File name: Pandora127s1_Mainz-MPIC_20250423_L2Fit_fwvt1c4d20250305p1-8.txt
File generation date: 20250904T070113.8Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c4p1-8
Local principal investigator: Thomas Wagner
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 127
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora127_OF_v4d20210611.txt
Instrument calibration file used: Pandora127s1_CF_v4d20250305.txt
Level 1 file used: Pandora127s1_Mainz-MPIC_20250423_L1_smca1c4d20250305p1-8.txt
Full location name: Max-Planck-Institute for Chemistry, Mainz
Short location name: Mainz-MPIC
Country of location: Germany
Location latitude [deg]: 49.9910
Location longitude [deg]: 8.2280
Location altitude [m]: 125
Local noon date: 20250423
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 1649 1799
Nominal wavelengths inside fitting window [nm]: 492.0762 492.1966 492.3169 492.4372 492.5575 492.6778 492.7980 492.9183 493.0385 493.1587 493.2789 493.3991 493.5192 493.6394 493.7595 493.8796 493.9997 494.1198 494.2398 494.3599 494.4799 494.5999 494.7199 494.8399 494.9598 495.0798 495.1997 495.3196 495.4395 495.5593 495.6792 495.7990 495.9188 496.0386 496.1584 496.2782 496.3979 496.5177 496.6374 496.7571 496.8768 496.9964 497.1161 497.2357 497.3553 497.4749 497.5945 497.7140 497.8336 497.9531 498.0726 498.1921 498.3116 498.4311 498.5505 498.6699 498.7893 498.9087 499.0281 499.1474 499.2668 499.3861 499.5054 499.6247 499.7439 499.8632 499.9824 500.1016 500.2208 500.3400 500.4592 500.5783 500.6975 500.8166 500.9357 501.0548 501.1738 501.2929 501.4119 501.5309 501.6499 501.7689 501.8878 502.0068 502.1257 502.2446 502.3635 502.4823 502.6012 502.7200 502.8389 502.9577 503.0764 503.1952 503.3140 503.4327 503.5514 503.6701 503.7888 503.9074 504.0261 504.1447 504.2633 504.3819 504.5005 504.6191 504.7376 504.8561 504.9746 505.0931 505.2116 505.3300 505.4485 505.5669 505.6853 505.8037 505.9221 506.0404 506.1587 506.2770 506.3953 506.5136 506.6319 506.7501 506.8684 506.9866 507.1048 507.2229 507.3411 507.4592 507.5774 507.6955 507.8136 507.9316 508.0497 508.1677 508.2857 508.4037 508.5217 508.6397 508.7576 508.8756 508.9935 509.1114 509.2293 509.3471 509.4650 509.5828 509.7006 509.8184 509.9362
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal
Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal
Column 100: Humidity in head sensor [%], -9=no humidity signal
Column 101: Pressure in head sensor [hPa], -9=no pressure signal
Columns 102-252: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 253-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20250423T071918.5Z 9244.305075 169 1 10.91 2 62.18 104.10 64.10 175.12 0.00 1 0.00 1 0 15 2.834e-03 2.813e-03 1.630e-04 1.628e-04 2.087054e+03 9.228980e+00 1.565428e+02 -6.000000e+00 1.501868e+02 274.64 -2.00 20.00 -2.00 505.25 0.00e+00 8.105914e-04 4.338168e-06 4.561816e-05 -6.000000e+00 7.718555e-05 274.64 -2.00 20.00 -2.00 500.47 0.00e+00 1.043464e-01 3.196081e-03 1.751255e-02 -6.000000e+00 5.595990e-02 228.60 -2.00 3.76 -2.00 502.05 0.00e+00 2.132 0.000 489.00 513.00 1 2.6629e+00 2.4403e-04 3.5184e-03 -6.0000e+00 4.2740e-03 5.2532e-03 6.3459e-05 4.3415e-04 -6.0000e+00 1.1166e-03 9.9204e-02 2.8904e-04 1.5180e-05 2.6609e-05 -6.0000e+00 2.7155e-04 3.8861e-03 -4.2263e-05 12 1 1 12 1 1 99.82 25.58 1.96 0.00389 0.00589 375 152 1 2 0 28.610 20.01 162.68 21.03 25.58 25.47 0.1 957.46 -371 -246 -142 -134 119 474 424 380 389 302 