File name: Pandora127s1_Mainz-MPIC_20251017_L2Fit_fwvt1c8d20250721p1-8.txt File generation date: 20251017T232015.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Thomas Wagner Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 127 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora127_OF_v4d20210611.txt Instrument calibration file used: Pandora127s1_CF_v8d20250721.txt Level 1 file used: Pandora127s1_Mainz-MPIC_20251017_L1_smca1c8d20250721p1-8.txt Full location name: Max-Planck-Institute for Chemistry, Mainz Short location name: Mainz-MPIC Country of location: Germany Location latitude [deg]: 49.9910 Location longitude [deg]: 8.2280 Location altitude [m]: 125 Local noon date: 20251017 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1649 1799 Nominal wavelengths inside fitting window [nm]: 492.0928 492.2131 492.3335 492.4538 492.5741 492.6944 492.8147 492.9349 493.0552 493.1754 493.2956 493.4158 493.5360 493.6562 493.7763 493.8964 494.0165 494.1366 494.2567 494.3768 494.4968 494.6168 494.7368 494.8568 494.9768 495.0968 495.2167 495.3366 495.4565 495.5764 495.6963 495.8161 495.9360 496.0558 496.1756 496.2954 496.4151 496.5349 496.6546 496.7743 496.8940 497.0137 497.1334 497.2530 497.3727 497.4923 497.6119 497.7315 497.8510 497.9706 498.0901 498.2096 498.3291 498.4486 498.5680 498.6875 498.8069 498.9263 499.0457 499.1651 499.2844 499.4038 499.5231 499.6424 499.7617 499.8810 500.0002 500.1195 500.2387 500.3579 500.4771 500.5962 500.7154 500.8345 500.9536 501.0727 501.1918 501.3109 501.4299 501.5490 501.6680 501.7870 501.9059 502.0249 502.1439 502.2628 502.3817 502.5006 502.6195 502.7383 502.8572 502.9760 503.0948 503.2136 503.3324 503.4511 503.5699 503.6886 503.8073 503.9260 504.0446 504.1633 504.2819 504.4005 504.5191 504.6377 504.7563 504.8748 504.9934 505.1119 505.2304 505.3489 505.4673 505.5858 505.7042 505.8226 505.9410 506.0594 506.1777 506.2961 506.4144 506.5327 506.6510 506.7693 506.8875 507.0057 507.1240 507.2422 507.3604 507.4785 507.5967 507.7148 507.8329 507.9510 508.0691 508.1872 508.3052 508.4232 508.5413 508.6593 508.7772 508.8952 509.0131 509.1311 509.2490 509.3669 509.4847 509.6026 509.7204 509.8382 509.9560 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-252: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 253-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20251017T082756.4Z 9421.352736 243 1 17.96 2 69.35 136.10 41.03 182.55 0.00 1 0.00 1 0 15 3.196e-03 3.163e-03 4.461e-04 4.452e-04 2.062666e+03 2.517990e+01 1.558886e+02 -6.000000e+00 1.686492e+02 276.72 -2.00 20.00 -2.00 505.27 0.00e+00 5.332843e-04 1.189683e-05 3.043857e-05 -6.000000e+00 8.723132e-05 276.72 -2.00 20.00 -2.00 500.45 0.00e+00 1.168044e-01 8.657606e-03 1.571170e-02 -6.000000e+00 6.233667e-02 224.42 -2.00 3.76 -2.00 502.04 0.00e+00 2.807 0.000 489.00 513.00 1 5.1178e+00 6.6128e-04 4.2322e-03 -6.0000e+00 4.7633e-03 1.7213e-02 1.7241e-04 