File name: Pandora56s1_MaunaLoaHI_20200830_L2Fit_ffus5c8d20200803p1-8.txt File generation date: 20250131T115353.7Z Data description: Level 2 spectral fitting results file Data file version: ffus5c8p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 56 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora56_OF_v1d20200131.txt Instrument calibration file used: Pandora56s1_CF_v8d20200803.txt Level 1 file used: Pandora56s1_MaunaLoaHI_20200830_L1_smca1c8d20200803p1-8.txt Full location name: Mauna Loa Short location name: MaunaLoaHI Country of location: USA Location latitude [deg]: 19.4795 Location longitude [deg]: -155.6027 Location altitude [m]: 4169 Local noon date: 20200830 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 415 681 Nominal wavelengths inside fitting window [nm]: 322.5815 322.7207 322.8598 322.9990 323.1381 323.2772 323.4163 323.5554 323.6945 323.8335 323.9726 324.1117 324.2507 324.3897 324.5287 324.6677 324.8067 324.9457 325.0847 325.2236 325.3626 325.5015 325.6404 325.7793 325.9182 326.0571 326.1960 326.3349 326.4737 326.6126 326.7514 326.8902 327.0290 327.1678 327.3066 327.4454 327.5841 327.7229 327.8616 328.0003 328.1391 328.2778 328.4164 328.5551 328.6938 328.8325 328.9711 329.1097 329.2484 329.3870 329.5256 329.6642 329.8027 329.9413 330.0798 330.2184 330.3569 330.4954 330.6339 330.7724 330.9109 331.0494 331.1879 331.3263 331.4647 331.6032 331.7416 331.8800 332.0184 332.1567 332.2951 332.4335 332.5718 332.7101 332.8485 332.9868 333.1251 333.2634 333.4016 333.5399 333.6781 333.8164 333.9546 334.0928 334.2310 334.3692 334.5074 334.6456 334.7837 334.9219 335.0600 335.1981 335.3362 335.4743 335.6124 335.7505 335.8885 336.0266 336.1646 336.3027 336.4407 336.5787 336.7167 336.8546 336.9926 337.1306 337.2685 337.4064 337.5444 337.6823 337.8202 337.9580 338.0959 338.2338 338.3716 338.5095 338.6473 338.7851 338.9229 339.0607 339.1985 339.3362 339.4740 339.6117 339.7494 339.8872 340.0249 340.1626 340.3002 340.4379 340.5756 340.7132 340.8509 340.9885 341.1261 341.2637 341.4013 341.5388 341.6764 341.8140 341.9515 342.0890 342.2265 342.3640 342.5015 342.6390 342.7765 342.9139 343.0514 343.1888 343.3262 343.4636 343.6010 343.7384 343.8758 344.0131 344.1505 344.2878 344.4251 344.5624 344.6997 344.8370 344.9743 345.1115 345.2488 345.3860 345.5232 345.6604 345.7976 345.9348 346.0720 346.2092 346.3463 346.4835 346.6206 346.7577 346.8948 347.0319 347.1690 347.3060 347.4431 347.5801 347.7172 347.8542 347.9912 348.1282 348.2652 348.4021 348.5391 348.6760 348.8130 348.9499 349.0868 349.2237 349.3606 349.4974 349.6343 349.7711 349.9080 350.0448 350.1816 350.3184 350.4552 350.5919 350.7287 350.8654 351.0022 351.1389 351.2756 351.4123 351.5490 351.6857 351.8223 351.9590 352.0956 352.2322 352.3688 352.5054 352.6420 352.7786 352.9152 353.0517 353.1882 353.3248 353.4613 353.5978 353.7343 353.8707 354.0072 354.1437 354.2801 354.4165 354.5529 354.6893 354.8257 354.9621 355.0985 355.2348 355.3711 355.5075 355.6438 355.7801 355.9164 356.0526 356.1889 356.3252 356.4614 356.5976 356.7338 356.8700 357.0062 357.1424 357.2786 357.4147 357.5508 357.6870 357.8231 357.9592 358.0953 358.2313 358.3674 358.5034 358.6395 358.7755 358.9115 359.0475 359.1835 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Bromine oxide slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of bromine oxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of bromine oxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of bromine oxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of bromine oxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Bromine oxide effective temperature [K] Column 28: Independent uncertainty of bromine oxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of bromine oxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of bromine oxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective bromine oxide fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for bromine oxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Formaldehyde slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of formaldehyde slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of formaldehyde slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of formaldehyde slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of formaldehyde slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Formaldehyde effective temperature [K] Column 39: Independent uncertainty of formaldehyde effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of formaldehyde effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of formaldehyde effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective formaldehyde fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for formaldehyde [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Nitrous acid slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of nitrous acid slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of nitrous acid slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of nitrous acid slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of nitrous acid slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Nitrous acid effective temperature [K] Column 50: Independent uncertainty of nitrous acid effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of nitrous acid effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of nitrous acid effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective nitrous acid fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for nitrous acid [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 56: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 57: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 58: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 59: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 60: Nitrogen dioxide effective temperature [K] Column 61: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 62: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 63: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 64: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 65: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 66: Oxygen dimer slant column amount [moles squared per meter to the 5th], -9e99=fitting not successful Column 67: Independent uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 68: Structured uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 69: Common uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 70: rms-based uncertainty of oxygen dimer slant column amount [moles squared per meter to the 5th], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 71: Oxygen dimer effective temperature [K] Column 72: Independent uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 73: Structured uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 74: Common uncertainty of oxygen dimer effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 75: Effective oxygen dimer fitting wavelength [nm], -9=fitting not successful Column 76: Diffuse correction applied before fitting at effective fitting wavelength for oxygen dimer [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 