316 2 -192 -179 -343 -331 -81 54 -56 -143 77 132 156 329 264 296 360 103 -287 -208 -189 -321 40 318 -105 -82 186 65 -72 -69 2 -44 76 231 241 280 268 244 90 -204 -411 -526 -1493 -433 -247 -266 -217 -80 -24 154 306 358 269 315 290 185 195 58 -122 -295 -140 -132 -171 67 -22 -276 -292 -127 -246 -286 -299 -358 -420 -173 -60 -269 -224 -80 -94 -125 24 320 343 213 286 376 110 -156 -210 -444 -574 -508 -249 -21 -270 -382 -230 -231 -166 24 -30 -104 116 182 248 418 537 462 331 338 216 156 234 383 106 83 261 210 234 400 159 -35 15 -160 -344 -23 -17 -295 -206 76 11 109 246 217 256 143 -82 -241 -266 -258 -296 -365 -239 -143 -135 122 497 438 395 404 319 329 2 -194 -179 -342 -332 -82 56 -58 -150 81 138 163 345 278 312 377 106 -291 -210 -187 -319 40 323 -110 -87 195 67 -73 -70 2 -45 78 241 253 295 281 253 92 -203 -410 -512 -1448 -418 -245 -263 -220 -82 -24 157 312 366 277 324 296 186 194 57 -121 -292 -136 -129 -169 67 -22 -271 -290 -124 -237 -275 -288 -348 -411 -170 -58 -263 -220 -78 -92 -123 23 319 347 211 290 375 107 -150 -203 -421 -538 -480 -241 -21 -272 -377 -232 -229 -162 23 -30 -101 115 182 249 422 545 470 336 339 213 151 232 380 103 80 254 204 226 385 153 -35 15 -153 -325 -21 -16 -283 -201 75 11 109 247 219 259 144 -82 -235 -254 -249 -287
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SQ 20250423T073356.4Z 9244.315237 177 1 48.68 2 59.91 107.26 63.92 178.98 0.00 1 0.00 1 0 22 2.849e-03 2.830e-03 6.953e-04 6.932e-04 2.031296e+03 3.968329e+01 1.518310e+02 -6.000000e+00 1.509871e+02 274.64 -2.00 20.00 -2.00 505.24 0.00e+00 8.329150e-04 1.846844e-05 4.672513e-05 -6.000000e+00 7.759686e-05 274.64 -2.00 20.00 -2.00 500.34 0.00e+00 1.194229e-01 1.371470e-02 1.707940e-02 -6.000000e+00 5.625890e-02 228.60 -2.00 3.76 -2.00 501.95 0.00e+00 1.986 0.000 489.00 513.00 1 6.7595e+00 1.0470e-03 3.3354e-03 -6.0000e+00 4.2969e-03 1.3615e-02 2.7296e-04 4.1681e-04 -6.0000e+00 1.1226e-03 1.6815e-03 1.8453e-04 6.4677e-05 2.5494e-05 -6.0000e+00 2.7300e-04 2.8078e-03 -3.7239e-05 10 0 0 10 0 0 99.86 25.58 1.98 0.00281 0.00409 48 11 1 2 0 1014.000 20.01 162.77 22.25 25.58 25.47 0.1 964.06 -371 -463 -106 -167 215 392 459 280 448 411 329 -48 -233 -94 -458 -245 -117 152 -25 -127 144 36 133 156 226 163 396 0 -196 -352 -34 -242 -26 422 -174 31 85 107 -120 36 -7 64 28 272 269 291 292 81 158 -261 -217 -548 -1522 -473 -272 -311 -202 -21 51 78 184 405 254 437 141 194 234 39 -163 -249 -70 -272 -25 63 -107 -303 -174 -202 -197 -187 -335 -308 -425 -55 -175 -243 -235 -133 -168 -29 69 436 420 153 420 171 113 -212 -102 -411 -557 -507 -252 -23 -382 -327 -310 -175 -213 11 -184 82 44 258 274 430 606 323 439 299 209 62 214 382 196 61 205 233 93 354 55 46 0 -126 -362 -38 28 -255 -156 10 -59 71 257 139 315 14 -70 -117 -255 -197 -270 -362 -458 -107 -172 225 415 491 300 478 436 346 -49 -239 -96 -466 -249 -120 158 -26 -136 154 38 143 167 242 175 420 0 -203 -359 -34 -242 -26 437 -185 33 90 113 -125 37 -7 66 29 285 283 307 308 84 162 -264 -216 -536 -1481 -458 -268 -313 -207 -21 53 80 188 415 260 447 145 196 234 39 -160 -243 -68 -263 -24 62 -106 -299 -170 -195 -188 -178 -319 -295 -409 -53 -170 -237 -230 -131 -164 -29 68 431 419 153 420 169 110 -203 -96 -383 -514 -471 -237 -22 -377 -326 -306 -171 -207 11 -180 80 44 257 275 433 609 327 441 299 206 60 207 370 190 59 199 226 90 342 53 44 0 -118 -338 -35 26 -244 -151 10 -58 70 252 138 311 14 -69 -113 -242 -184 -253
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