File name: Pandora56s1_MaunaLoaHI_20210101_L2Fit_fout2c8d20200803p1-8.txt File generation date: 20250131T123006.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 56 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora56_OF_v5d20200131.txt Instrument calibration file used: Pandora56s1_CF_v8d20200803.txt Level 1 file used: Pandora56s1_MaunaLoaHI_20210101_L1_smca1c8d20200803p1-8.txt Full location name: Mauna Loa Short location name: MaunaLoaHI Country of location: USA Location latitude [deg]: 19.4795 Location longitude [deg]: -155.6027 Location altitude [m]: 4169 Local noon date: 20210101 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 290 432 Nominal wavelengths inside fitting window [nm]: 305.0988 305.2393 305.3798 305.5203 305.6608 305.8013 305.9418 306.0823 306.2228 306.3632 306.5037 306.6441 306.7845 306.9249 307.0653 307.2057 307.3461 307.4865 307.6268 307.7672 307.9075 308.0478 308.1881 308.3284 308.4687 308.6090 308.7493 308.8895 309.0298 309.1700 309.3102 309.4504 309.5907 309.7308 309.8710 310.0112 310.1514 310.2915 310.4317 310.5718 310.7119 310.8520 310.9921 311.1322 311.2723 311.4123 311.5524 311.6924 311.8324 311.9725 312.1125 312.2525 312.3925 312.5324 312.6724 312.8123 312.9523 313.0922 313.2321 313.3721 313.5120 313.6518 313.7917 313.9316 314.0714 314.2113 314.3511 314.4909 314.6307 314.7705 314.9103 315.0501 315.1899 315.3296 315.4694 315.6091 315.7488 315.8885 316.0282 316.1679 316.3076 316.4473 316.5869 316.7266 316.8662 317.0058 317.1454 317.2850 317.4246 317.5642 317.7038 317.8433 317.9829 318.1224 318.2619 318.4014 318.5409 318.6804 318.8199 318.9594 319.0988 319.2383 319.3777 319.5171 319.6565 319.7959 319.9353 320.0747 320.2140 320.3534 320.4927 320.6321 320.7714 320.9107 321.0500 321.1893 321.3285 321.4678 321.6071 321.7463 321.8855 322.0248 322.1640 322.3032 322.4423 322.5815 322.7207 322.8598 322.9990 323.1381 323.2772 323.4163 323.5554 323.6945 323.8335 323.9726 324.1117 324.2507 324.3897 324.5287 324.6677 324.8067 324.9457 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210101T180604.3Z 7671.754216 258 1 50.59 2 76.33 120.76 76.11 287.46 0.00 1 0.00 1 0 25 6.490e-02 5.512e-03 3.056e-02 1.802e-03 4.744582e-01 9.382456e-04 4.894313e-03 -6.000000e+00 3.844584e-02 222.44 -2.00 3.11 -2.00 319.70 0.00e+00 6.597327e-04 2.718597e-04 2.553537e-04 -6.000000e+00 1.654787e-03 269.33 -2.00 20.00 -2.00 319.24 0.00e+00 4.142 0.000 302.00 328.00 3 3.4317e+00 2.6337e-03 3.2941e-02 -6.0000e+00 9.4651e-02 -1.1947e-02 3.1135e-03 2.1356e-02 -6.0000e+00 1.0325e-01 4.4982e-03 2.6882e-03 1.0937e-02 -6.0000e+00 6.1298e-02 -9.9137e-03 1.4123e-03 3.3500e-03 -6.0000e+00 2.5543e-02 7.5645e-04 -3.8611e-04 5.7764e-05 4.3821e-05 -6.0000e+00 2.0635e-03 5.2956e-03 