4.3355e-04 -6.0000e+00 1.2466e-03 7.7794e-03 2.0387e-04 3.9954e-05 2.3342e-05 -6.0000e+00 2.9468e-04 4.8998e-03 -7.4038e-05 12 1 1 12 1 1 48.33 20.53 1.99 0.00490 0.00631 46 30 1 2 0 382.000 19.93 20.53 21.34 25.39 25.39 0.1 953.28 -587 -426 -257 -26 103 470 465 358 459 271 269 -31 -234 -335 -402 -420 -115 44 99 -82 183 152 166 377 232 395 453 179 -294 -381 -401 -348 -110 367 64 95 235 30 -168 -117 -50 -120 185 176 358 337 340 258 146 -107 -425 -606 -1629 -574 -332 -163 -153 30 24 138 275 329 374 351 344 204 262 24 -79 -249 -287 -153 -120 199 51 -141 -224 -144 -315 -388 -426 -307 -450 -282 -64 -224 -183 -92 -133 -147 8 289 383 319 350 454 190 -57 -251 -574 -672 -579 -336 -7 23 -207 -114 -204 -322 -148 31 -98 176 84 188 358 618 476 428 258 197 42 40 335 117 170 255 252 310 333 228 -85 -39 -265 -353 -298 -106 -166 -157 173 63 115 155 330 341 160 20 -266 -429 -437 -343 -577 -427 -258 -26 107 494 496 375 478 286 280 -32 -237 -336 -401 -421 -117 46 103 -86 192 160 174 397 245 418 475 186 -307 -384 -398 -346 -112 374 68 100 246 31 -172 -119 -50 -123 191 184 376 355 356 266 148 -109 -422 -587 -1572 -552 -328 -166 -155 31 24 141 279 336 383 360 350 204 258 24 -78 -244 -279 -148 -118 198 50 -141 -221 -140 -302 -370 -407 -296 -438 -276 -63 -218 -178 -89 -130 -143 8 286 386 324 353 450 185 -56 -240 -538 -624 -542 -323 -7 23 -204 -114 -201 -313 -144 30 -98 174 83 188 360 623 482 432 257 193 42 40 328 115 169 252 249 305 328 224 -82 -38 -249 -330 -280 -102 -163 -152 169 62 114 154 329 342 160 19 -258 -416 -418 -328 SQ 20251017T083412.9Z 9421.357094 247 1 48.84 2 68.66 137.58 41.12 184.87 0.00 1 0.00 1 0 15 3.216e-03 3.201e-03 6.872e-04 6.854e-04 2.036758e+03 3.906660e+01 1.541118e+02 -6.000000e+00 1.697040e+02 276.72 -2.00 20.00 -2.00 505.27 0.00e+00 5.128271e-04 1.828640e-05 3.016397e-05 -6.000000e+00 8.777690e-05 276.72 -2.00 20.00 -2.00 500.40 0.00e+00 1.316133e-01 1.335194e-02 1.539159e-02 -6.000000e+00 6.272636e-02 224.42 -2.00 3.76 -2.00 502.00 0.00e+00 2.722 0.000 489.00 513.00 1 6.7255e+00 1.0182e-03 4.1107e-03 -6.0000e+00 4.7931e-03 1.6219e-02 2.6626e-04 4.2359e-04 -6.0000e+00 1.2544e-03 1.5761e-03 2.6999e-04 6.1616e-05 2.2605e-05 -6.0000e+00 2.9653e-04 4.5649e-03 -7.1627e-05 10 0 0 10 0 0 93.85 20.55 2.01 0.00456 0.00644 37 9 1 2 0 1319.860 20.17 20.55 21.22 25.39 25.28 0.1 952.94 -562 -514 -60 -139 209 383 483 489 412 363 287 118 -196 -349 -440 -383 -168 25 12 -107 389 65 144 305 239 311 469 284 -356 -446 -234 -561 -130 330 178 3 308 58 -188 -237 -10 -87 69 178 308 356 363 264 125 -129 -397 -617 -1650 -603 -294 -29 -116 113 -12 56 238 297 317 388 228 257 232 87 -197 -281 -256 -217 -155 141 2 -100 -210 -179 -270 -267 -292 -389 -399 -158 -66 -121 -263 -56 -82 -214 -21 324 389 293 465 244 87 15 -280 -533 -652 -554 -381 97 -67 -159 31 -347 -368 -173 -125 -37 41 205 272 415 595 564 278 407 101 40 11 209 117 102 196 324 272 411 235 -138 -21 -298 -332 -317 -94 -175 -149 166 137 70 284 368 264 255 -72 -151 -426 -347 -307 -558 -496 -59 -143 220 411 526 512 430 391 305 123 -203 -357 -448 -392 -174 26 13 -113 409 68 152 321 253 329 493 295 -362 -460 -236 -571 -135 338 188 3 323 60 -193 -242 -10 -90 71 186 325 376 381 273 127 -128 -402 -609 -1624 -591 -296 -29 -118 115 -12 57 242 303 325 398 232 258 229 85 -190 -268 -253 -215 -148 137 2 -98 -201 -168 -263 -260 -284 -365 -378 -151 -63 -118 -257 -55 -80 -210 -20 322 393 299 469 243 84 15 -260 -487 -617 -505 -357 94 -68 -161 31 -343 -359 -168 -123 -37 41 201 268 411 590 562 276 399 102 40 11 206 115 102 194 321 269 404 231 -135 -20 -281 -311 -298 -90 -172 -142 159 133 69 277 361 261 251 -71 -143 -414 -332 -294 SQ 20251017T084405.4Z 9421.363951 251 1 48.71 2 67.61 139.95 41.34 188.48 0.00 1 0.00 1 0 15 3.267e-03 3.244e-03 4.675e-04 4.660e-04 1.956017e+03 2.650009e+01 1.498685e+02 -6.000000e+00 1.723936e+02 276.72 -2.00 20.00 -2.00 505.26 0.00e+00 5.596802e-04 1.240943e-05 3.239909e-05 -6.000000e+00 8.916680e-05 276.72 -2.00 20.00 -2.00 500.38 0.00e+00 1.205464e-01 9.067079e-03 1.454509e-02 -6.000000e+00 6.371650e-02 224.42 -2.00 3.76 -2.00 501.98 0.00e+00 2.604 0.000 489.00 513.00 1 6.0222e+00 6.9107e-04 3.9435e-03 -6.0000e+00 4.8688e-03 1.6606e-02 1.8096e-04 4.0256e-04 -6.0000e+00 1.2741e-03 3.2386e-03 2.1058e-04 4.1883e-05 2.2931e-05 -6.0000e+00 3.0121e-04 4.4124e-03 -6.6139e-05 10 0 0 10 0 0 99.01 20.54 2.01 0.00441 0.00587 79 19 1 2 0 616.520 19.85 20.54 21.18 25.39 25.39 0.1 953.82 -658 -380 -177 -64 115 589 438 464 471 332 287 -56 -187 -428 -366 -413 -141 85 -19 -51 172 157 88 325 234 380 440 240 -300 -399 -321 -437 -67 383 105 44 191 16 -65 -179 10 -124 141 275 334 386 263 279 125 -149 -411 -587 -1665 -662 -223 -252 -122 -56 103 59 246 354 316 432 342 195 141 95 -117 -368 -287 -122 -168 196 5 -76 -171 -157 -277 -285 -377 -455 -360 -252 1 -245 -182 -111 -162 -166 -51 320 356 316 330 430 164 8 -238 -570 -810 -557 -460 24 -79 -111 -48 -285 -266 -97 -107 -48 160 279 266 449 518 453 261 242 176 51 47 277 194 125 352 169 366 351 243 -125 -29 -176 -450 -311 -117 -170 -77 109 9 130 218 368 402 287 -42 -264 -370 -447 -371 -655 -368 -177 -66 122 634 459 489 494 344 306 -59 -194 -440 -375 -425 -147 87 -20 -54 182 167 94 345 250 404 465 251 -307 -412 -326 -445 -70 394 112 47 202 17 -67 -183 10 -128 147 289 353 410 278 291 128 -149 -400 -582 -1645 -652 -225 -251 -124 -58 106 61 252 364 327 445 350 197 140 93 -113 -353 -273 -115 -162 191 5 -74 -165 -148 -259 -266 -353 -430 -342 -241 1 -240 -179 -109 -159 -163 -50 320 362 324 335 430 161 8 -223 -523 -738 -511 -434 24 -80 -113 -49 -283 -260 -95 -106 -48 157 275 264 447 518 455 262 239 171 51 46 273 193 120 336 161 348 333 230 -123 -28 -167 -424 -294 -113 -160 -74 106 8 127 215 364 399 284 -41 -253 -346 -429 -357 SQ 20251017T094336.0Z 9421.405278 286 1 9.85 2 62.49 155.14 44.62 209.17 0.00 1 0.00 1 0 15 3.616e-03 