File name: Pandora56s1_MaunaLoaHI_20200822_L2Fit_fout2c8d20200803p1-8.txt File generation date: 20250131T115340.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 56 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora56_OF_v1d20200131.txt Instrument calibration file used: Pandora56s1_CF_v8d20200803.txt Level 1 file used: Pandora56s1_MaunaLoaHI_20200822_L1_smca1c8d20200803p1-8.txt Full location name: Mauna Loa Short location name: MaunaLoaHI Country of location: USA Location latitude [deg]: 19.4795 Location longitude [deg]: -155.6027 Location altitude [m]: 4169 Local noon date: 20200822 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 290 432 Nominal wavelengths inside fitting window [nm]: 305.0988 305.2393 305.3798 305.5203 305.6608 305.8013 305.9418 306.0823 306.2228 306.3632 306.5037 306.6441 306.7845 306.9249 307.0653 307.2057 307.3461 307.4865 307.6268 307.7672 307.9075 308.0478 308.1881 308.3284 308.4687 308.6090 308.7493 308.8895 309.0298 309.1700 309.3102 309.4504 309.5907 309.7308 309.8710 310.0112 310.1514 310.2915 310.4317 310.5718 310.7119 310.8520 310.9921 311.1322 311.2723 311.4123 311.5524 311.6924 311.8324 311.9725 312.1125 312.2525 312.3925 312.5324 312.6724 312.8123 312.9523 313.0922 313.2321 313.3721 313.5120 313.6518 313.7917 313.9316 314.0714 314.2113 314.3511 314.4909 314.6307 314.7705 314.9103 315.0501 315.1899 315.3296 315.4694 315.6091 315.7488 315.8885 316.0282 316.1679 316.3076 316.4473 316.5869 316.7266 316.8662 317.0058 317.1454 317.2850 317.4246 317.5642 317.7038 317.8433 317.9829 318.1224 318.2619 318.4014 318.5409 318.6804 318.8199 318.9594 319.0988 319.2383 319.3777 319.5171 319.6565 319.7959 319.9353 320.0747 320.2140 320.3534 320.4927 320.6321 320.7714 320.9107 321.0500 321.1893 321.3285 321.4678 321.6071 321.7463 321.8855 322.0248 322.1640 322.3032 322.4423 322.5815 322.7207 322.8598 322.9990 323.1381 323.2772 323.4163 323.5554 323.6945 323.8335 323.9726 324.1117 324.2507 324.3897 324.5287 324.6677 324.8067 324.9457 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Azimuth motor temperature [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given 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9.2953e-04 0.0000e+00 10 0 0 10 0 0 79.69 21.50 0.35 0.00093 -0.00126 1877 1877 1 5 0 15.810 26.32 20.00 21.50 21.53 49.60 10.2 927.95 -596 -1492 -2004 -2410 -1302 132 912 1266 840 -377 -417 405 423 457 257 -173 -253 374 441 520 598 724 1250 767 647 332 -353 -269 608 1314 1438 1335 553 -962 -1462 -512 -438 -285 -211 -1043 -1337 -1127 -1060 -914 -762 -574 -809 -380 1 488 1012 787 1037 897 639 699 413 158 282 721 917 1131 895 274 -355 -563 83 254 1044 788 3 83 -151 107 43 43 428 467 555 -156 -730 -1356 -1575 -1307 -936 -859 -627 -321 -453 -241 -68 213 469 916 1018 718 618 175 -244 -347 -364 -193 156 333 -499 -852 -625 -589 -155 1 6 -186 -64 106 247 580 584 567 188 -212 -312 -100 186 328 686 769 943 1243 721 356 12 -136 -61 131 -181 -280 -134 -183 -238 -287 -246 -290 -409 -232 -614 -814 -911 -480 47 337 473 338 -158 -174 172 182 217 134 -90 -135 203 245 294 341 413 722 462 380 199 -207 -158 332 696 779 758 328 -578 -850 -297 -260 -195 -151 -849 -1118 -978 -892 -771 -670 -496 -681 -307 1 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2.8906e-03 1.6868e-01 -2.7019e-04 3.5497e-06 1.6704e-05 -6.0000e+00 2.3106e-04 8.8877e-04 0.0000e+00 10 0 0 10 0 0 86.54 21.52 0.36 0.00089 -0.00114 1932 1932 1 5 0 15.350 26.32 20.01 21.52 21.57 49.60 10.2 927.91 -530 -1473 -2025 -2374 -1344 174 902 1279 759 -420 -528 360 468 465 264 -159 -247 314 430 502 563 735 1217 719 710 323 -328 -297 609 1257 1376 1295 544 -981 -1450 -507 -477 -318 -189 -1054 -1339 -1106 -1079 -906 -743 -562 -825 -354 20 484 995 811 1032 907 643 667 414 