File name: Pandora56s1_MaunaLoaHI_20201009_L2Fit_fwvt1c8d20200803p1-8.txt File generation date: 20250131T121309.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 56 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora56_OF_v4d20200131.txt Instrument calibration file used: Pandora56s1_CF_v8d20200803.txt Level 1 file used: Pandora56s1_MaunaLoaHI_20201009_L1_smca1c8d20200803p1-8.txt Full location name: Mauna Loa Short location name: MaunaLoaHI Country of location: USA Location latitude [deg]: 19.4795 Location longitude [deg]: -155.6027 Location altitude [m]: 4169 Local noon date: 20201009 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1714 1864 Nominal wavelengths inside fitting window [nm]: 492.0468 492.1674 492.2879 492.4085 492.5290 492.6495 492.7699 492.8904 493.0108 493.1312 493.2516 493.3720 493.4924 493.6128 493.7331 493.8534 493.9737 494.0940 494.2143 494.3345 494.4548 494.5750 494.6952 494.8154 494.9356 495.0557 495.1758 495.2960 495.4161 495.5362 495.6562 495.7763 495.8963 496.0163 496.1363 496.2563 496.3763 496.4962 496.6162 496.7361 496.8560 496.9759 497.0957 497.2156 497.3354 497.4552 497.5750 497.6948 497.8146 497.9343 498.0541 498.1738 498.2935 498.4132 498.5328 498.6525 498.7721 498.8917 499.0113 499.1309 499.2505 499.3700 499.4896 499.6091 499.7286 499.8481 499.9675 500.0870 500.2064 500.3258 500.4452 500.5646 500.6839 500.8033 500.9226 501.0419 501.1612 501.2805 501.3998 501.5190 501.6382 501.7574 501.8766 501.9958 502.1150 502.2341 502.3532 502.4723 502.5914 502.7105 502.8296 502.9486 503.0676 503.1866 503.3056 503.4246 503.5435 503.6625 503.7814 503.9003 504.0192 504.1381 504.2569 504.3758 504.4946 504.6134 504.7322 504.8509 504.9697 505.0884 505.2071 505.3258 505.4445 505.5632 505.6818 505.8005 505.9191 506.0377 506.1563 506.2748 506.3934 506.5119 506.6304 506.7489 506.8674 506.9858 507.1043 507.2227 507.3411 507.4595 507.5779 507.6963 507.8146 507.9329 508.0512 508.1695 508.2878 508.4061 508.5243 508.6425 508.7607 508.8789 508.9971 509.1152 509.2334 509.3515 509.4696 509.5877 509.7058 509.8238 509.9419 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Azimuth motor temperature [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-252: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 253-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20201009T162807.0Z 7587.686192 400 1 34.02 2 87.85 97.79 7.73 313.42 0.00 1 0.00 1 0 22 3.383e-03 3.363e-03 6.330e-05 6.324e-05 2.733956e+03 3.747038e+00 2.044655e+02 -6.000000e+00 1.859015e+02 271.21 -2.00 20.00 -2.00 505.32 0.00e+00 7.543014e-04 1.717357e-06 4.225926e-05 -6.000000e+00 9.341016e-05 271.21 -2.00 20.00 -2.00 500.70 0.00e+00 9.531722e-01 1.252220e-03 2.255456e-02 -6.000000e+00 6.837318e-02 225.06 -2.00 3.11 -2.00 502.26 0.00e+00 16.125 0.018 489.00 513.00 1 3.1523e-01 9.5773e-05 1.4339e-02 -6.0000e+00 5.2330e-03 -1.5201e-02 2.4247e-05 9.4129e-04 -6.0000e+00 1.3451e-03 3.2404e-01 5.9467e-03 6.9008e-06 3.2508e-05 -6.0000e+00 3.8007e-04 1.8770e-02 -2.0703e-04 10 0 0 10 0 0 62.44 20.06 1.65 0.01877 0.06002 1928 381 1 4 0 17.080 25.17 20.60 20.06 8.22 36.10 10.5 772.84 -595 -486 -89 78 95 577 758 675 