File name: Pandora127s1_Mainz-MPIC_20250731_L2Fit_fwvt1c5d20250721p1-8.txt
File generation date: 20250902T105716.9Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c5p1-8
Local principal investigator: Thomas Wagner
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 127
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora127_OF_v4d20210611.txt
Instrument calibration file used: Pandora127s1_CF_v6d20250721.txt
Level 1 file used: Pandora127s1_Mainz-MPIC_20250731_L1_smca1c5d20250721p1-8.txt
Full location name: Max-Planck-Institute for Chemistry, Mainz
Short location name: Mainz-MPIC
Country of location: Germany
Location latitude [deg]: 49.9910
Location longitude [deg]: 8.2280
Location altitude [m]: 125
Local noon date: 20250731
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 1649 1799
Nominal wavelengths inside fitting window [nm]: 492.0932 492.2135 492.3339 492.4542 492.5745 492.6948 492.8151 492.9353 493.0556 493.1758 493.2960 493.4162 493.5364 493.6565 493.7767 493.8968 494.0169 494.1370 494.2571 494.3771 494.4972 494.6172 494.7372 494.8572 494.9772 495.0971 495.2170 495.3370 495.4569 495.5767 495.6966 495.8165 495.9363 496.0561 496.1759 496.2957 496.4155 496.5352 496.6549 496.7746 496.8943 497.0140 497.1337 497.2533 497.3730 497.4926 497.6122 497.7317 497.8513 497.9708 498.0904 498.2099 498.3294 498.4488 498.5683 498.6877 498.8072 498.9266 499.0459 499.1653 499.2847 499.4040 499.5233 499.6426 499.7619 499.8812 500.0004 500.1197 500.2389 500.3581 500.4773 500.5964 500.7156 500.8347 500.9538 501.0729 501.1920 501.3110 501.4301 501.5491 501.6681 501.7871 501.9061 502.0250 502.1440 502.2629 502.3818 502.5007 502.6196 502.7384 502.8573 502.9761 503.0949 503.2137 503.3324 503.4512 503.5699 503.6886 503.8073 503.9260 504.0447 504.1633 504.2820 504.4006 504.5192 504.6378 504.7563 504.8749 504.9934 505.1119 505.2304 505.3489 505.4673 505.5858 505.7042 505.8226 505.9410 506.0593 506.1777 506.2960 506.4144 506.5327 506.6509 506.7692 506.8875 507.0057 507.1239 507.2421 507.3603 507.4785 507.5966 507.7147 507.8328 507.9509 508.0690 508.1871 508.3051 508.4231 508.5412 508.6591 508.7771 508.8951 509.0130 509.1309 509.2488 509.3667 509.4846 509.6025 509.7203 509.8381 509.9559
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal
Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal
Column 100: Humidity in head sensor [%], -9=no humidity signal
Column 101: Pressure in head sensor [hPa], -9=no pressure signal
Columns 102-252: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 253-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20250731T070744.4Z 9343.297042 153 1 6.59 2 61.12 95.92 129.64 57.93 0.00 1 0.00 1 0 15 3.450e-03 3.419e-03 1.394e-04 1.392e-04 2.905523e+03 8.228626e+00 2.087262e+02 -6.000000e+00 1.872511e+02 283.59 -2.00 20.00 -2.00 505.27 0.00e+00 5.248484e-04 3.781134e-06 3.215280e-05 -6.000000e+00 9.570548e-05 283.59 -2.00 20.00 -2.00 500.51 0.00e+00 7.312136e-02 2.714229e-03 2.128249e-02 -6.000000e+00 6.775442e-02 233.03 -2.00 3.76 -2.00 502.09 0.00e+00 2.061 0.000 489.00 513.00 1 1.7856e+00 2.0758e-04 3.5042e-03 -6.0000e+00 5.1855e-03 -4.6150e-03 5.4032e-05 5.2975e-04 -6.0000e+00 1.3570e-03 2.4204e-01 4.1303e-04 1.2465e-05 2.7401e-05 -6.0000e+00 3.1830e-04 4.1433e-03 -7.2317e-05 10 0 0 10 0 0 69.31 21.79 1.94 0.00414 0.00701 501 118 1 2 0 12.960 20.00 21.79 25.53 25.58 25.47 0.0 980.03 -655 -471 -205 -51 137 502 523 497 441 288 307 17 -276 -314 -472 -422 -165 26 27 -52 112 141 127 334 297 368 436 191 -319 -395 -374 -445 -83 375 121 109 245 77 -82 -132 -27 -37 145 273 373 383 398 340 162 -168 -495 -664 -1685 -619 -303 -192 -59 32 79 157 273 370 361 414 388 233 194 66 -143 -356 -352 -196 -188 76 61 -170 -239 -229 -350 -444 -384 -427 -423 -254 -87 -216 -205 -116 -163 -148 -30 269 449 354 349 446 230 -71 -334 -642 -765 -601 -361 44 -35 -192 -102 -282 -327 -161 -65 -68 166 242 313 485 627 615 419 354 211 102 115 321 141 140 294 248 285 452 259 -51 -58 -270 -478 -252 -113 -232 -122 111 60 77 237 266 305 243 1 -265 -433 -458 -398 -644 -456 -205 -51 140 521 553 529 468 301 317 18 -278 -312 -468 -420 -167 27 28 -54 117 146 132 348 311 384 453 196 -331 -397 -369 -442 -85 380 126 114 255 79 -84 -133 -27 -37 149 282 390 401 414 350 164 -172 -493 -645 -1630 -597 -300 -190 -60 32 81 159 277 377 370 424 394 234 191 67 -143 -352 -344 -191 -186 76 60 -166 -238 -224 -338 -427 -371 -416 -416 -252 -84 -211 -201 -114 -160 -145 -29 269 455 361 353 443 224 -68 -322 -608 -718 -569 -351 43 -35 -190 -103 -281 -322 -158 -65 -67 165 242 315 490 636 627 426 356 209 99 115 319 137 136 286 241 276 437 250 -51 -56 -258 -455 -241 -110 -224 -119 110 60 78 240 270 311 247 1 -260 -416 -434 -377
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SQ 20250731T070757.8Z 9343.297197 153 3 6.56 2 61.09 95.96 129.61 57.99 0.00 1 0.00 1 0 15 3.435e-03 3.389e-03 1.487e-04 1.485e-04 2.918258e+03 8.804592e+00 2.090905e+02 -6.000000e+00 1.864566e+02 283.59 -2.00 20.00 -2.00 505.28 0.00e+00 5.207943e-04 4.034508e-06 3.199193e-05 -6.000000e+00 9.529879e-05 283.59 -2.00 20.00 -2.00 500.49 0.00e+00 7.114823e-02 2.901493e-03 2.148309e-02 -6.000000e+00 6.746501e-02 233.03 -2.00 3.76 -2.00 502.08 0.00e+00 2.058 0.000 489.00 513.00 1 1.9002e+00 2.2202e-04 3.5086e-03 -6.0000e+00 5.1634e-03 -4.4225e-03 5.7733e-05 5.3292e-04 -6.0000e+00 1.3512e-03 2.1595e-01 3.8433e-04 1.3313e-05 2.6985e-05 -6.0000e+00 3.1694e-04 4.0592e-03 -6.9875e-05 10 0 0 10 0 0 59.56 21.79 1.94 0.00406 0.00673 501 118 1 2 0 12.960 20.00 21.79 25.53 25.58 25.47 0.0 980.03 -653 -487 -181 -78 142 519 487 475 455 305 298 17 -250 -262 -443 -389 -157 47 30 -95 114 145 150 339 296 349 418 195 -308 -422 -376 -445 -66 381 135 96 240 95 -115 -118 -49 -68 148 257 374 379 346 336 172 -146 -477 -647 -1673 -613 -289 -198 -76 43 54 140 279 381 344 416 358 214 215 54 -141 -387 -326 -190 -194 99 57 -166 -260 -205 -332 -455 -396 -389 -424 -275 -84 -224 -201 -134 -173 -162 -20 284 429 368 368 404 236 -103 -298 -623 -799 -628 -357 50 -43 -175 -127 -290 -327 -124 -91 -72 167 253 313 496 617 593 419 378 213 89 93 293 157 119 328 268 272 467 255 -54 -42 -254 -495 -250 -105 -225 -154 132 59 114 255 273 318 267 2 -280 -427 -468 -422 -639 -469 -180 -80 144 535 511 502 478 317 305 17 -249 -268 -451 -398 -157 48 32 -101 121 154 160 362 307 362 445 205 -318 -421 -368 -438 -66 395 139 100 248 97 -120 -122 -51 -71 150 264 387 393 357 342 179 -148 -471 -623 -1606 -587 -283 -200 -76 44 55 141 280 384 349 422 360 213 217 54 -140 -379 -317 -184 -190 98 57 -166 -257 -199 -318 -435 -380 -375 -413 -270 -84 -217 -195 -131 -168 -158 -19 281 430 372 370 398 228 -100 -284 -584 -744 -590 -345 48 -43 -177 -127 -287 -319 -121 -90 -72 169 250 312 495 619 598 422 376 216 89 92 289 156 119 326 267 269 461 252 -53 -41 -240 -467 -237 -102 -223 -149 130 59 114 254 274 320 268 2 -273 -420 -453 -410
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