3.590e-03 1.575e-03 1.571e-03 1.377951e+03 8.688780e+01 1.026252e+02 -6.000000e+00 1.907730e+02 276.71 -2.00 20.00 -2.00 505.25 0.00e+00 6.532093e-04 4.193876e-05 3.562791e-05 -6.000000e+00 9.867100e-05 276.71 -2.00 20.00 -2.00 500.40 0.00e+00 1.043036e-01 3.058563e-02 1.208167e-02 -6.000000e+00 7.048487e-02 224.42 -2.00 3.76 -2.00 502.00 0.00e+00 2.154 0.000 489.00 513.00 1 6.9202e+00 2.3368e-03 3.3046e-03 -6.0000e+00 5.3864e-03 1.7518e-02 6.1099e-04 3.1377e-04 -6.0000e+00 1.4089e-03 1.4066e-03 -3.1749e-04 1.4163e-04 1.7831e-05 -6.0000e+00 3.3326e-04 4.2128e-03 -3.9432e-05 12 1 1 12 1 1 -3.74 20.59 2.07 0.00421 0.00201 4 6 1 2 0 1968.810 20.08 20.59 21.99 25.47 25.39 0.1 958.13 -828 -352 -137 -289 160 366 519 286 580 317 468 135 -188 -442 -575 -168 -269 -135 -167 169 232 12 53 126 497 390 500 463 -418 -221 -484 -228 11 394 223 16 155 -55 -115 -89 -36 -186 230 125 142 269 416 480 75 -359 -377 -670 -1614 -480 -177 -226 -35 -25 219 580 179 88 546 328 242 -77 197 38 -24 -399 -495 -130 12 329 329 -165 -113 -96 -157 -148 -434 -591 -651 -558 -60 -210 -198 -54 -299 -127 -15 323 168 341 702 310 299 -205 -69 -933 -574 -542 -238 -256 42 186 -76 -307 -445 -118 -222 265 25 349 394 490 625 495 385 387 140 -118 215 232 48 -128 315 34 202 581 298 -66 226 -291 -454 -287 -83 -153 -66 91 15 4 310 -43 457 467 -380 -204 -604 -511 5 -808 -349 -136 -297 168 380 547 305 613 331 481 142 -194 -451 -584 -171 -279 -140 -177 180 247 13 57 134 532 405 532 486 -430 -226 -487 -229 11 407 231 17 160 -58 -120 -92 -37 -193 240 128 147 279 429 502 78 -362 -380 -658 -1579 -468 -177 -226 -36 -26 226 594 184 91 549 331 249 -79 197 37 -24 -385 -487 -127 12 320 324 -163 -109 -94 -151 -142 -421 -579 -624 -539 -59 -207 -195 -54 -295 -126 -15 324 166 340 694 303 295 -198 -65 -893 -541 -516 -225 -252 41 184 -74 -297 -436 -115 -214 258 25 349 398 496 635 491 391 388 138 -115 207 223 46 -124 305 33 196 559 286 -62 216 -276 -427 -271 -80 -147 -64 90 15 4 309 -42 446 454 -379 -198 -573 -477 5 SQ 20251017T110404.0Z 9421.461158 332 1 48.82 2 59.45 177.61 53.24 232.51 0.00 1 0.00 1 0 15 4.122e-03 4.087e-03 1.644e-03 1.638e-03 1.599839e+03 9.230452e+01 1.194847e+02 -6.000000e+00 2.175123e+02 276.70 -2.00 20.00 -2.00 505.26 0.00e+00 6.978853e-04 4.365702e-05 3.968531e-05 -6.000000e+00 1.125058e-04 276.70 -2.00 20.00 -2.00 500.35 0.00e+00 4.984192e-02 3.211538e-02 1.369170e-02 -6.000000e+00 8.039564e-02 224.41 -2.00 3.76 -2.00 501.95 0.00e+00 1.960 0.000 489.00 513.00 1 8.1903e+00 2.4567e-03 3.1286e-03 -6.0000e+00 6.1433e-03 7.4970e-03 6.3955e-04 3.4159e-04 -6.0000e+00 1.6076e-03 4.0708e-04 1.0907e-04 1.4771e-04 1.9799e-05 -6.0000e+00 3.8007e-04 3.4225e-03 -5.9641e-05 11 8 0 10 0 0 99.71 20.65 1.92 0.00342 0.00418 17 4 1 2 0 2871.460 20.00 20.65 23.75 25.47 25.39 0.0 968.68 -676 -814 135 -153 184 -62 743 260 606 391 258 241 -239 39 -659 -185 161 239 -191 -116 403 -279 46 330 167 398 600 134 -541 -503 -503 -402 -237 292 -166 262 329 8 92 -129 -149 12 152 136 530 407 521 393 117 -321 -203 -808 -1915 -950 -646 -111 -282 365 141 79 521 423 492 584 234 196 243 -112 -104 -282 -170 -525 -271 -6 -31 175 19 -207 -648 -269 -303 -128 -614 -369 -81 75 -292 -414 -110 -173 -167 359 672 193 882 -7 374 -210 -423 -604 -685 -557 -354 180 70 -200 62 5 -753 -72 -373 159 -210 660 248 536 996 780 281 186 -78 -103 -43 391 -52 -115 296 290 -194 520 302 -214 -409 79 -206 -402 49 119 -237 66 251 184 144 326 245 503 -181 -201 -682 -183 -581 -661 -815 138 -154 188 -66 786 279 644 411 266 246 -241 39 -655 -184 162 248 -203 -125 431 -300 50 355 181 429 643 142 -563 -505 -496 -398 -239 305 -179 283 353 8 96 -134 -155 12 160 145 569 439 557 416 122 -327 -201 -781 -1847 -914 -638 -113 -294 382 147 83 541 442 517 613 245 202 246 -112 -103 -276 -165 -511 -266 -6 -31 175 18 -200 -622 -256 -289 -124 -599 -362 -80 75 -277 -394 -104 -164 -160 346 657 191 862 -7 355 -196 -407 -569 -639 -524 -342 170 68 -197 60 5 -716 -68 -358 154 -208 656 249 539 1002 789 284 186 -77 -100 -42 374 -51 -111 286 280 -187 499 289 -203 -382 72 -187 -369 46 113 -231 65 248 182 143 326 246 502 -180 -194 -647 -170 -544 SQ 20251017T132127.0Z 9421.556562 410 1 48.96 2 65.78 215.26 73.52 262.30 0.00 1 0.00 1 0 15 3.416e-03 3.390e-03 1.061e-03 1.056e-03 1.641732e+03 5.943362e+01 1.240928e+02 -6.000000e+00 1.802301e+02 276.69 -2.00 20.00 -2.00 505.24 0.00e+00 5.201317e-04 2.817058e-05 2.972629e-05 -6.000000e+00 9.322525e-05 276.69 -2.00 20.00 -2.00 500.32 0.00e+00 9.209414e-02 2.069632e-02 1.301005e-02 -6.000000e+00 6.662241e-02 224.40 -2.00 3.76 -2.00 501.92 0.00e+00 2.421 0.000 489.00 513.00 1 7.3794e+00 1.5832e-03 3.6472e-03 -6.0000e+00 5.0908e-03 1.5603e-02 4.1299e-04 3.5714e-04 -6.0000e+00 1.3323e-03 8.5803e-04 1.6261e-04 9.5204e-05 1.8726e-05 -6.0000e+00 3.1495e-04 3.4624e-03 -6.3761e-05 10 0 0 10 0 0 99.93 20.66 1.92 0.00346 0.00459 41 10 1 2 0 1193.880 19.99 20.66 22.88 25.47 25.39 0.1 963.06 -680 -638 -422 -37 217 470 418 532 468 238 337 42 -233 -263 -438 -403 -293 102 254 -144 263 -144 184 256 109 272 358 239 -293 -415 -560 -335 -122 289 283 30 447 26 -232 -106 -8 -79 245 309 410 477 357 422 73 -246 -533 -701 -1689 -601 -399 -247 -109 66 194 117 312 407 485 533 262 170 -32 -186 -79 -371 -62 -300 -21 112 118 50 -360 -50 -250 -249 -360 -354 -525 -270 -31 -212 -254 13 -174 -127 -185 308 383 464 443 313 141 57 -194 -629 -798 -446 -220 -88 -24 3 14 -162 -270 -250 -205 -9 154 376 389 475 305 491 503 232 -1 -76 94 341 -55 100 31 307 137 501 259 -97 -27 -279 -351 -277 -110 -158 51 63 21 4 143 177 179 336 -139 -136 -523 -251 -314 -666 -638 -436 -37 223 492 445 570 499 251 350 43 -236 -262 -436 -403 -298 106 270 -155 283 -156 198 276 119 295 385 254 -304 -418 -554 -332 -123 302 305 33 479 28 -244 -110 -8 -83 259 329 441 514 383 447 76 -251 -527 -676 -1624 -575 -392 -250 -114 69 202 122 324 425 508 559 273 175 -32 -186 -78 -363 -60 -290 -21 110 118 50 -355 -48 -238 -236 -343 -340 -509 -263 -31 -211 -254 13 -174 -120 -177 297 374 458 434 303 133 55 -185 -590 -742 -417 -211 -83 -23 3 14 -155 -254 -236 -196 -9 152 374 389 477 308 497 506 231 -1 -73 89 324 -53 96 30 295 132 478 247 -92 -25 -255 -318 -253 -102 -150 49 61 20 4 142 176 179 335 -137 -131 -493 -232 -291 SQ 20251017T132652.0Z 9421.560325 414 1 30.28 2 66.29 216.62 74.37 263.32 0.00 1 0.00 1 0 15 3.609e-03 3.601e-03 1.149e-03 1.146e-03 1.560257e+03 6.405542e+01 1.207531e+02 -6.000000e+00 1.904221e+02 276.69 -2.00 20.00 -2.00 505.25 0.00e+00 5.818718e-04 3.054508e-05 3.322745e-05 -6.000000e+00 9.849529e-05 276.69 -2.00 20.00 -2.00 500.39 0.00e+00 1.034501e-01 2.228363e-02 1.197952e-02 -6.000000e+00 7.038393e-02 224.40 -2.00 3.76 -2.00 501.99 0.00e+00 2.469 0.000 489.00 513.00 1 7.3022e+00 1.7005e-03 3.7050e-03 -6.0000e+00 5.3783e-03 1.5112e-02 4.4503e-04 3.3903e-04 -6.0000e+00 1.4074e-03 9.1921e-04 1.7072e-04 1.0322e-04 1.9692e-05 -6.0000e+00 3.3274e-04 3.6938e-03 -5.9123e-05 12 1 1 12 1 1 96.74 20.66 2.05 0.00369 0.00488 10 4 1 2 0 2751.920 20.00 20.66 22.84 25.47 25.39 0.1 962.93 -655 -522 -45 90 117 378 715 355 475 292 474 -142 -235 -466 -555 -300 -295 198 45 -24 147 13 112 315 349 429 548 199 -375 -629 -430 -480 -207 221 113 59 436 61 -208 28 -143 35 -9 306 550 382 262 285 385 -229 -401 -633 -1803 -891 -167 -222 -81 206 297 195 138 444 250 451 328 260 109 -30 -183 -371 -174 -140 1 131 -191 -51 -320 -339 -320 -136 -227 -462 -318 -275 -151 -51 -195 -284 -156 -147 -208 579 327 393 528 146 391 -18 -166 -788 -490 -568 -406 -61 -4 -210 3 -273 -191 13 -331 124 -86 185 300 547 704 570 552 107 314 -88 174 -16 181 -113 135 474 116 235 258 -255 37 -277 -545 -335 -193 -64 -219 39 79 51 335 417 327 159 54 -136 -362 -259 -300 -648 -526 -45 92 123 406 745 373 498 302 502 -150 -243 -477 -566 -307 -307 202 47 -26 155 14 119 333 370 455 578 207 -383 -648 -435 -488 -215 227 120 63 458 64 -214 29 -146 36 -9 321 580 405 276 296 392 -229 -406 -625 -1777 -877 -168 -221 -83 212 304 199 141 455 258 464 336 262 108 -29 -178 -355 -172 -138 1 127 -188 -50 -309 -320 -312 -132 -221 -436 -303 -263 -147 -50 -192 -279 -153 -145 -206 577 331 402 536 147 383 -18 -155 -727 -465 -522 -384 -60 -4 -205 3 -270 -187 12 -328 124 -84 184 299 546 704 573 553 106 305 -85 172 -16 173 -109 129 452 111 224 245 -250 36 -262 -514 -317 -186 -60 -211 38 77 50 329 412 325 158 52 -130 -339 -248 -289 SQ 20251017T133533.8Z 9421.566364 418 1 48.82 2 67.15 218.76 75.76 264.95 0.00 1 0.00 1 0 15 3.344e-03 3.321e-03 5.296e-04 5.280e-04 1.684597e+03 2.973853e+01 1.281358e+02 -6.000000e+00 1.764209e+02 276.69 -2.00 20.00 -2.00 505.26 0.00e+00 5.660090e-04 1.406171e-05 3.209843e-05 -6.000000e+00 9.125746e-05 276.69 -2.00 20.00 -2.00 500.38 0.00e+00 1.004761e-01 1.027473e-02 1.309874e-02 -6.000000e+00 6.522276e-02 224.40 -2.00 3.76 -2.00 501.99 0.00e+00 2.555 