File name: Pandora127s1_Mainz-MPIC_20250919_L2Fit_ffus5c8d20250721p1-8.txt File generation date: 20251015T101524.3Z Data description: Level 2 spectral fitting results file Data file version: ffus5c8p1-8 Local principal investigator: Thomas Wagner Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 127 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora127_OF_v4d20210611.txt Instrument calibration file used: Pandora127s1_CF_v8d20250721.txt Level 1 file used: Pandora127s1_Mainz-MPIC_20250919_L1_smca1c8d20250721p1-8.txt Full location name: Max-Planck-Institute for Chemistry, Mainz Short location name: Mainz-MPIC Country of location: Germany Location latitude [deg]: 49.9910 Location longitude [deg]: 8.2280 Location altitude [m]: 125 Local noon date: 20250919 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 348 614 Nominal wavelengths inside fitting window [nm]: 322.5548 322.6939 322.8330 322.9721 323.1111 323.2502 323.3892 323.5283 323.6673 323.8063 323.9453 324.0843 324.2233 324.3622 324.5012 324.6401 324.7791 324.9180 325.0569 325.1958 325.3347 325.4735 325.6124 325.7513 325.8901 326.0289 326.1677 326.3065 326.4453 326.5841 326.7229 326.8616 327.0003 327.1391 327.2778 327.4165 327.5552 327.6939 327.8325 327.9712 328.1098 328.2485 328.3871 328.5257 328.6643 328.8029 328.9415 329.0800 329.2186 329.3571 329.4957 329.6342 329.7727 329.9112 330.0496 330.1881 330.3266 330.4650 330.6034 330.7419 330.8803 331.0187 331.1571 331.2954 331.4338 331.5721 331.7105 331.8488 331.9871 332.1254 332.2637 332.4020 332.5403 332.6785 332.8167 332.9550 333.0932 333.2314 333.3696 333.5078 333.6459 333.7841 333.9222 334.0604 334.1985 334.3366 334.4747 334.6128 334.7509 334.8889 335.0270 335.1650 335.3030 335.4411 335.5791 335.7171 335.8550 335.9930 336.1310 336.2689 336.4068 336.5447 336.6827 336.8205 336.9584 337.0963 337.2342 337.3720 337.5098 337.6477 337.7855 337.9233 338.0610 338.1988 338.3366 338.4743 338.6121 338.7498 338.8875 339.0252 339.1629 339.3006 339.4382 339.5759 339.7135 339.8512 339.9888 340.1264 340.2640 340.4016 340.5391 340.6767 340.8142 340.9518 341.0893 341.2268 341.3643 341.5018 341.6392 341.7767 341.9141 342.0516 342.1890 342.3264 342.4638 342.6012 342.7386 342.8759 343.0133 343.1506 343.2879 343.4252 343.5625 343.6998 343.8371 343.9744 344.1116 344.2489 344.3861 344.5233 344.6605 344.7977 344.9349 345.0720 345.2092 345.3463 345.4835 345.6206 345.7577 345.8948 346.0319 346.1689 346.3060 346.4430 346.5801 346.7171 346.8541 346.9911 347.1281 347.2650 347.4020 347.5389 347.6759 347.8128 347.9497 348.0866 348.2235 348.3603 348.4972 348.6340 348.7709 348.9077 349.0445 349.1813 349.3181 349.4549 349.5916 349.7284 349.8651 350.0018 350.1385 350.2752 350.4119 350.5486 350.6852 350.8219 350.9585 351.0951 351.2317 351.3683 351.5049 351.6415 351.7781 351.9146 352.0511 352.1877 352.3242 352.4607 352.5972 352.7336 352.8701 353.0065 353.1430 353.2794 353.4158 353.5522 353.6886 353.8249 353.9613 354.0977 354.2340 354.3703 354.5066 354.6429 354.7792 354.9155 355.0517 355.1880 355.3242 355.4604 355.5966 355.7328 355.8690 356.0052 356.1413 356.2775 356.4136 356.5497 356.6858 356.8219 356.9580 357.0941 357.2301 357.3662 357.5022 357.6382 357.7742 357.9102 358.0462 358.1822 358.3181 358.4541 358.5900 358.7259 358.8618 358.9977 359.1336 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Bromine oxide slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of bromine oxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of bromine oxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of bromine oxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of bromine oxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Bromine oxide effective temperature [K] Column 28: Independent uncertainty of bromine oxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of bromine oxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of bromine oxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective bromine oxide fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for bromine oxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Formaldehyde slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of formaldehyde slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of formaldehyde slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of formaldehyde slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of formaldehyde slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Formaldehyde effective temperature [K] Column 39: Independent uncertainty of formaldehyde effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of formaldehyde effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of formaldehyde effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective formaldehyde fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for formaldehyde [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Nitrous acid slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of nitrous acid slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of nitrous acid slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of nitrous acid slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of nitrous acid slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Nitrous acid effective temperature [K] Column 50: Independent uncertainty of nitrous acid effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of nitrous acid effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of nitrous acid effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective nitrous acid fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for nitrous acid [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 56: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 57: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 58: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 59: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 60: Nitrogen dioxide effective temperature [K] Column 61: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 62: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 63: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 64: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 65: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 66: Oxygen dimer slant column amount [moles squared per meter to the 5th], -9e99=fitting not successful Column 67: Independent uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 68: Structured uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 69: Common uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 70: rms-based uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 71: Oxygen dimer effective temperature [K] Column 72: Independent uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 73: Structured uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 74: Common uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 75: Effective oxygen dimer fitting wavelength [nm], -9=fitting not successful Column 76: Diffuse correction applied before fitting at effective fitting wavelength for oxygen dimer [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 77: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 78: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 