File name: Pandora127s1_Mainz-MPIC_20250901_L2Fit_fnvh3c5d20250721p1-8.txt File generation date: 20250904T075419.7Z Data description: Level 2 spectral fitting results file Data file version: fnvh3c5p1-8 Local principal investigator: Thomas Wagner Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 127 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora127_OF_v4d20210611.txt Instrument calibration file used: Pandora127s1_CF_v6d20250721.txt Level 1 file used: Pandora127s1_Mainz-MPIC_20250901_L1_smca1c5d20250721p1-8.txt Full location name: Max-Planck-Institute for Chemistry, Mainz Short location name: Mainz-MPIC Country of location: Germany Location latitude [deg]: 49.9910 Location longitude [deg]: 8.2280 Location altitude [m]: 125 Local noon date: 20250901 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1190 1631 Nominal wavelengths inside fitting window [nm]: 435.1166 435.2443 435.3720 435.4997 435.6274 435.7551 435.8827 436.0104 436.1380 436.2656 436.3932 436.5208 436.6483 436.7759 436.9034 437.0309 437.1584 437.2859 437.4134 437.5408 437.6683 437.7957 437.9231 438.0505 438.1779 438.3053 438.4326 438.5599 438.6873 438.8146 438.9418 439.0691 439.1964 439.3236 439.4509 439.5781 439.7053 439.8324 439.9596 440.0868 440.2139 440.3410 440.4681 440.5952 440.7223 440.8494 440.9764 441.1034 441.2305 441.3575 441.4844 441.6114 441.7384 441.8653 441.9922 442.1191 442.2460 442.3729 442.4998 442.6266 442.7534 442.8803 443.0071 443.1338 443.2606 443.3874 443.5141 443.6408 443.7675 443.8942 444.0209 444.1476 444.2742 444.4009 444.5275 444.6541 444.7807 444.9072 445.0338 445.1603 445.2869 445.4134 445.5399 445.6663 445.7928 445.9193 446.0457 446.1721 446.2985 446.4249 446.5513 446.6776 446.8040 446.9303 447.0566 447.1829 447.3092 447.4354 447.5617 447.6879 447.8141 447.9403 448.0665 448.1927 448.3189 448.4450 448.5711 448.6972 448.8233 448.9494 449.0755 449.2015 449.3275 449.4536 449.5796 449.7055 449.8315 449.9575 450.0834 450.2093 450.3352 450.4611 450.5870 450.7129 450.8387 450.9645 451.0904 451.2162 451.3419 451.4677 451.5935 451.7192 451.8449 451.9706 452.0963 452.2220 452.3476 452.4733 452.5989 452.7245 452.8501 452.9757 453.1013 453.2268 453.3523 453.4779 453.6034 453.7289 453.8543 453.9798 454.1052 454.2306 454.3561 454.4814 454.6068 454.7322 454.8575 454.9829 455.1082 455.2335 455.3588 455.4840 455.6093 455.7345 455.8597 455.9849 456.1101 456.2353 456.3605 456.4856 456.6107 456.7358 456.8609 456.9860 457.1111 457.2361 457.3612 457.4862 457.6112 457.7362 457.8611 457.9861 458.1110 458.2359 458.3608 458.4857 458.6106 458.7355 458.8603 458.9851 459.1099 459.2347 459.3595 459.4843 459.6090 459.7338 459.8585 459.9832 460.1079 460.2325 460.3572 460.4818 460.6064 460.7310 460.8556 460.9802 461.1048 461.2293 461.3538 461.4783 461.6028 461.7273 461.8518 461.9762 462.1006 462.2250 462.3494 462.4738 462.5982 462.7225 462.8469 462.9712 463.0955 463.2198 463.3440 463.4683 463.5925 463.7168 463.8410 463.9652 464.0893 464.2135 464.3376 464.4617 464.5859 464.7099 464.8340 464.9581 465.0821 465.2062 465.3302 465.4542 465.5782 465.7021 465.8261 465.9500 466.0739 466.1978 466.3217 466.4456 466.5694 466.6933 466.8171 466.9409 467.0647 467.1884 467.3122 467.4359 467.5596 467.6834 467.8070 467.9307 468.0544 468.1780 468.3016 468.4253 468.5488 468.6724 468.7960 468.9195 469.0431 469.1666 469.2901 469.4135 469.5370 469.6605 469.7839 469.9073 470.0307 470.1541 470.2774 470.4008 470.5241 470.6474 470.7707 470.8940 471.0173 471.1406 471.2638 471.3870 471.5102 471.6334 471.7566 471.8797 472.0029 472.1260 472.2491 472.3722 472.4952 472.6183 472.7413 472.8644 472.9874 473.1104 473.2333 473.3563 473.4792 473.6022 473.7251 473.8480 473.9708 474.0937 474.2165 474.3394 474.4622 474.5850 474.7077 474.8305 474.9532 475.0760 475.1987 475.3214 475.4440 475.5667 475.6894 475.8120 475.9346 476.0572 476.1798 476.3023 476.4249 476.5474 476.6699 476.7924 476.9149 477.0374 477.1598 477.2822 477.4046 477.5270 477.6494 477.7718 477.8941 478.0165 478.1388 478.2611 478.3834 478.5056 478.6279 478.7501 478.8723 478.9945 479.1167 479.2389 479.3610 479.4831 479.6053 479.7273 479.8494 479.9715 480.0935 480.2156 480.3376 480.4596 480.5816 480.7035 480.8255 480.9474 481.0693 481.1912 481.3131 481.4350 481.5568 481.6786 481.8005 481.9223 482.0440 482.1658 482.2876 482.4093 482.5310 482.6527 482.7744 482.8960 483.0177 483.1393 483.2609 483.3825 483.5041 483.6257 483.7472 483.8687 483.9903 484.1118 484.2332 484.3547 484.4761 484.5976 