77: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 78: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 79: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 80: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 81: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 82: Ozone effective temperature [K] Column 83: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 84: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 85: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 86: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 87: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 88: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 89: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 90: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 91: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 92: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 93: Sulfur dioxide effective temperature [K] Column 94: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 95: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 96: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 97: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 98: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 99: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 100: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 101: Lower limit used for wavelength scaling [nm] Column 102: Upper limit used for wavelength scaling [nm] Column 103: Order of smoothing polynomial Column 104: Smoothing polynomial coefficient, order 0 Column 105: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 106: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 107: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 108: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 109: Smoothing polynomial coefficient, order 1 Column 110: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 111: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 112: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 113: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 114: Smoothing polynomial coefficient, order 2 Column 115: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 116: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 117: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 118: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 119: Smoothing polynomial coefficient, order 3 Column 120: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 121: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 122: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 123: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 124: Smoothing polynomial coefficient, order 4 Column 125: Independent uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 126: Structured uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 127: Common uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 128: rms-based uncertainty of smoothing polynomial coefficient, order 4, -9=fitting not successful Column 129: Mean value of measured data inside fitting window [same units as measurements] Column 130: Offset polynomial coefficient, order 0 Column 131: Independent uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 132: Structured uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 133: Common uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 134: rms-based uncertainty of offset polynomial coefficient, order 0, -9=fitting not successful Column 135: Wavelength change polynomial coefficient, order 0 Column 