146 279 754 949 1150 903 300 -352 -584 83 252 1038 801 7 61 -182 99 34 31 394 478 561 -147 -748 -1398 -1557 -1319 -904 -845 -600 -311 -464 -221 -73 187 455 904 1038 715 618 173 -228 -331 -381 -190 146 357 -488 -829 -616 -576 -147 27 46 -166 -55 111 236 593 578 575 171 -224 -306 -93 153 331 685 778 933 1249 749 347 8 -133 -44 123 -170 -276 -140 -177 -242 -281 -245 -294 -396 -203 -597 -811 -884 -488 60 327 470 301 -173 -217 151 212 217 135 -86 -130 167 234 279 315 411 690 425 435 202 -200 -171 326 696 780 721 317 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3.5636e-03 -6.0000e+00 6.9862e-03 -3.0842e-03 4.0327e-05 1.0133e-03 -6.0000e+00 2.9021e-03 1.7089e-01 -2.7245e-04 3.5103e-06 1.6477e-05 -6.0000e+00 2.3198e-04 8.0716e-04 0.0000e+00 10 0 0 10 0 0 91.72 21.53 0.36 0.00081 -0.00124 1838 1838 1 5 0 16.150 26.32 20.00 21.53 21.58 51.40 10.2 927.61 -548 -1461 -2022 -2416 -1313 216 915 1308 846 -401 -465 381 441 434 291 -207 -213 362 451 519 606 725 1208 750 645 312 -316 -272 650 1264 1402 1320 532 -963 -1413 -505 -479 -283 -229 -1045 -1371 -1118 -1079 -920 -778 -563 -811 -362 23 512 1005 809 1035 905 639 677 416 179 261 747 943 1147 888 283 -383 -567 77 260 994 805 -8 68 -166 91 32 48 421 492 579 -180 -734 -1366 -1562 -1301 -920 -863 -632 -313 -458 -243 -83 221 461 927 1053 732 616 174 -218 -347 -347 -190 133 347 -503 -846 -623 -598 -156 6 28 -180 -63 106 242 587 563 556 179 -215 -329 -93 167 320 684 782 942 1254 727 341 6 -145 -46 127 -181 -268 -127 -182 -254 -290 -241 -301 -402 -218 -612 -837 -930 -493 78 343 496 346 -170 -197 165 192 209 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-2.3392e-02 1.6172e-04 7.0866e-03 -6.0000e+00 1.1727e-02 4.6949e-03 9.2474e-05 3.5276e-03 -6.0000e+00 6.9571e-03 -3.2992e-03 3.9329e-05 1.0023e-03 -6.0000e+00 2.8899e-03 1.7948e-01 -2.8904e-04 3.4246e-06 1.6415e-05 -6.0000e+00 2.3102e-04 9.7001e-04 0.0000e+00 10 0 0 10 0 0 48.14 21.54 0.36 0.00097 -0.00120 1960 1960 1 5 0 15.130 26.32 20.00 21.54 21.55 50.40 10.1 927.06 -517 -1479 -2009 -2371 -1306 167 977 1277 853 -393 -426 332 472 441 315 -207 -216 386 414 523 627 734 1213 753 668 345 -301 -279 607 1300 1379 1299 561 -980 -1401 -497 -464 -268 -173 -1039 -1347 -1099 -1050 -928 -774 -555 -815 -367 29 503 987 788 1058 914 670 675 423 172 279 758 932 1151 883 288 -377 -583 75 246 1045 785 11 78 -142 109 39 47 413 474 554 -167 -745 -1356 -1579 -1303 -916 -832 -632 -313 -460 -230 -85 207 456 906 1029 703 616 170 -228 -353 -347 -192 150 347 -506 -851 -617 -572 -157 20 30 -174 -63 90 222 574 558 573 166 -214 -318 -95 178 325 698 788 926 1261 723 345 -12 -145 -66 133 -171 -257 -127 -181 -239 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0.00e+00 1.368 0.000 302.00 328.00 3 8.5734e-02 1.4357e-04 1.0954e-02 -6.0000e+00 1.0789e-02 -2.3333e-02 1.5926e-04 7.0407e-03 -6.0000e+00 1.1737e-02 4.4999e-03 9.1076e-05 3.5049e-03 -6.0000e+00 6.9631e-03 -3.2091e-03 3.8708e-05 9.9506e-04 -6.0000e+00 2.8925e-03 1.8482e-01 -2.8672e-04 3.3735e-06 1.6305e-05 -6.0000e+00 2.3121e-04 8.6341e-04 0.0000e+00 10 0 0 10 0 0 22.80 21.55 0.36 0.00086 -0.00129 2007 2007 1 5 0 14.770 26.32 20.00 21.55 21.53 47.90 10.1 926.90 -582 -1429 -1990 -2337 -1302 222 1006 1317 880 -394 -450 405 460 437 292 -200 -246 371 423 484 596 765 1215 705 655 338 -316 -257 662 1286 1396 1305 568 -944 -1408 -510 -474 -275 -209 -1020 -1349 -1096 -1089 -938 -775 -552 -806 -368 20 475 1003 817 1031 912 641 718 416 172 271 746 933 1173 877 287 -368 -569 77 238 1027 804 14 100 -161 100 47 66 408 494 565 -177 -755 -1371 -1578 -1303 -903 -861 -625 -315 -464 -236 -85 200 461 907 1042 726 621 168 -227 -350 -358 -199 155 364 -501 -841 -624 -601 -154 15 26 -187 -62 95 228 582 561 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