534 363 288 17 -331 -402 -326 -456 -283 141 220 -22 72 221 141 344 472 315 350 227 -380 -610 -339 -453 -298 413 348 -75 46 158 -57 -160 -24 -5 55 220 363 369 330 311 153 -218 -577 -628 -784 -654 -272 -121 -56 -22 10 59 256 377 335 287 252 130 38 -30 -166 -402 -325 -217 -257 -55 147 -95 -366 -275 -312 -432 -414 -413 -588 -413 -102 -240 -320 -256 -116 -144 -93 161 432 323 256 376 194 -109 -271 -526 -666 -765 -520 -84 -93 -354 -233 -239 -245 -12 51 -8 145 312 393 483 665 714 569 456 392 205 185 438 302 83 287 243 179 335 240 -99 -62 -194 -385 -160 118 -103 -172 55 98 80 235 265 194 132 -1 -255 -406 -385 -389 -557 -462 -84 77 94 578 753 677 536 361 290 17 -327 -393 -318 -448 -283 139 223 -22 73 224 143 350 481 322 356 228 -385 -603 -330 -443 -297 411 356 -78 48 161 -58 -161 -24 -5 57 223 370 377 336 313 155 -216 -561 -613 -759 -636 -264 -120 -57 -22 10 59 258 381 340 291 255 130 38 -30 -164 -393 -316 -211 -253 -54 147 -95 -361 -267 -300 -415 -399 -400 -576 -408 -99 -236 -316 -253 -115 -143 -93 159 431 324 256 378 191 -106 -264 -505 -637 -740 -504 -83 -93 -358 -235 -239 -243 -12 51 -8 147 318 404 499 689 742 590 469 398 206 185 436 303 84 289 245 180 336 241 -99 -61 -193 -383 -157 117 -104 -174 57 102 84 246 273 200 136 -1 -261 -410 -386 -391 SO 20201009T162900.6Z 7587.686813 402 1 33.25 2 87.65 97.87 7.88 312.46 0.00 1 0.00 1 0 22 3.205e-03 3.182e-03 1.158e-04 1.157e-04 2.569198e+03 6.854505e+00 1.916163e+02 -6.000000e+00 1.761135e+02 271.21 -2.00 20.00 -2.00 505.32 0.00e+00 7.172292e-04 3.139287e-06 4.033554e-05 -6.000000e+00 8.849221e-05 271.21 -2.00 20.00 -2.00 500.68 0.00e+00 9.359051e-01 2.295262e-03 2.137314e-02 -6.000000e+00 6.477494e-02 225.06 -2.00 3.11 -2.00 502.24 0.00e+00 15.541 0.017 489.00 513.00 1 1.5812e+00 1.7549e-04 1.3802e-02 -6.0000e+00 4.9576e-03 -1.2451e-02 4.4463e-05 9.0026e-04 -6.0000e+00 1.2744e-03 9.6306e-02 5.7734e-03 1.2639e-05 3.0271e-05 -6.0000e+00 3.6006e-04 2.0956e-02 -2.2275e-04 10 0 0 10 0 0 50.26 20.09 1.62 0.02096 0.06100 568 112 1 4 0 58.520 25.17 20.01 20.09 8.99 37.10 10.5 773.80 -565 -462 -86 81 64 524 727 606 494 345 288 12 -332 -388 -329 -457 -312 116 206 -41 56 190 137 323 445 307 351 237 -366 -549 -297 -391 -261 404 325 -105 23 153 -30 -144 -4 5 53 208 323 326 306 305 133 -206 -534 -601 -730 -608 -250 -113 -62 -20 -7 41 236 373 323 264 250 117 35 -32 -164 -412 -303 -206 -264 -55 130 -111 -336 -248 -276 -394 -376 -412 -582 -400 -112 -225 -339 -220 -102 -115 -95 163 402 277 237 367 180 -125 -283 -490 -635 -723 -503 -87 -103 -343 -214 -218 -209 0 71 -14 148 289 343 455 623 692 545 446 349 192 196 436 299 73 285 238 160 329 249 -84 -41 -157 -337 -124 124 -130 -182 40 101 68 225 249 182 111 -16 -251 -419 -390 -345 -526 -437 -83 79 63 523 736 620 505 350 288 12 -325 -377 -319 -447 -309 117 208 -42 58 195 141 334 451 311 354 242 -368 -539 -294 -389 -258 408 330 -108 23 155 -30 -144 -4 5 54 213 334 338 316 311 134 -208 -526 -580 -699 -585 -246 -111 -62 -21 -7 42 241 382 324 265 250 118 35 -31 -160 -398 -298 -203 -256 -53 128 -110 -328 -239 -269 -383 -366 -395 -564 -390 -110 -223 -339 -220 -100 -113 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