136: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 137: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 138: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 139: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 140: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 141: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 142: Resolution change polynomial coefficient, order 0 Column 143: Independent uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 144: Structured uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 145: Common uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 146: rms-based uncertainty of resolution change polynomial coefficient, order 0, -9=fitting not successful Column 147: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 148: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 149: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 150: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 151: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 152: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 153: Atmospheric variability [%], 999=no atmospheric variability was determined Column 154: Wavelength effective temperature [°C], 999=no effective temperature given Column 155: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 156: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 157: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 158: Number of bright count cycles Column 159: Number of dark count cycles Column 160: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 161: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 162: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 163: Integration time [ms] Column 164: Temperature at electronics board [°C], 999=no temperature signal Column 165: Spectrometer control temperature [°C], 999=no temperature signal Column 166: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 167: Temperature in head sensor [°C], 999=no temperature signal Column 168: Azimuth motor temperature [°C], 999=no temperature signal Column 169: Humidity in head sensor [%], -9=no humidity signal Column 170: Pressure in head sensor [hPa], -9=no pressure signal Columns 171-437: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 438-704: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20200830T162345.2Z 7547.683162 1544 1 30.33 2 86.92 81.90 122.93 256.42 0.00 1 0.00 1 0 33 4.839e-03 1.407e-03 4.998e-03 1.381e-03 1.431273e-06 5.537053e-07 1.165188e-07 3.425997e-07 1.574284e-06 225.44 -2.00 3.11 -2.00 347.46 0.00e+00 3.096748e-04 1.651586e-04 5.340259e-05 6.594387e-06 3.796561e-04 271.97 -2.00 20.00 -2.00 346.32 0.00e+00 -2.971565e-05 1.878833e-05 1.989502e-06 2.275454e-05 7.229575e-05 271.97 -2.00 20.00 -2.00 351.20 0.00e+00 4.701724e-04 5.466988e-05 2.832715e-05 1.644042e-06 2.058888e-04 271.97 -2.00 20.00 -2.00 350.74 0.00e+00 2.507994e+06 1.581272e+05 9.282870e+04 1.741242e+05 3.883690e+05 252.51 -2.00 10.06 -2.00 354.84 0.00e+00 1.179181e+00 5.558404e-03 6.980063e-03 8.265539e-04 7.067798e-03 225.44 -2.00 3.11 -2.00 338.12 0.00e+00 -9.928940e-03 1.004978e-02 4.284433e-03 4.939237e-05 6.997697e-03 271.97 -2.00 20.00 -2.00 340.88 0.00e+00 13.638 0.011 319.50 362.20 4 9.9103e-01 1.6272e-03 5.8922e-02 1.2958e-03 5.0077e-03 -1.0345e-01 8.1305e-04 9.2635e-03 2.2579e-04 1.5581e-03 1.5172e-03 1.4008e-03 1.7555e-03 1.1914e-04 2.8805e-03 -1.5550e-03 1.2340e-03 1.1920e-03 3.2044e-05 1.2705e-03 1.6174e-03 1.2754e-03 6.8726e-04 1.0166e-04 2.0076e-03 1.3338e-03 -1.7901e-04 5.3734e-04 1.2748e-04 1.2750e-05 3.0222e-04 -3.4665e-05 1.8920e-05 4.9809e-06 5.1288e-07 7.4827e-05 6.3191e-03 0.0000e+00 -3.5509e-01 8.7479e-02 1.8388e-02 7.3603e-04 1.7003e-01 12 9 8 11 8 0 8.02 20.51 1.15 0.00632 0.00589 18 18 1 5 0 1684.570 25.47 20.24 20.51 15.00 41.30 10.3 866.97 3097 3490 2417 1065 -102 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-130 62 9 -91 180 -275 27 -107 -227 -179 58 2 -43 63 155 176 136 72 -8 -62 60 22 106 10 4 152 -239 117 21 -35 -282 -29 -164 -120 -94 -28 -34 172 13 -117 42 192 -147 18 16 199 35 171 164 127 -107 -104 60 -9 -13 -76 -94 -266 147 38 -55 170 -68 92 121 218 12 -136 -145 -65 -8 -309 -191 -171 34 7 274 52 -17 56 -50 -17 132 -10 -109 -39 -25 14 -197 189 -124 -44 -110 52 -235 77 -96 74 -53 -177 -189 1 105 249 -139 -132 -53 -103 223 -131 70 35 272 49 -183 61 268 -193 -79 70 -67 241 307 -40 104 194 -112 -20 63 -37 115 -205 59 -132 -81 -194 6 -10 214 48 40 184 24 52 -89 -206 -114 -174 36 -65 -217 -1 -225 2 148 155 67 121 16 83 14 -114 93 64 166 124 222 -47 101 61 131 -118 -129 -86 203 -4 15 -31 -49 -78 94 128 -83 195 -14 203 -32 -168 -63 -52 121 101 -117 57 -135 -145 21 192 -160 -185 -63 32 -154 1 -122 -287 32 -35 28 146 -58 -300 45 29 -143 -113 71 -24 69 -213 -90 220 146 45 -7 170 118 5 -11 -71 91 -145 174 -62 96 -12 -119 -170 -188 -210 -84 53 150 158 -212 -55 17 -27 -33 272 73 322 113 -134 297 -286 170 -13 -165 77 151 -179 174 37 68 127 378 -207 101 15 -140 253 -369 35 -138 -303 -242 83 3 -72 109 SU 20200830T162535.9Z 7547.684443 1546 1 29.83 2 86.49 82.05 123.33 256.51 0.00 1 0.00 1 0 33 2.149e-03 1.170e-03 2.955e-03 1.040e-03 1.527077e-06 4.084017e-07 9.831640e-08 3.425601e-07 6.976415e-07 225.44 -2.00 3.11 -2.00 346.75 0.00e+00 5.319088e-04 1.195835e-04 4.857313e-05 6.614888e-06 1.698875e-04 271.97 -2.00 20.00 -2.00 345.43 0.00e+00 -3.924263e-05 1.404814e-05 2.447771e-06 2.275190e-05 3.214067e-05 271.97 -2.00 20.00 -2.00 350.79 0.00e+00 4.317222e-04 4.111019e-05 2.503683e-05 1.606579e-06 9.147966e-05 271.97 -2.00 20.00 -2.00 350.25 0.00e+00 2.378604e+06 1.140064e+05 1.011810e+05 1.741269e+05 1.738126e+05 252.51 -2.00 10.06 -2.00 354.58 0.00e+00 1.129625e+00 3.718073e-03 6.791330e-03 8.275413e-04 3.160940e-03 225.44 -2.00 3.11 -2.00 337.03 0.00e+00 9.102494e-04 6.274571e-03 3.606109e-03 6.108765e-05 3.057486e-03 271.97 -2.00 20.00 -2.00 338.82 0.00e+00 12.649 0.009 319.50 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-213 37 -142 69 62 12 92 -34 72 -19 -102 23 -139 -176 -144 59 -117 189 101 120 -37 84 -55 -70 110 142 56 -60 -25 63 -30 21 -181 108 27 -159 128 -74 -259 -88 77 -102 -135 11 -6 -21 244 213 101 64 32 102 -17 -127 5 70 -156 131 77 174 55 12 -87 -51 -52 -49 278 153 -45 -51 28 101 36 249 172 216 -189 38 173 48 75 -68 120 63 -29 -27 17 -11 -167 -159 -53 -218 -106 -201 -127 -154 49 -244 -86 -98 -165 61 -37 -60 206 -114 -101 -192 -46 -183 102 144 -104 109 177 238 98 242 83 -89 7 -195 146 -83 80 -268 10 -67 -72 -91 160 64 -167 -174 -104 -99 85 -87 -40 -7 -3 -20 49 203 289 -59 126 9 94 27 73 71 -65 -141 119 15 57 264 134 30 260 12 -54 -27 -299 -115 145 -278 -45 146 -236 -59 -18 SU 20200830T162725.0Z 7547.685706 1548 1 29.92 2 86.06 82.20 123.73 256.59 0.00 1 0.00 1 0 49 2.186e-03 9.402e-04 1.943e-03 8.192e-04 1.953279e-06 3.169523e-07 1.000141e-07 3.425301e-07 7.091659e-07 225.44 -2.00 3.11 -2.00 346.08 0.00e+00 4.190100e-04 9.178409e-05 3.958037e-05 6.622891e-06 1.740904e-04 271.97 -2.00 20.00 -2.00 344.60 0.00e+00 -3.429392e-05 1.097968e-05 1.665688e-06 2.274973e-05 3.272012e-05 271.97 -2.00 20.00 -2.00 350.40 0.00e+00 3.907920e-04 3.227284e-05 2.651436e-05 1.603083e-06 