 445.0235 445.1501 445.2766 445.4031 445.5296 445.6560 445.7825 445.9089 446.0354 446.1618 446.2882 446.4145 446.5409 446.6673 446.7936 446.9199 447.0462 447.1725 447.2988 447.4250 447.5513 447.6775 447.8037 447.9299 448.0561 448.1822 448.3084 448.4345 448.5606 448.6867 448.8128 448.9389 449.0649 449.1910 449.3170 449.4430 449.5690 449.6950 449.8209 449.9469 450.0728 450.1987 450.3246 450.4505 450.5763 450.7022 450.8280 450.9538 451.0796 451.2054 451.3312 451.4570 451.5827 451.7084 451.8341 451.9598 452.0855 452.2112 452.3368 452.4624 452.5881 452.7137 452.8392 452.9648 453.0904 453.2159 453.3414 453.4669 453.5924 453.7179 453.8433 453.9688 454.0942 454.2196 454.3450 454.4704 454.5958 454.7211 454.8464 454.9718 455.0971 455.2223 455.3476 455.4729 455.5981 455.7233 455.8485 455.9737 456.0989 456.2240 456.3492 456.4743 456.5994 456.7245 456.8496 456.9747 457.0997 457.2247 457.3497 457.4747 457.5997 457.7247 457.8496 457.9746 458.0995 458.2244 458.3493 458.4742 458.5990 458.7239 458.8487 458.9735 459.0983 459.2231 459.3478 459.4726 459.5973 459.7220 459.8467 459.9714 460.0961 460.2207 460.3453 460.4700 460.5946 460.7191 460.8437 460.9683 461.0928 461.2173 461.3418 461.4663 461.5908 461.7153 461.8397 461.9641 462.0885 462.2129 462.3373 462.4617 462.5860 462.7103 462.8347 462.9590 463.0832 463.2075 463.3317 463.4560 463.5802 463.7044 463.8286 463.9528 464.0769 464.2010 464.3252 464.4493 464.5734 464.6974 464.8215 464.9455 465.0695 465.1936 465.3175 465.4415 465.5655 465.6894 465.8134 465.9373 466.0612 466.1850 466.3089 466.4328 466.5566 466.6804 466.8042 466.9280 467.0517 467.1755 467.2992 467.4229 467.5466 467.6703 467.7940 467.9177 468.0413 468.1649 468.2885 468.4121 468.5357 468.6592 468.7828 468.9063 469.0298 469.1533 469.2768 469.4002 469.5237 469.6471 469.7705 469.8939 470.0173 470.1406 470.2640 470.3873 470.5106 470.6339 470.7572 470.8804 471.0037 471.1269 471.2501 471.3733 471.4965 471.6197 471.7428 471.8660 471.9891 472.1122 472.2352 472.3583 472.4814 472.6044 472.7274 472.8504 472.9734 473.0964 473.2193 473.3423 473.4652 473.5881 473.7110 473.8338 473.9567 474.0795 474.2023 474.3251 474.4479 474.5707 474.6935 474.8162 474.9389 475.0616 475.1843 475.3070 475.4296 475.5523 475.6749 475.7975 475.9201 476.0427 476.1652 476.2878 476.4103 476.5328 476.6553 476.7778 476.9002 477.0227 477.1451 477.2675 477.3899 477.5123 477.6346 477.7570 477.8793 478.0016 478.1239 478.2462 478.3684 478.4907 478.6129 478.7351 478.8573 478.9795 479.1017 479.2238 479.3459 479.4680 479.5901 479.7122 479.8343 479.9563 480.0783 480.2004 480.3224 480.4443 480.5663 480.6882 480.8102 480.9321 481.0540 481.1759 481.2977 481.4196 481.5414 481.6632 481.7850 481.9068 482.0285 482.1503 482.2720 482.3937 482.5154 482.6371 482.7587 482.8804 483.0020 483.1236 483.2452 483.3668 483.4884 483.6099 483.7314 483.8529 483.9744 484.0959 484.2174 484.3388 484.4603 484.5817 484.7031 484.8244 484.9458 485.0671 485.1885 485.3098 485.4311 485.5523 485.6736 485.7948 485.9161 486.0373 486.1585 486.2796 486.4008 486.5219 486.6431 486.7642 486.8853 487.0063 487.1274 487.2484 487.3695 487.4905 487.6115 487.7324 487.8534 487.9743 488.0953 488.2162 488.3370 488.4579 488.5788 488.6996 488.8204 488.9412 489.0620 489.1828 489.3035 489.4243 489.5450 489.6657 489.7864 489.9071 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Oxygen dimer slant column amount [moles squared per meter to the 5th], -9e99=fitting not successful Column 45: Independent uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Oxygen dimer effective temperature [K] Column 50: Independent uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective oxygen dimer fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for oxygen dimer [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 56: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 57: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 58: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 59: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 60: Ozone effective temperature [K] Column 61: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 62: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 63: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 64: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 65: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 66: Fitted Ring spectrum, -9e99=no fitting done or fitting not successful Column 67: Independent uncertainty of fitted Ring spectrum, -9=fitting not successful Column 68: Structured uncertainty of fitted Ring spectrum, -9=fitting not successful Column 69: Common uncertainty of fitted Ring spectrum, -9=fitting not successful Column 70: rms-based uncertainty of fitted Ring spectrum, -9=fitting not successful Column 71: Effective Ring fitting wavelength [nm], -9=fitting not done or not successful Column 72: Diffuse correction applied before fitting at effective Ring fitting wavelength [%], 0=no diffuse correction applied, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 73: Lower limit used for wavelength scaling [nm] Column 74: Upper limit used for wavelength scaling [nm] Column 75: Order of smoothing polynomial Column 76: Smoothing polynomial coefficient, order 0 Column 77: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 78: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 79: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 