File name: Pandora127s1_Mainz-MPIC_20250604_L2Fit_fwvt1c4d20250305p1-8.txt
File generation date: 20250904T072119.7Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c4p1-8
Local principal investigator: Thomas Wagner
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 127
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora127_OF_v4d20210611.txt
Instrument calibration file used: Pandora127s1_CF_v4d20250305.txt
Level 1 file used: Pandora127s1_Mainz-MPIC_20250604_L1_smca1c4d20250305p1-8.txt
Full location name: Max-Planck-Institute for Chemistry, Mainz
Short location name: Mainz-MPIC
Country of location: Germany
Location latitude [deg]: 49.9910
Location longitude [deg]: 8.2280
Location altitude [m]: 125
Local noon date: 20250604
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 1649 1799
Nominal wavelengths inside fitting window [nm]: 492.0762 492.1966 492.3169 492.4372 492.5575 492.6778 492.7980 492.9183 493.0385 493.1587 493.2789 493.3991 493.5192 493.6394 493.7595 493.8796 493.9997 494.1198 494.2398 494.3599 494.4799 494.5999 494.7199 494.8399 494.9598 495.0798 495.1997 495.3196 495.4395 495.5593 495.6792 495.7990 495.9188 496.0386 496.1584 496.2782 496.3979 496.5177 496.6374 496.7571 496.8768 496.9964 497.1161 497.2357 497.3553 497.4749 497.5945 497.7140 497.8336 497.9531 498.0726 498.1921 498.3116 498.4311 498.5505 498.6699 498.7893 498.9087 499.0281 499.1474 499.2668 499.3861 499.5054 499.6247 499.7439 499.8632 499.9824 500.1016 500.2208 500.3400 500.4592 500.5783 500.6975 500.8166 500.9357 501.0548 501.1738 501.2929 501.4119 501.5309 501.6499 501.7689 501.8878 502.0068 502.1257 502.2446 502.3635 502.4823 502.6012 502.7200 502.8389 502.9577 503.0764 503.1952 503.3140 503.4327 503.5514 503.6701 503.7888 503.9074 504.0261 504.1447 504.2633 504.3819 504.5005 504.6191 504.7376 504.8561 504.9746 505.0931 505.2116 505.3300 505.4485 505.5669 505.6853 505.8037 505.9221 506.0404 506.1587 506.2770 506.3953 506.5136 506.6319 506.7501 506.8684 506.9866 507.1048 507.2229 507.3411 507.4592 507.5774 507.6955 507.8136 507.9316 508.0497 508.1677 508.2857 508.4037 508.5217 508.6397 508.7576 508.8756 508.9935 509.1114 509.2293 509.3471 509.4650 509.5828 509.7006 509.8184 509.9362
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal
Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal
Column 100: Humidity in head sensor [%], -9=no humidity signal
Column 101: Pressure in head sensor [hPa], -9=no pressure signal
Columns 102-252: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 253-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20250604T103241.2Z 9286.439366 285 1 11.21 2 29.39 154.53 108.78 66.96 0.00 1 0.00 1 0 15 3.129e-03 3.116e-03 1.613e-03 1.609e-03 2.181211e+03 9.350559e+01 1.590497e+02 -6.000000e+00 1.690995e+02 279.46 -2.00 20.00 -2.00 505.24 0.00e+00 4.766820e-04 4.339426e-05 2.771705e-05 -6.000000e+00 8.621101e-05 279.46 -2.00 20.00 -2.00 500.41 0.00e+00 1.363427e-03 3.176100e-02 1.694134e-02 -6.000000e+00 6.191103e-02 232.49 -2.00 3.76 -2.00 502.00 0.00e+00 1.147 0.000 489.00 513.00 1 7.1836e+00 2.4280e-03 2.2571e-03 -6.0000e+00 4.7350e-03 8.4880e-03 6.3225e-04 4.0855e-04 -6.0000e+00 1.2362e-03 1.2548e-03 2.2441e-04 1.5006e-04 2.1934e-05 -6.0000e+00 2.9995e-04 3.1652e-03 -3.2092e-05 12 1 1 12 1 1 99.32 25.68 2.06 0.00317 0.00472 4 5 1 2 0 2241.290 20.01 162.77 24.18 25.68 25.58 0.0 974.77 -615 -246 -247 -149 -31 468 258 604 