File name: Pandora56s1_MaunaLoaHI_20211209_L2Fit_fout2c9d20210409p1-8.txt File generation date: 20250131T200617.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 56 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora56_OF_v5d20200131.txt Instrument calibration file used: Pandora56s1_CF_v9d20210409.txt Level 1 file used: Pandora56s1_MaunaLoaHI_20211209_L1_smca1c9d20210409p1-8.txt Full location name: Mauna Loa Short location name: MaunaLoaHI Country of location: USA Location latitude [deg]: 19.4795 Location longitude [deg]: -155.6027 Location altitude [m]: 4169 Local noon date: 20211209 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 290 432 Nominal wavelengths inside fitting window [nm]: 305.0686 305.2091 305.3497 305.4902 305.6307 305.7712 305.9118 306.0522 306.1927 306.3332 306.4737 306.6141 306.7546 306.8950 307.0354 307.1758 307.3162 307.4566 307.5970 307.7373 307.8777 308.0180 308.1584 308.2987 308.4390 308.5793 308.7196 308.8599 309.0001 309.1404 309.2806 309.4208 309.5611 309.7013 309.8415 309.9817 310.1218 310.2620 310.4022 310.5423 310.6824 310.8226 310.9627 311.1028 311.2429 311.3829 311.5230 311.6631 311.8031 311.9431 312.0832 312.2232 312.3632 312.5032 312.6432 312.7831 312.9231 313.0630 313.2030 313.3429 313.4828 313.6227 313.7626 313.9025 314.0423 314.1822 314.3220 314.4619 314.6017 314.7415 314.8813 315.0211 315.1609 315.3006 315.4404 315.5801 315.7199 315.8596 315.9993 316.1390 316.2787 316.4183 316.5580 316.6977 316.8373 316.9769 317.1166 317.2562 317.3958 317.5354 317.6749 317.8145 317.9540 318.0936 318.2331 318.3726 318.5121 318.6516 318.7911 318.9306 319.0701 319.2095 319.3489 319.4884 319.6278 319.7672 319.9066 320.0460 320.1853 320.3247 320.4640 320.6034 320.7427 320.8820 321.0213 321.1606 321.2999 321.4392 321.5784 321.7177 321.8569 321.9961 322.1353 322.2745 322.4137 322.5529 322.6921 322.8312 322.9704 323.1095 323.2486 323.3877 323.5268 323.6659 323.8050 323.9440 324.0831 324.2221 324.3612 324.5002 324.6392 324.7782 324.9172 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20211209T171424.4Z 8013.718339 51 1 49.70 2 84.66 116.57 155.10 86.12 0.00 1 0.00 1 0 17 5.802e-01 1.801e-02 3.897e-01 1.151e-02 9.022369e-01 6.943552e-03 8.646238e-03 -6.000000e+00 3.555791e-01 222.96 -2.00 3.11 -2.00 322.07 0.00e+00 1.544744e-05 3.671368e-03 4.201549e-03 -6.000000e+00 1.687672e-02 269.69 -2.00 20.00 -2.00 321.68 0.00e+00 9.467 0.004 302.00 328.00 3 2.4212e+00 2.4639e-02 7.5271e-02 -6.0000e+00 8.7969e-01 4.5259e-01 3.6871e-02 5.3029e-02 -6.0000e+00 9.6108e-01 -6.9962e-01 4.1376e-02 2.6661e-02 -6.0000e+00 5.6281e-01 2.8734e-01 1.9140e-02 8.4969e-03 -6.0000e+00 2.3263e-01 5.9687e-05 -7.5024e-04 3.5788e-04 1.5176e-04 -6.0000e+00 1.9412e-02 1.3195e-03 0.0000e+00 12 9 8 11 8 0 55.05 20.28 0.45 0.00132 -0.00432 26 5 1 5 0 1910.900 25.39 20.01 20.28 11.13 12.4 695.36 -29171 -254442 -273041 3569 -144870 