9.312971e-05 271.97 -2.00 20.00 -2.00 349.78 0.00e+00 2.164743e+06 8.658137e+04 9.204135e+04 1.741442e+05 1.778935e+05 252.51 -2.00 10.06 -2.00 354.32 0.00e+00 1.080286e+00 2.647074e-03 6.662255e-03 8.285713e-04 3.220295e-03 225.44 -2.00 3.11 -2.00 336.12 0.00e+00 -6.357917e-03 4.181180e-03 1.326525e-03 6.282336e-05 3.055746e-03 271.97 -2.00 20.00 -2.00 337.13 0.00e+00 11.770 0.007 319.50 362.20 4 7.4444e-01 9.5742e-04 5.0779e-02 1.2950e-03 2.2910e-03 -8.1839e-02 4.0883e-04 7.9952e-03 2.2599e-04 7.0234e-04 4.5144e-03 7.2348e-04 1.5799e-03 1.0419e-04 1.3300e-03 -3.7824e-03 5.6682e-04 1.0999e-03 2.6497e-05 5.7211e-04 2.1047e-03 6.5962e-04 6.8126e-04 8.7747e-05 9.3819e-04 3.5165e-03 -1.3771e-04 3.3626e-04 7.7645e-05 1.5865e-05 2.2974e-04 -8.7474e-05 1.1188e-05 4.8581e-06 5.0962e-07 3.3782e-05 7.0274e-03 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78 -54 75 63 -69 -141 69 -27 -101 63 -68 31 83 -91 117 -78 129 42 -51 20 140 202 -108 34 33 -95 -2 179 66 5 252 32 102 12 51 27 -57 -31 26 144 -158 -160 34 -125 -97 -127 SU 20200830T162914.0Z 7547.686967 1550 1 29.92 2 85.64 82.35 124.13 256.68 0.00 1 0.00 1 0 49 1.763e-03 8.438e-04 1.344e-03 6.643e-04 1.786393e-06 2.530792e-07 1.055097e-07 3.425276e-07 5.716203e-07 225.44 -2.00 3.11 -2.00 345.53 0.00e+00 3.423146e-04 7.270914e-05 3.694636e-05 6.607564e-06 1.415190e-04 271.97 -2.00 20.00 -2.00 343.95 0.00e+00 -3.660198e-05 8.844858e-06 1.556460e-06 2.274790e-05 2.639513e-05 271.97 -2.00 20.00 -2.00 350.08 0.00e+00 4.000711e-04 2.613344e-05 2.661680e-05 1.622160e-06 7.515379e-05 271.97 -2.00 20.00 -2.00 349.39 0.00e+00 2.062606e+06 6.819968e+04 8.579242e+04 1.741842e+05 1.442569e+05 252.51 -2.00 10.06 -2.00 354.11 0.00e+00 1.029945e+00 1.967101e-03 6.554737e-03 8.295294e-04 2.587751e-03 225.44 -2.00 3.11 -2.00 335.37 0.00e+00 -8.212928e-04 2.974794e-03 1.165659e-03 6.137811e-05 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1.968577e-04 271.97 -2.00 20.00 -2.00 327.56 0.00e+00 1.453 0.000 319.50 362.20 4 2.8545e-02 9.3582e-05 6.2615e-03 1.2920e-03 2.3682e-04 -2.4107e-03 2.1790e-05 9.9771e-04 2.2716e-04 5.3981e-05 -6.7104e-04 4.1958e-05 2.1592e-04 6.1177e-05 1.0448e-04 -6.8170e-04 1.9728e-05 2.2873e-04 1.5755e-05 4.3634e-05 5.0520e-04 3.2408e-05 1.7131e-04 4.3621e-05 7.6796e-05 5.0625e-01 1.0667e-03 5.8351e-05 1.2213e-04 6.0305e-05 1.4204e-04 -3.4825e-05 1.0398e-06 1.9935e-06 5.1010e-07 2.5915e-06 8.7487e-04 0.0000e+00 -9.7331e-03 6.2663e-03 8.9879e-03 3.6012e-03 1.5554e-02 10 0 0 10 0 0 9.89 21.75 0.35 0.00087 0.00045 1976 1976 1 5 0 15.010 26.51 20.00 21.75 23.86 51.60 10.2 930.55 -11 -11 23 15 8 -1 7 6 18 9 20 12 1 -24 -56 -49 -34 -35 -4 -18 5 25 28 31 23 19 10 9 2 -6 -21 -25 -24 -24 -20 -37 -41 -23 -9 13 31 22 7 27 22 17 25 22 22 14 10 -3 -1 -8 -11 0 5 35 11 -2 2 14 13 6 16 9 10 16 -12 2 -8 -14 -21 -21 -26 -21 -18 -23 -15 -17 -3 -2 5 3 23 12 2 18 9 -10 -4 1 -7 -12 2 -8 -1 -21 8 6 7 2 18 -4 -14 -8 14 17 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4 4.6525e-02 9.2769e-05 5.8610e-03 1.2920e-03 3.0865e-04 -2.4844e-03 2.1533e-05 9.3470e-04 2.2713e-04 7.0285e-05 -6.4062e-04 4.1536e-05 2.0335e-04 6.0755e-05 1.3607e-04 -1.2875e-03 1.9475e-05 2.1723e-04 1.5757e-05 5.6904e-05 4.1980e-04 3.2029e-05 1.6267e-04 4.3287e-05 9.9890e-05 5.1793e-01 7.3306e-04 5.7974e-05 1.1394e-04 6.0309e-05 1.8575e-04 -1.4760e-05 1.0259e-06 1.9295e-06 5.1469e-07 3.3812e-06 2.2582e-03 0.0000e+00 -2.7397e-01 6.2532e-03 8.4231e-03 3.6358e-03 2.0429e-02 10 0 0 10 0 0 25.22 21.47 0.36 0.00226 0.00208 2013 2013 1 5 0 14.730 26.32 20.01 21.47 23.68 51.60 10.2 929.02 19 