572 429 426 -4 -137 -126 -394 -317 -108 57 -121 -96 180 174 239 27 30 325 391 -22 -421 -439 -241 99 191 342 -241 -114 308 109 -309 163 -75 -191 162 97 292 162 291 216 122 -12 -334 -369 -1395 -389 -191 -248 -293 -20 109 119 123 244 474 401 292 72 267 -360 36 -251 -44 97 -105 1 -437 -184 77 -42 -418 19 -496 -537 -658 -262 212 -367 -230 17 -1 25 -10 595 100 376 536 214 1 10 -334 -588 -380 -577 0 -47 -326 -275 -271 -362 -267 67 -157 -112 273 6 347 420 703 522 391 328 -43 63 198 299 251 -29 350 401 36 84 148 -219 -4 -395 -70 -200 6 -420 -17 357 -145 126 139 393 178 230 -213 -90 -339 -110 -336 -603 -243 -248 -152 -32 490 272 640 604 451 443 -4 -140 -128 -399 -321 -110 59 -128 -101 190 184 252 29 32 343 412 -23 -435 -445 -241 99 194 354 -253 -120 323 113 -320 168 -77 -196 167 101 304 169 303 223 125 -12 -332 -362 -1361 -379 -188 -249 -299 -21 111 121 125 249 484 410 297 72 267 -358 35 -246 -43 94 -102 1 -434 -182 75 -40 -402 18 -478 -519 -638 -255 207 -360 -226 17 -1 24 -10 590 100 377 535 212 1 10 -318 -554 -356 -543 0 -46 -324 -274 -269 -355 -261 65 -153 -110 272 6 348 421 707 526 393 328 -43 62 193 290 246 -28 341 390 35 82 143 -212 -4 -374 -66 -189 6 -406 -17 349 -143 124 137 389 176 228 -209 -87 -324 -104 -320
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SQ 20250604T104626.0Z 9286.448912 293 1 50.24 2 28.55 160.86 106.83 69.79 0.00 1 0.00 1 0 15 3.225e-03 3.210e-03 1.276e-03 1.271e-03 3.169487e+03 7.667486e+01 2.250049e+02 -6.000000e+00 1.742786e+02 279.46 -2.00 20.00 -2.00 505.24 0.00e+00 4.510543e-04 3.427913e-05 2.788441e-05 -6.000000e+00 8.884689e-05 279.46 -2.00 20.00 -2.00 500.32 0.00e+00 5.077933e-02 2.525439e-02 2.431685e-02 -6.000000e+00 6.379572e-02 232.49 -2.00 3.76 -2.00 501.93 0.00e+00 1.138 0.000 489.00 513.00 1 7.9978e+00 1.9303e-03 2.6849e-03 -6.0000e+00 4.8793e-03 7.0293e-03 5.0156e-04 5.8008e-04 -6.0000e+00 1.2736e-03 5.5366e-04 3.3137e-04 1.1821e-04 2.8422e-05 -6.0000e+00 3.0909e-04 1.8768e-03 -1.3107e-05 10 0 0 10 0 0 98.89 25.68 2.00 0.00188 0.00418 15 4 1 2 0 3348.670 20.01 162.77 24.96 25.68 25.58 0.0 978.59 -680 -344 -78 -259 146 253 424 219 140 405 300 -97 -22 -404 -487 -205 44 255 -39 -359 521 -8 92 144 176 387 365 98 -507 -327 -47 -150 -220 586 -113 -251 363 286 -255 37 -98 77 181 178 316 303 170 274 77 -160 -192 -363 -1360 -314 -516 -342 -387 -48 147 -114 397 367 443 380 583 156 362 156 -163 -284 109 1 -241 239 -193 112 -432 -322 -416 -188 -455 -592 -244 -203 234 -400 -195 -415 -117 -213 48 527 422 308 627 212 41 -143 -98 -609 -515 -422 -336 15 -33 -122 -38 -432 -282 -6 -9 18 73 -87 573 414 826 521 248 211 57 28 7 274 42 119 122 524 121 300 141 -525 73 -169 -263 -278 -123 -258 -140 21 -77 -58 335 217 51 62 29 -176 -385 -36 -181 -663 -340 -78 -269 153 269 455 236 150 430 315 -101 -22 -414 -497 -210 45 267 -42 -386 558 -9 98 154 190 416 391 103 -530 -333 -47 -150 -225 610 -121 -269 385 299 -267 39 -101 80 189 187 335 320 180 285 79 -163 -190 -354 -1321 -304 -509 -344 -397 -50 151 -117 405 377 454 390 595 157 360 154 -160 -276 106 1 -235 234 -191 110 -422 -309 -396 -179 -432 -567 -234 -196 227 -392 -192 -407 -114 -208 48 519 420 309 622 208 40 -137 -91 -562 -471 -389 -316 15 -32 -121 -37 -423 -272 -6 -9 18 72 -87 573 414 828 523 249 210 56 28 7 264 41 115 119 506 117 288 135 -502 68 -157 -243 -259 -116 -246 -135 20 -75 -57 329 214 50 61 28 -169 -366 -34 -169
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