79: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 80: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 81: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 82: Ozone effective temperature [K] Column 83: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 84: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 85: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 86: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 87: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 88: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 89: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 90: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 91: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 92: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 93: Sulfur dioxide effective temperature [K] Column 94: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 95: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 96: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 97: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 98: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 99: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 100: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 101: Lower limit used for wavelength scaling [nm] Column 102: Upper limit used for wavelength scaling [nm] Column 103: Order of smoothing polynomial Column 104: Smoothing polynomial coefficient, order 0 Column 105: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 106: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 107: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 108: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 109: Smoothing polynomial coefficient, order 1 Column 110: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 111: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 112: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 113: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 114: Smoothing polynomial coefficient, order 2 Column 115: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 116: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 117: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 118: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 119: Smoothing polynomial coefficient, order 3 Column 120: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 121: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 122: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 123: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 124: Smoothing polynomial coefficient, order 4 Column 125: Independent uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 126: Structured uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 127: Common uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 128: rms-based uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 129: Mean value of measured data inside fitting window [same units as measurements] Column 130: Offset polynomial coefficient, order 0 Column 131: Independent uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 132: Structured uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 133: Common uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 134: rms-based uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 135: Wavelength change polynomial coefficient, order 0 Column 136: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 137: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 138: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 139: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 140: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 141: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 142: Resolution change polynomial coefficient, order 0 Column 143: Independent uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 144: Structured uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 145: Common uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 146: rms-based uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 147: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 148: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 149: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 150: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 151: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 152: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 153: Atmospheric variability [%], 999=no atmospheric variability was determined Column 154: Wavelength effective temperature [°C], 999=no effective temperature given Column 155: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 156: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 157: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 158: Number of bright count cycles Column 159: Number of dark count cycles Column 160: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 161: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 162: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 163: Integration time [ms] Column 164: Spectrometer control temperature [°C], 999=no temperature signal Column 165: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 166: Temperature in head sensor [°C], 999=no temperature signal Column 167: Temperature at electronics board 1 [°C], 999=no temperature signal Column 168: Temperature at electronics board 2 [°C], 999=no temperature signal Column 169: Humidity in head sensor [%], -9=no humidity signal Column 170: Pressure in head sensor [hPa], -9=no pressure signal Columns 171-437: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 438-704: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250919T074323.0Z 9393.321794 198 1 42.19 2 66.90 117.95 43.07 137.82 0.00 1 0.00 1 0 33 3.846e-04 3.598e-04 1.063e-04 9.854e-05 6.444172e-07 3.233307e-08 5.554806e-08 4.196470e-07 1.218504e-07 228.28 -2.00 3.76 -2.00 340.55 0.00e+00 2.817071e-04 8.903994e-06 1.391087e-05 2.138470e-05 3.368182e-05 280.39 -2.00 20.00 -2.00 337.99 0.00e+00 2.628268e-05 1.317624e-06 1.379904e-06 2.759773e-05 5.697758e-06 280.39 -2.00 20.00 -2.00 346.63 0.00e+00 2.918614e-04 3.832994e-06 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20250919T075418.5Z 9393.329381 203 1 49.25 2 65.37 120.42 41.99 141.32 0.00 1 0.00 1 0 33 3.316e-04 3.037e-04 9.207e-05 8.547e-05 3.636007e-07 2.797720e-08 5.430565e-08 4.196759e-07 1.050474e-07 228.27 -2.00 3.76 -2.00 340.46 0.00e+00 3.040772e-04 7.718504e-06 1.231652e-05 2.136682e-05 2.897992e-05 280.39 -2.00 20.00 -2.00 337.94 0.00e+00 6.150030e-06 1.144860e-06 1.494877e-06 2.759761e-05 4.922439e-06 280.39 -2.00 20.00 -2.00 346.53 0.00e+00 3.272046e-04 3.330577e-06 2.034018e-05 1.170637e-05 1.400039e-05 280.39 -2.00 20.00 -2.00 345.17 0.00e+00 4.808766e+05 7.072672e+03 3.472936e+04 2.172116e+05 2.703416e+04 262.91 -2.00 11.42 -2.00 352.04 0.00e+00 2.646687e-01 1.088626e-04 2.282074e-03 3.270954e-03 3.505228e-04 228.27 -2.00 3.76 -2.00 330.63 0.00e+00 -1.652813e-03 1.521396e-04 8.391957e-04 1.510027e-04 3.974637e-04 280.39 -2.00 20.00 -2.00 328.57 0.00e+00 2.384 0.000 319.50 362.20 4 3.6945e-01 1.1065e-04 1.6564e-02 1.5932e-03 4.5041e-04 -1.3967e-02 2.9349e-05 2.5887e-03 3.0997e-04 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