6 20 -2 10 -5 -6 7 24 1 8 24 -25 -11 -16 -25 -43 -48 2 -27 -12 2 1 6 26 11 20 16 -18 -9 -28 -22 -17 -21 -6 -12 -18 -30 -5 5 6 17 37 30 8 9 21 12 17 19 16 15 -11 6 17 6 29 49 5 15 -2 -9 31 26 18 15 12 6 11 13 -16 -23 -28 -22 -29 -31 -18 -16 -3 -13 -9 -7 0 8 -1 15 -4 24 10 -38 -9 -15 -37 -25 1 9 31 -9 -23 -23 -17 1 26 13 44 12 -6 -23 -25 12 24 -10 8 27 -44 15 7 -34 -1 11 -17 -6 13 7 -17 -9 -11 0 -11 18 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23 -19 1 29 2 1 19 -18 -13 18 25 -14 21 13 0 51 -19 2 28 -9 -14 19 22 -42 14 -9 -42 -12 11 -21 -18 -1 -13 -19 -30 -31 -10 -25 -8 -10 3 12 -7 -23 15 12 -21 29 13 -19 17 -6 10 -7 -8 -11 13 4 -9 -17 28 -7 19 16 -31 27 -31 -82 52 4 -48 25 33 9 2 10 -5 -8 -45 -21 34 -39 -4 49 6 15 23 SU 20200831T011518.5Z 7548.052297 2110 1 30.92 2 43.14 261.52 119.01 103.28 0.00 1 0.00 1 0 33 2.177e-04 2.135e-04 6.984e-05 6.853e-05 -1.458605e-07 2.206575e-08 2.733499e-08 3.428121e-07 7.073576e-08 225.43 -2.00 3.11 -2.00 338.75 0.00e+00 1.264210e-04 5.889025e-06 6.847182e-06 6.214211e-06 1.889529e-05 271.97 -2.00 20.00 -2.00 336.13 0.00e+00 -2.024387e-05 9.923493e-07 7.019298e-07 2.272859e-05 3.372946e-06 271.97 -2.00 20.00 -2.00 345.09 0.00e+00 1.181348e-04 2.782387e-06 8.944710e-06 2.866514e-06 9.240716e-06 271.97 -2.00 20.00 -2.00 343.54 0.00e+00 2.754619e+05 5.387146e+03 1.955946e+04 1.748737e+05 1.719824e+04 252.51 -2.00 10.06 -2.00 351.62 0.00e+00 1.660368e-01 7.587738e-05 1.208023e-03 8.282056e-04 2.289793e-04 225.43 -2.00 3.11 -2.00 329.53 0.00e+00 -6.697294e-04 9.428537e-05 4.185402e-04 7.119895e-05 2.545924e-04 271.97 -2.00 20.00 -2.00 327.53 0.00e+00 1.369 0.000 319.50 362.20 4 5.0617e-02 9.2955e-05 5.9014e-03 1.2920e-03 3.0557e-04 -2.5570e-03 2.1612e-05 9.4102e-04 2.2713e-04 6.9595e-05 -4.0961e-04 4.1665e-05 2.0420e-04 6.0792e-05 1.3471e-04 -1.2888e-03 1.9556e-05 2.1769e-04 1.5772e-05 5.6342e-05 3.0799e-04 3.2134e-05 1.6245e-04 4.3329e-05 9.8910e-05 5.1365e-01 7.6505e-04 5.8108e-05 1.1487e-04 6.0266e-05 1.8384e-04 -1.4649e-05 1.0295e-06 1.9412e-06 5.1223e-07 3.3473e-06 2.2625e-03 0.0000e+00 -2.7648e-01 6.2686e-03 8.4815e-03 3.6457e-03 2.0214e-02 10 0 0 10 0 0 20.46 21.47 0.35 0.00226 0.00208 1997 1997 1 5 0 14.850 26.32 20.00 21.47 23.75 54.10 10.2 929.60 20 10 20 -20 21 -3 -9 1 28 1 -14 20 -1 -13 -15 -20 -39 -48 3 -15 -6 -8 -10 6 12 14 27 21 -5 -10 -19 -36 -10 -32 3 -10 -24 -15 -15 5 0 14 28 46 8 7 27 3 17 23 16 13 -4 12 4 -5 30 47 11 23 4 -4 30 12 17 -1 1 -5 6 12 -21 -23 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20.00 -2.00 343.55 0.00e+00 2.703114e+05 5.400730e+03 1.969943e+04 1.748715e+05 1.727602e+04 252.51 -2.00 10.06 -2.00 351.61 0.00e+00 1.671512e-01 7.602036e-05 1.217128e-03 8.282237e-04 2.300484e-04 225.43 -2.00 3.11 -2.00 329.54 0.00e+00 -6.419670e-04 9.448661e-05 4.469209e-04 7.120458e-05 2.556876e-04 271.97 -2.00 20.00 -2.00 327.53 0.00e+00 1.378 0.000 319.50 362.20 4 4.9942e-02 9.3184e-05 5.9434e-03 1.2920e-03 3.0695e-04 -2.7007e-03 2.1658e-05 9.4779e-04 2.2714e-04 6.9914e-05 -6.2712e-04 4.1756e-05 2.0708e-04 6.0934e-05 1.3535e-04 -1.3246e-03 1.9600e-05 2.2019e-04 1.5773e-05 5.6597e-05 4.1314e-04 3.2203e-05 1.6496e-04 4.3400e-05 9.9389e-05 5.1184e-01 6.7622e-04 5.8188e-05 1.1567e-04 6.0142e-05 1.8461e-04 -1.5266e-05 1.0304e-06 1.9486e-06 5.1337e-07 3.3619e-06 2.2380e-03 0.0000e+00 -2.8819e-01 6.2770e-03 8.5486e-03 3.6357e-03 2.0293e-02 10 0 0 10 0 0 15.89 21.47 0.35 0.00224 0.00205 1991 1991 1 5 0 14.890 26.32 20.00 21.47 23.81 50.10 10.1 929.28 32 0 -2 5 8 -5 1 -7 31 -2 -2 16 -4 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