80: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 81: Smoothing polynomial coefficient, order 1 Column 82: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 83: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 84: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 85: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 86: Smoothing polynomial coefficient, order 2 Column 87: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 88: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 89: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 90: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 91: Smoothing polynomial coefficient, order 3 Column 92: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 93: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 94: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 95: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 96: Smoothing polynomial coefficient, order 4 Column 97: Independent uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 98: Structured uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 99: Common uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 100: rms-based uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 101: Mean value of measured data inside fitting window [same units as measurements] Column 102: Offset polynomial coefficient, order 0 Column 103: Independent uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 104: Structured uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 105: Common uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 106: rms-based uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 107: Offset polynomial coefficient, order 1 Column 108: Independent uncertainty of offset polynomial coefficient, order 1, -9=fitting not successful Column 109: Structured uncertainty of offset polynomial coefficient, order 1, -9=fitting not successful Column 110: Common uncertainty of offset polynomial coefficient, order 1, -9=fitting not successful Column 111: rms-based uncertainty of offset polynomial coefficient, order 1, -9=fitting not successful Column 112: Wavelength change polynomial coefficient, order 0 Column 113: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 114: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 115: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 116: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 117: Wavelength change polynomial coefficient, order 1 Column 118: Independent uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 119: Structured uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 120: Common uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 121: rms-based uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 122: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 123: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 124: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 125: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 126: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 127: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 128: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 129: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 130: Atmospheric variability [%], 999=no atmospheric variability was determined Column 131: Wavelength effective temperature [°C], 999=no effective temperature given Column 132: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 133: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 134: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 135: Number of bright count cycles Column 136: Number of dark count cycles Column 137: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 138: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 139: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 140: Integration time [ms] Column 141: Spectrometer control temperature [°C], 999=no temperature signal Column 142: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 143: Temperature in head sensor [°C], 999=no temperature signal Column 144: Temperature at electronics board 1 [°C], 999=no temperature signal Column 145: Temperature at electronics board 2 [°C], 999=no temperature signal Column 146: Humidity in head sensor [%], -9=no humidity signal Column 147: Pressure in head sensor [hPa], -9=no pressure signal Columns 148-589: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 590-1031: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- EO 20250422T044607.8Z 9243.198701 97 1 10.51 6 86.84 74.60 74.89 151.15 0.46 0 113.25 0 0 76 2.307e-03 2.289e-03 2.196e-03 2.177e-03 -4.732367e+03 3.516798e+02 4.210509e+02 -6.000000e+00 3.638670e+02 274.51 -2.00 20.00 -2.00 460.83 0.00e+00 -1.377329e-03 2.504135e-05 1.029143e-04 -6.000000e+00 2.659885e-05 274.51 -2.00 20.00 -2.00 460.88 0.00e+00 -1.308037e+06 3.169149e+04 2.432123e+04 -6.000000e+00 3.493004e+04 274.51 -2.00 20.00 -2.00 474.61 0.00e+00 1.412719e-01 3.633610e-02 1.021400e-02 -6.000000e+00 4.035547e-02 274.51 -2.00 20.00 -2.00 471.77 0.00e+00 -1.1525e+02 9.1701e+01 3.6571e+01 -6.0000e+00 9.4231e+01 461.48 0.00e+00 432.04 492.92 4 -5.3980e-01 2.5192e-03 2.6965e-03 -6.0000e+00 2.4704e-03 4.8918e-02 2.1551e-03 1.2703e-03 -6.0000e+00 2.0608e-03 2.1932e-03 8.9232e-04 4.3023e-04 -6.0000e+00 9.7624e-04 1.2675e-03 2.9755e-04 2.3288e-04 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