484.7190 484.8404 484.9618 485.0831 485.2045 485.3258 485.4471 485.5684 485.6897 485.8109 485.9322 486.0534 486.1746 486.2958 486.4170 486.5381 486.6593 486.7804 486.9015 487.0226 487.1437 487.2647 487.3858 487.5068 487.6278 487.7488 487.8698 487.9907 488.1117 488.2326 488.3535 488.4744 488.5953 488.7161 488.8370 488.9578 489.0786 489.1994 489.3201 489.4409 489.5616 489.6823 489.8030 489.9237 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Oxygen dimer slant column amount [moles squared per meter to the 5th], -9e99=fitting not successful Column 45: Independent uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Oxygen dimer effective temperature [K] Column 50: Independent uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective oxygen dimer fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for oxygen dimer [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 56: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 57: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 58: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 59: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 60: Ozone effective temperature [K] Column 61: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 62: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 63: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 64: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 65: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 66: Fitted Ring spectrum, -9e99=no fitting done or fitting not successful Column 67: Independent uncertainty of fitted Ring spectrum, -9=fitting not successful Column 68: Structured uncertainty of fitted Ring spectrum, -9=fitting not successful Column 69: Common uncertainty of fitted Ring spectrum, -9=fitting not successful Column 70: rms-based uncertainty of fitted Ring spectrum, -9=fitting not successful Column 71: Effective Ring fitting wavelength [nm], -9=fitting not done or not successful Column 72: Diffuse correction applied before fitting at effective Ring fitting wavelength [%], 0=no diffuse correction applied, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 73: Lower limit used for wavelength scaling [nm] Column 74: Upper limit used for wavelength scaling [nm] Column 75: Order of smoothing polynomial Column 76: Smoothing polynomial coefficient, order 0 Column 77: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 78: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 79: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 80: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 81: Smoothing polynomial coefficient, order 1 Column 82: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 83: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 84: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 85: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 86: Smoothing polynomial coefficient, order 2 Column 87: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 88: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 89: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 90: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 91: Smoothing polynomial coefficient, order 3 Column 92: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 93: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 94: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 95: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 96: Smoothing polynomial coefficient, order 4 Column 97: Independent uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 98: Structured uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 99: Common uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 100: rms-based uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 101: Mean value of measured data inside fitting window [same units as measurements] Column 102: Offset polynomial coefficient, order 0 Column 103: Independent uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 104: Structured uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 105: Common uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 106: rms-based uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 107: Offset polynomial coefficient, order 1 Column 108: Independent uncertainty of offset polynomial coefficient, order 1, -9=fitting not successful Column 109: Structured uncertainty of offset polynomial coefficient, order 1, -9=fitting not successful Column 110: Common uncertainty of offset polynomial