0.000 489.00 513.00 1 6.2353e+00 7.8291e-04 3.8388e-03 -6.0000e+00 4.9837e-03 1.6261e-02 2.0526e-04 3.6405e-04 -6.0000e+00 1.3045e-03 2.6400e-03 3.2064e-04 4.7465e-05 2.0273e-05 -6.0000e+00 3.0832e-04 3.8373e-03 -7.4874e-05 10 0 0 10 0 0 97.92 20.66 1.97 0.00384 0.00606 70 16 1 2 0 697.410 20.00 20.66 22.85 25.47 25.39 0.0 962.93 -517 -414 -210 -95 147 443 501 387 485 301 261 17 -195 -331 -446 -434 -116 121 98 -90 168 166 121 345 329 360 516 227 -341 -493 -377 -464 -135 338 127 -53 261 125 -151 -84 -141 -126 138 277 292 307 378 321 143 -153 -338 -638 -1663 -610 -346 -312 -54 28 160 145 284 315 360 486 254 263 115 28 -97 -260 -206 -259 -163 108 153 -101 -295 -198 -356 -315 -387 -370 -460 -261 -26 -293 -193 -167 -97 -149 -28 316 390 286 406 475 201 -149 -269 -695 -762 -582 -294 44 7 -103 -62 -286 -304 -92 -209 -48 109 285 242 442 609 513 357 347 154 -6 112 153 121 10 331 248 224 467 263 -52 -33 -240 -378 -319 -44 -266 -88 93 35 110 324 310 334 290 17 -228 -446 -491 -343 -516 -400 -210 -98 156 477 524 407 508 312 279 18 -203 -341 -456 -446 -121 129 103 -95 177 176 127 365 349 382 545 237 -348 -510 -382 -473 -140 347 135 -57 275 130 -155 -86 -144 -130 143 290 308 325 398 333 146 -152 -328 -633 -1644 -601 -350 -311 -55 28 164 148 289 323 371 500 260 266 114 28 -94 -249 -196 -246 -157 104 150 -99 -285 -187 -333 -293 -362 -349 -438 -251 -25 -287 -190 -164 -96 -146 -27 315 395 293 413 475 198 -143 -252 -640 -694 -534 -277 43 7 -105 -62 -283 -297 -90 -207 -48 106 281 240 439 607 514 357 342 149 -6 110 151 121 9 316 237 222 462 260 -51 -32 -228 -355 -301 -43 -251 -84 90 34 107 318 306 331 286 17 -218 -416 -472 -330 SQ 20251017T142754.6Z 9421.602715 444 1 48.92 2 73.10 230.95 84.11 274.58 0.00 1 0.00 1 0 15 3.502e-03 3.467e-03 8.261e-04 8.236e-04 2.106615e+03 4.696865e+01 1.631024e+02 -6.000000e+00 1.847383e+02 276.69 -2.00 20.00 -2.00 505.27 0.00e+00 7.088803e-04 2.205783e-05 3.960445e-05 -6.000000e+00 9.555902e-05 276.69 -2.00 20.00 -2.00 500.38 0.00e+00 2.279148e-01 1.610368e-02 1.592102e-02 -6.000000e+00 6.829342e-02 224.40 -2.00 3.76 -2.00 501.99 0.00e+00 3.387 0.001 489.00 513.00 1 6.9201e+00 1.2324e-03 5.0447e-03 -6.0000e+00 5.2184e-03 1.5348e-02 3.2065e-04 4.6112e-04 -6.0000e+00 1.3658e-03 1.1702e-03 3.5029e-04 7.3923e-05 2.4545e-05 -6.0000e+00 3.2284e-04 4.2606e-03 -7.1677e-05 10 0 0 10 0 0 99.03 20.62 1.95 0.00426 0.00669 33 8 1 2 0 1482.250 19.99 20.62 22.00 25.47 25.39 0.1 957.86 -661 -551 -104 0 82 389 562 364 546 470 338 17 -185 -248 -507 -391 -249 158 -24 -85 215 71 95 337 226 349 568 157 -197 -442 -476 -585 -68 424 70 103 129 54 -191 -107 -129 -5 196 310 339 234 376 248 269 -180 -504 -664 -1658 -575 -410 -230 45 -89 103 15 184 436 277 458 313 212 301 9 28 -356 -254 -290 8 83 137 -246 -225 2 -421 -389 -475 -434 -489 -190 -36 -261 -125 -102 -120 -107 -15 440 594 198 502 347 241 41 -293 -704 -837 -632 -374 128 -24 -147 -11 -247 -390 -269 -226 -17 -11 325 328 441 590 608 272 275 104 53 25 232 -32 123 198 204 300 564 239 -39 -71 -137 -369 -394 -121 -37 57 99 171 57 276 370 322 201 -176 -132 -428 -498 -382 -643 -548 -107 0 85 408 599 391 583 496 351 17 -187 -249 -506 -392 -253 164 -26 -92 232 77 103 364 246 380 612 168 -205 -446 -472 -584 -70 445 72 107 133 57 -201 -112 -135 -5 208 317 350 243 387 252 282 -185 -502 -645 -1606 -555 -406 -235 44 -90 104 15 184 437 279 461 313 210 306 9 28 -350 -247 -283 8 83 138 -248 -223 2 -405 -373 -457 -421 -478 -186 -35 -250 -120 -98 -115 -103 -15 429 588 198 497 339 230 39 -281 -664 -782 -595 -361 122 -24 -146 -11 -239 -373 -258 -219 -17 -11 327 333 448 603 623 279 278 103 52 24 225 -31 120 194 199 292 546 232 -37 -67 -127 -340 -366 -115 -36 56 98 171 57 279 358 312 195 -169 -129 -411 -471 -362 SQ 20251017T143703.1Z 9421.609064 448 1 19.79 2 74.26 232.97 85.56 276.24 0.00 1 0.00 1 0 15 3.398e-03 3.366e-03 3.380e-04 3.374e-04 2.305895e+03 1.917929e+01 1.737872e+02 -6.000000e+00 1.792956e+02 276.68 -2.00 20.00 -2.00 505.26 0.00e+00 6.803210e-04 9.020844e-06 3.827140e-05 -6.000000e+00 9.274357e-05 276.68 -2.00 20.00 -2.00 500.47 0.00e+00 2.172678e-01 6.553519e-03 1.778739e-02 -6.000000e+00 6.628066e-02 224.40 -2.00 3.76 -2.00 502.05 0.00e+00 3.621 0.001 489.00 513.00 1 4.5443e+00 5.0046e-04 5.3932e-03 -6.0000e+00 5.0646e-03 1.0486e-02 1.3053e-04 5.0542e-04 -6.0000e+00 1.3255e-03 1.2195e-02 2.6711e-04 3.0277e-05 2.6651e-05 -6.0000e+00 3.1333e-04 4.1965e-03 -7.0304e-05 12 1 1 12 1 1 99.45 20.61 1.87 0.00420 0.00605 81 47 1 2 0 241.230 19.99 20.61 21.96 25.47 25.39 0.1 957.72 -688 -511 -235 -42 124 473 491 474 376 305 280 10 -281 -297 -463 -400 -125 66 42 -95 150 106 102 319 304 346 467 237 -272 -441 -419 -421 -109 387 123 173 264 65 -136 -104 -34 -22 137 266 391 361 367 267 195 -142 -489 -613 -1678 -664 -295 -191 -103 54 50 112 301 413 391 432 357 243 218 27 -139 -370 -292 -174 -125 64 75 -132 -214 -194 -304 -399 -464 -359 -421 -224 -58 -198 -206 -148 -102 -121 -11 254 471 358 412 421 267 -11 -322 -577 -827 -583 -376 27 -28 -194 -67 -277 -307 -165 -45 -99 207 194 277 487 629 550 345 332 188 22 87 316 116 129 260 284 258 409 209 -77 -98 -269 -465 -324 -127 -191 -68 103 101 100 177 288 325 228 -26 -262 -407 -451 -366 -670 -507 -234 -43 127 493 520 492 400 320 290 10 -283 -304 -472 -399 -126 69 44 -100 157 111 106 334 319 364 488 245 -283 -443 -414 -417 -111 394 130 183 276 67 -139 -105 -34 -23 141 277 411 380 384 277 198 -145 -486 -595 -1622 -641 -292 -190 -104 55 51 114 307 422 402 444 364 245 216 27 -139 -365 -284 -170 -123 64 73 -129 -212 -188 -292 -382 -447 -348 -412 -220 -56 -194 -202 -145 -100 -119 -11 254 477 356 418 420 261 -11 -310 -544 -773 -550 -364 26 -28 -192 -66 -275 -301 -161 -45 -97 206 195 280 493 640 562 352 335 187 22 84 305 113 126 254 277 250 397 203 -74 -95 -257 -441 -309 -123 -185 -66 103 102 101 174 285 323 226 -26 -259 -391 -427 -348