0.0000e+00 10 0 0 10 0 0 98.04 20.20 0.35 0.00530 0.00239 47 9 1 5 0 1076.230 25.28 20.01 20.20 9.26 11.1 717.64 -10181 -37105 581 -21642 -29546 -19496 -22813 -14567 -9543 -22680 -22763 -4583 -15519 -7818 -3048 -8821 -3178 -167 -3616 -7159 -2104 -2053 -1677 -829 -3615 72 -4098 -3372 -1880 -2120 2677 -1156 748 -2362 -2983 -1156 -3527 1992 -1839 -2077 -3288 -993 -1731 -463 -365 -1286 588 -788 1077 1632 913 1927 985 2142 528 727 142 305 -90 972 2279 1754 1744 160 -325 747 1243 916 1407 1119 -35 -519 335 83 286 109 694 690 438 -245 -1057 -1235 -1465 -1163 -927 -819 -510 -290 -355 183 186 385 996 1306 994 914 610 96 -483 -570 -371 50 281 -87 -642 -1104 -984 -734 -112 55 -120 -289 -4 242 322 758 704 342 -76 -585 -427 -189 289 290 313 390 793 1141 796 199 -28 11 -20 59 -289 -211 26 -12 -319 -228 -52 -203 158 -147 -776 9 -384 -540 -325 -429 -284 -196 -570 -612 -116 -524 -295 -118 -413 -154 -8 -202 -431 -123 -123 -105 -56 -266 5 -314 -250 -136 -163 220 -112 78 -261 -328 -128 -446 282 -323 -425 -753 -236 -431 -116 -92 -331 149 -206 283 450 275 627 349 801 210 298 60 127 -37 397 957 804 880 88 -182 403 653 494 822 670 -23 -354 224 53 183 63 376 375 260 -153 -758 -988 -1270 -1069 -906 -848 -551 -320 -388 191 181 349 858 1138 941 975 680 120 -637 -746 -456 56 324 -102 -738 -1349 -1267 -1003 -164 87 -189 -468 -7 395 494 1108 1028 521 -122 -913 -670 -311 459 442 457 545 1076 1585 1201 330 -46 18 -36 112 -581 -444 52 -24 -652 -483 -106 -393 298 SS 20210101T181206.9Z 7671.758414 261 1 49.86 2 75.11 121.45 77.42 287.82 0.00 1 0.00 1 0 25 3.756e-02 5.284e-03 1.539e-02 1.209e-03 4.407024e-01 6.301371e-04 4.596369e-03 -6.000000e+00 2.225090e-02 222.44 -2.00 3.11 -2.00 319.36 0.00e+00 4.697119e-04 1.623932e-04 1.987649e-04 -6.000000e+00 9.577155e-04 269.33 -2.00 20.00 -2.00 318.89 0.00e+00 3.822 0.000 302.00 328.00 3 2.9784e+00 1.7339e-03 3.0459e-02 -6.0000e+00 5.4780e-02 -1.5577e-02 2.0153e-03 1.9734e-02 -6.0000e+00 5.9755e-02 6.2311e-03 1.6261e-03 1.0053e-02 -6.0000e+00 3.5476e-02 -1.0325e-02 8.5957e-04 3.0329e-03 -6.0000e+00 1.4784e-02 1.5002e-03 -3.3837e-04 3.9025e-05 4.1164e-05 -6.0000e+00 1.1943e-03 5.2242e-03 0.0000e+00 10 0 0 10 0 0 97.42 20.21 0.31 0.00522 0.00268 83 16 1 5 0 600.640 25.28 20.00 20.21 9.50 11.1 719.40 -18414 -9256 -5881 -8526 -12279 -15765 -3283 -17670 -11691 -13175 -9049 -3172 -3824 -6356 -4490 -646 -4368 -783 -539 -5620 1367 -983 676 -1558 -1071 -1021 -3836 -2827 -2004 -444 -86 -760 -2046 -4261 -3063 -2810 -431 -1134 -1834 -1226 -2387 -932 -783 133 -391 291 461 24 635 624 2028 1176 1724 1251 620 1080 207 -25 54 930 1378 1242 1330 339 122 52 686 740 1278 924 -48 272 -217 -57 241 -119 662 747 1031 -229 -665 -1370 -1578 -1143 -945 -662 -526 -214 -326 -94 388 379 1028 