File name: Pandora127s1_Mainz-MPIC_20250721_L2Fit_fwvt1c8d20250721p1-8.txt
File generation date: 20251015T093500.4Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c8p1-8
Local principal investigator: Thomas Wagner
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 127
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora127_OF_v4d20210611.txt
Instrument calibration file used: Pandora127s1_CF_v8d20250721.txt
Level 1 file used: Pandora127s1_Mainz-MPIC_20250721_L1_smca1c8d20250721p1-8.txt
Full location name: Max-Planck-Institute for Chemistry, Mainz
Short location name: Mainz-MPIC
Country of location: Germany
Location latitude [deg]: 49.9910
Location longitude [deg]: 8.2280
Location altitude [m]: 125
Local noon date: 20250721
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 1649 1799
Nominal wavelengths inside fitting window [nm]: 492.0928 492.2131 492.3335 492.4538 492.5741 492.6944 492.8147 492.9349 493.0552 493.1754 493.2956 493.4158 493.5360 493.6562 493.7763 493.8964 494.0165 494.1366 494.2567 494.3768 494.4968 494.6168 494.7368 494.8568 494.9768 495.0968 495.2167 495.3366 495.4565 495.5764 495.6963 495.8161 495.9360 496.0558 496.1756 496.2954 496.4151 496.5349 496.6546 496.7743 496.8940 497.0137 497.1334 497.2530 497.3727 497.4923 497.6119 497.7315 497.8510 497.9706 498.0901 498.2096 498.3291 498.4486 498.5680 498.6875 498.8069 498.9263 499.0457 499.1651 499.2844 499.4038 499.5231 499.6424 499.7617 499.8810 500.0002 500.1195 500.2387 500.3579 500.4771 500.5962 500.7154 500.8345 500.9536 501.0727 501.1918 501.3109 501.4299 501.5490 501.6680 501.7870 501.9059 502.0249 502.1439 502.2628 502.3817 502.5006 502.6195 502.7383 502.8572 502.9760 503.0948 503.2136 503.3324 503.4511 503.5699 503.6886 503.8073 503.9260 504.0446 504.1633 504.2819 504.4005 504.5191 504.6377 504.7563 504.8748 504.9934 505.1119 505.2304 505.3489 505.4673 505.5858 505.7042 505.8226 505.9410 506.0594 506.1777 506.2961 506.4144 506.5327 506.6510 506.7693 506.8875 507.0057 507.1240 507.2422 507.3604 507.4785 507.5967 507.7148 507.8329 507.9510 508.0691 508.1872 508.3052 508.4232 508.5413 508.6593 508.7772 508.8952 509.0131 509.1311 509.2490 509.3669 509.4847 509.6026 509.7204 509.8382 509.9560
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal
Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal
Column 100: Humidity in head sensor [%], -9=no humidity signal
Column 101: Pressure in head sensor [hPa], -9=no pressure signal
Columns 102-252: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 253-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20250721T095929.6Z 9333.416315 347 1 47.75 2 34.99 139.27 30.14 230.24 0.00 1 0.00 1 0 15 3.632e-03 3.598e-03 1.269e-03 1.264e-03 2.214665e+03 7.405110e+01 1.672042e+02 -6.000000e+00 1.971236e+02 283.52 -2.00 20.00 -2.00 505.24 0.00e+00 4.268024e-04 3.427848e-05 2.517693e-05 -6.000000e+00 1.007471e-04 283.52 -2.00 20.00 -2.00 500.36 0.00e+00 2.303220e-02 2.489103e-02 1.480585e-02 -6.000000e+00 7.138057e-02 233.48 -2.00 3.76 -2.00 501.95 0.00e+00 1.220 0.000 489.00 513.00 1 7.9400e+00 1.9063e-03 2.2215e-03 -6.0000e+00 5.4628e-03 3.8427e-03 4.9689e-04 3.7863e-04 -6.0000e+00 1.4296e-03 5.8232e-04 4.2521e-04 1.1366e-04 2.2089e-05 -6.0000e+00 3.3514e-04 2.1585e-03 -5.7674e-05 12 1 1 12 4 4 99.78 162.77 2.09 0.00216 0.00511 15 4 1 2 0 3182.800 20.00 162.77 28.31 25.79 25.79 0.0 997.08 -780 -322 74 63 -75 360 446 408 575 286 387 -101 -101 -471 -559 -468 -270 -37 337 -79 656 -245 132 303 234 303 540 360 -384 -538 -493 -389 -11 262 44 29 193 -114 12 -312 -10 -162 228 134 341 399 171 346 6 239 -512 -343 -1473 -512 -584 -338 -180 112 322 -55 285 283 380 251 407 325 460 -238 -446 -184 -274 100 -307 220 -213 130 -528 -25 -557 -245 -583 -312 -346 -330 335 -551 -226 -215 173 -376 185 619 502 279 477 335 204 47 -509 -351 -701 -494 -603 -111 4 -131 169 -369 -531 -176 102 155 32 185 480 360 553 741 -47 354 -140 43 -67 313 125 52 -60 415 105 389 46 -255 369 -180 -106 -347 -70 -193 119 58 -81 406 251 484 260 240 -308 -186 -487 -506 -281 -758 -317 75 66 -77 375 472 436 610 300 399 -103 -101 -469 -554 -466 -272 -38 356 -85 700 -263 142 325 253 326 578 381 -398 -539 -485 -383 -11 273 47 31 206 -121 12 -324 -10 -169 240 143 365 428 183 364 7 241 -505 -328 -1407 -488 -573 -342 -186 117 335 -57 295 295 397 263 422 333 462 -237 -441 -179 -264 96 -299 217 -213 129 -519 -24 -530 -232 -556 -299 -334 -322 328 -550 -226 -215 172 -377 186 626 491 276 467 323 203 46 -485 -327 -647 -460 -579 -110 4 -129 164 -355 -503 -166 98 151 32 184 480 362 557 749 -48 353 -138 42 -64 299 120 50 -58 399 101 372 44 -242 341 -165 -96 -317 -65 -184 115 57 -80 401 249 482 261 240 -306 -180 -460 -471 -262
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SQ 20250721T103604.1Z 9333.441714 366 1 26.46 2 31.74 153.74 34.85 242.04 0.00 1 0.00 1 0 15 3.363e-03 3.336e-03 7.223e-04 7.205e-04 1.771341e+03 4.156754e+01 1.300514e+02 -6.000000e+00 1.824817e+02 283.52 -2.00 20.00 -2.00 505.27 0.00e+00 4.122439e-04 1.952447e-05 2.469008e-05 -6.000000e+00 9.326264e-05 283.52 -2.00 20.00 -2.00 500.42 0.00e+00 -2.104394e-02 1.411014e-02 1.318819e-02 -6.000000e+00 6.607473e-02 233.47 -2.00 3.76 -2.00 502.02 0.00e+00 1.175 0.000 489.00 513.00 1 6.5635e+00 1.0787e-03 2.0822e-03 -6.0000e+00 5.0568e-03 2.5426e-03 2.8208e-04 3.2367e-04 -6.0000e+00 1.3233e-03 2.3311e-03 3.2411e-04 6.5016e-05 1.7820e-05 -6.0000e+00 3.1023e-04 1.9938e-03 -5.2877e-05 12 1 1 12 5 5 99.74 162.77 1.99 0.00199 0.00424 19 9 1 2 0 1322.740 20.01 162.77 29.19 25.90 25.79 0.0 999.91 -579 -487 -119 -121 72 442 617 498 564 146 363 32 -160 -237 -342 -363 -157 80 21 -95 226 9 130 274 233 342 447 154 -321 -448 -356 -436 -88 310 89 16 226 -7 -148 -28 -60 -37 137 335 333 481 371 327 137 -111 -492 -687 -1710 -647 -375 -307 -35 130 31 100 281 378 304 366 358 191 256 0 -231 -360 -250 -60 -122 127 67 -103 -278 -178 -324 -541 -302 -295 -362 -239 -31 -384 -152 -114 -47 -152 -185 357 459 305 475 339 241 -129 -309 -596 -717 -726 -203 126 -150 -187 21 -281 -312 -173 -100 -63 4 308 299 369 638 561 326 263 139 80 263 272 130 91 152 210 214 511 247 -117 31 -115 -568 -287 -153 -173 -51 81 -35 6 277 273 203 275 38 -240 -318 -322 -256 -565 -485 -118 -124 75 456 646 525 591 152 371 33 -165 -242 -347 -370 -162 82 23 -101 240 10 138 292 249 365 474 161 -329 -460 -358 -441 -88 320 95 16 239 -8 -153 -29 -61 -38 143 352 342 495 379 341 141 -112 -480 -677 -1680 -634 -364 -308 -36 134 32 103 288 390 316 379 368 194 256 0 -225 -348 -239 -57 -117 124 66 -102 -270 -170 -305 -510 -284 -280 -348 -231 -30 -380 -151 -113 -46 -151 -185 348 455 305 471 331 238 -125 -293 -554 -661 -675 -193 125 -148 -186 21 -272 -309 -171 -97 -62 4 310 303 376 651 574 333 265 138 78 254 263 126 89 149 205 208 494 239 -112 30 -110 -542 -275 -144 -167 -50 81 -35 6 278 267 200 269 38 -235 -304 -302 -241
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