coefficient, order 1, -9=fitting not successful Column 111: rms-based uncertainty of offset polynomial coefficient, order 1, -9=fitting not successful Column 112: Wavelength change polynomial coefficient, order 0 Column 113: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 114: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 115: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 116: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 117: Wavelength change polynomial coefficient, order 1 Column 118: Independent uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 119: Structured uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 120: Common uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 121: rms-based uncertainty of wavelength change polynomial coefficient, order 1, -9=fitting not successful Column 122: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 123: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 124: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 125: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 126: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 127: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 128: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 129: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 130: Atmospheric variability [%], 999=no atmospheric variability was determined Column 131: Wavelength effective temperature [°C], 999=no effective temperature given Column 132: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 133: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 134: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 135: Number of bright count cycles Column 136: Number of dark count cycles Column 137: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 138: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 139: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 140: Integration time [ms] Column 141: Spectrometer control temperature [°C], 999=no temperature signal Column 142: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 143: Temperature in head sensor [°C], 999=no temperature signal Column 144: Temperature at electronics board 1 [°C], 999=no temperature signal Column 145: Temperature at electronics board 2 [°C], 999=no temperature signal Column 146: Humidity in head sensor [%], -9=no humidity signal Column 147: Pressure in head sensor [hPa], -9=no pressure signal Columns 148-589: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 590-1031: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- EO 20250901T132647.9Z 9375.560277 4 1 12.23 6 48.79 221.07 101.94 121.65 0.00 0 12.00 0 0 31 5.857e-04 5.829e-04 4.345e-04 4.318e-04 -9.115452e+03 7.135487e+01 7.518331e+02 -6.000000e+00 9.529904e+01 282.18 -2.00 20.00 -2.00 460.47 0.00e+00 -9.796634e-04 5.018397e-06 7.589293e-05 -6.000000e+00 6.829140e-06 282.18 -2.00 20.00 -2.00 460.58 0.00e+00 -1.283686e+06 6.695989e+03 1.889242e+04 -6.000000e+00 9.436082e+03 282.18 -2.00 20.00 -2.00 474.59 0.00e+00 4.817100e-02 8.053026e-03 1.025090e-02 -6.000000e+00 1.130933e-02 282.18 -2.00 20.00 -2.00 471.72 0.00e+00 3.2804e+01 2.8830e+00 4.9157e+00 -6.0000e+00 3.8284e+00 461.14 0.00e+00 432.04 492.93 4 -1.1675e+00 5.0254e-04 2.0154e-03 -6.0000e+00 6.4130e-04 -2.3632e-02 4.2260e-04 1.0806e-03 -6.0000e+00 5.3195e-04 -1.3473e-03 1.7873e-04 4.0617e-04 -6.0000e+00 2.5009e-04 1.0510e-04 5.8941e-05 2.1301e-04 -6.0000e+00 8.0223e-05 6.6288e-04 7.0374e-05 1.8183e-04 -6.0000e+00 9.6690e-05 9.2905e-05 2.8718e-03 1.3188e-03 2.6064e-03 -6.0000e+00 1.7461e-03 -2.4024e-04 3.8589e-04 4.2072e-04 -6.0000e+00 4.6963e-04 -1.4718e-04 9.2558e-06 6.6797e-06 -6.0000e+00 1.2712e-05 -2.1160e-05 8.2304e-06 2.9595e-06 -6.0000e+00 1.1045e-05 1.3323e-03 -4.7245e-05 10 0 0 10 0 0 81.32 21.12 2.14 0.00133 0.00112 137 32 1 1 0 88.610 19.99 21.12 28.02 25.79 25.79 0.0 991.64 63 65 107 8 21 28 97 -62 -73 -9 -14 -16 -31 36 -106 12 -106 -21 -79 4 37 -53 -27 -131 83 -82 87 15 52 4 23 49 143 12 -1 75 38 37 67 33 -4 36 -30 14 -25 34 -40 -13 -75 -26 -55 -119 -101 -79 1 17 -1 3 62 173 188 161 53 38 -33 -26 -73 -46 -55 -73 4 -100 -6 7 13 -80 -23 -4 -10 -19 18 31 -61 40 -51 -49 -100 69 -51 -82 -42 -134 -84 -233 -104 -169 8 -54 -3 -1 47 44 12 52 -4 101 -18 97 -35 49 -68 7 -64 -18 58 -49 15 10 44 -51 59 -42 -3 96 79 72 51 79 43 97 20 34 -12 76 -63 4 14 -23 19 -17 81 -9 72 31 60 -79 -14 17 2 -17 -2 97 -12 -18 -119 -40 -89 40 -13 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