1157 1041 776 610 178 -540 -312 -423 -215 130 97 -811 -1170 -638 -615 -130 58 -103 -160 -97 150 322 744 639 385 109 -433 -422 -149 14 200 494 655 927 1295 525 247 -60 -162 75 53 -67 -295 -26 -41 -262 -175 -161 53 -128 -423 -214 -135 -192 -272 -364 -73 -508 -350 -427 -299 -110 -158 -294 -239 -37 -286 -53 -38 -439 102 -77 54 -137 -100 -99 -380 -269 -186 -43 -9 -91 -271 -593 -415 -389 -65 -203 -394 -303 -658 -269 -233 40 -119 89 140 7 198 204 707 449 705 547 285 510 100 -12 26 438 673 604 708 195 71 29 373 410 764 617 -35 205 -162 -40 158 -71 366 412 613 -156 -518 -1195 -1489 -1053 -926 -686 -570 -237 -358 -99 379 372 956 1085 974 814 722 234 -700 -399 -549 -258 147 112 -996 -1525 -871 -827 -187 90 -170 -272 -162 237 477 1048 899 563 168 -702 -689 -238 22 296 698 885 1309 1733 763 391 -103 -270 129 96 -127 -591 -54 -86 -545 -354 -311 98 -233 SS 20210101T182201.2Z 7671.765291 264 1 50.34 2 73.13 122.63 79.58 288.44 0.00 1 0.00 1 0 25 2.298e-02 5.409e-03 6.767e-03 8.135e-04 3.941043e-01 4.203684e-04 4.138900e-03 -6.000000e+00 1.361293e-02 222.44 -2.00 3.11 -2.00 318.83 0.00e+00 2.470943e-04 9.240567e-05 1.365819e-04 -6.000000e+00 5.859010e-04 269.33 -2.00 20.00 -2.00 318.36 0.00e+00 3.398 0.000 302.00 328.00 3 2.6047e+00 1.1327e-03 2.7102e-02 -6.0000e+00 3.3514e-02 -1.5294e-02 1.2970e-03 1.7529e-02 -6.0000e+00 3.6558e-02 3.0861e-03 9.5026e-04 8.8988e-03 -6.0000e+00 2.1704e-02 -7.4587e-03 5.0165e-04 2.6373e-03 -6.0000e+00 9.0448e-03 2.9772e-03 -3.0817e-04 2.6261e-05 3.4245e-05 -6.0000e+00 7.3062e-04 4.9272e-03 0.0000e+00 10 0 0 10 0 0 95.69 20.23 0.31 0.00493 0.00261 139 27 1 5 0 359.510 25.28 20.01 20.23 10.00 11.1 722.51 -6671 -8477 -5637 -6238 -11283 -8276 -9815 -4842 -6000 -5428 -5211 -4088 -2424 -3883 -2313 -2532 -1238 -742 -1582 -1134 -496 -556 289 -92 -627 -650 -2295 -1806 427 14 162 752 -362 -1949 -2383 -808 -893 -163 -331 -1199 -1097 -1357 -598 -688 -77 -113 -88 168 552 804 1186 870 1113 1127 705 559 444 -73 386 793 1559 1611 910 635 -202 68 476 712 1181 799 -49 201 15 235 136 177 721 460 489 -72 -667 -1303 -1599 -1285 -857 -867 -599 -377 -361 -92 124 464 869 1151 1139 912 603 117 -400 -477 -421 -247 148 219 -876 -1072 -721 -556 -143 -15 -37 -181 -3 82 282 723 664 559 -31 -413 -485 -152 43 232 573 578 991 1260 673 266 -72 -89 15 177 -224 -238 -84 -52 -263 -164 -129 -213 -108 -212 -300 -216 -230 -412 -293 -382 -201 -277 -264 -265 -227 -140 -268 -182 -224 -116 -74 -167 -123 -55 -62 34 -11 -83 -89 -317 -239 54 2 23 119 -63 -351 -423 -144 -177 -38 -91 -384 -386 -506 -229 -267 -30 -44 -34 65 215 325 511 372 509 547 358 292 236 -39 201 412 835 932 577 429 -138 45 300 453 807 609 -37 160 12 191 102 121 455 287 328 -55 -533 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