900000 900000 900000 -48783 900000 -210693 -244012 900000 -70304 900000 900000 -82496 -4432 -128121 900000 141737 900000 -31408 140284 900000 37793 -42462 900000 900000 -46027 -47657 44175 -85443 -10650 -64027 70604 -1626 28660 38128 -31199 111517 -15067 78509 103403 -15682 35216 37382 53031 -4167 33062 10647 -8868 43069 -5436 75512 23105 24348 9653 27862 50506 3963 22259 11760 26491 22284 14322 7218 4358 9011 6701 13174 9880 11902 1601 3363 2512 -1102 12153 -1003 -328 4550 -5503 -496 -1694 1233 1321 3598 4127 -5366 1808 -3780 4623 323 -1527 -184 -4723 224 -1478 -156 125 -501 -1488 -94 -884 -2800 -1338 -2299 -1506 -2236 -1564 -204 -1685 -635 40 -863 305 -691 701 -26 511 1303 598 1765 -523 1302 602 2140 1824 1280 1669 138 395 -312 -227 391 -62 254 -522 212 44 372 -1131 -1137 -327 -4347 -5766 40 -1622 900000 900000 900000 -546 900000 -3340 -6305 900000 -787 900000 900000 -1228 -50 -3439 900000 1587 900000 -361 1571 900000 423 -666 900000 900000 -825 -1032 495 -3667 -237 -2384 791 -36 556 814 -1538 1552 -771 1688 1784 -860 1209 1278 1655 -242 1476 661 -746 2430 -539 3671 1940 2069 941 2212 3148 391 2023 1335 2943 2796 2005 1102 730 1602 1381 2791 2253 2618 365 684 465 -204 2052 -218 -84 1313 -2037 -195 -727 547 612 1698 1980 -2814 862 -1804 1935 140 -720 -97 -3051 163 -1243 -142 116 -448 -1219 -70 -642 -2148 -1070 -1978 -1382 -2313 -1816 -265 -2424 -940 58 -1242 423 -970 1003 -38 782 1946 861 2400 -710 1676 758 2629 2366 1867 2795 262 809 -693 -535 979 -164 680 -1418 573 115 896 -2607 -2507 SS 20211209T172645.5Z 8013.726915 54 1 49.97 2 82.07 117.76 152.33 87.34 0.00 1 0.00 1 0 25 2.507e-01 4.750e-03 1.930e-01 1.541e-03 7.023154e-01 8.524837e-04 6.919414e-03 -6.000000e+00 1.494955e-01 222.96 -2.00 3.11 -2.00 321.14 0.00e+00 2.626521e-03 3.714632e-04 1.757362e-03 -6.000000e+00 6.410184e-03 269.69 -2.00 20.00 -2.00 320.74 0.00e+00 6.816 0.001 302.00 328.00 3 1.0853e+00 2.6518e-03 5.3518e-02 -6.0000e+00 3.6847e-01 -6.2525e-03 3.7913e-03 3.6108e-02 -6.0000e+00 4.0112e-01 -1.8492e-02 4.3734e-03 1.8644e-02 -6.0000e+00 2.3812e-01 -2.1991e-03 2.1244e-03 6.8811e-03 -6.0000e+00 9.9667e-02 1.3121e-03 -4.9435e-04 4.6963e-05 8.4391e-05 -6.0000e+00 7.9696e-03 1.4583e-03 0.0000e+00 10 0 0 10 0 0 96.11 20.28 0.34 0.00146 -0.00226 225 44 1 5 0 222.040 25.39 20.01 20.28 11.22 12.5 697.06 127796 -115619 -17566 43423 -74834 -35609 -88301 -52039 -62865 -98467 -63890 -82626 -25192 -69628 -16167 -28987 -21458 -3680 -30991 -13658 -23992 5868 -27396 -2952 -16949 -24123 -8991 -15134 -18438 -12465 -1098 3168 -9338 2315 -9497 -431 -9163 1707 662 -4923 -4233 -4397 -64 -2769 757 344 -296 1161 1434 1773 1030 2418 1784 -94 1761 -402 552 -562 -456 -167 -50 1872 1224 1815 619 848 1520 878 1791 646 850 -14 -197 132 -10 -116 -318 990 -160 194 -355 -889 -992 -1489 -963 -878 -420 -236 -364 278 215 1117 752 966 1122 565 974 435 41 -311 -169 -136 322 471 -667 -1176 -992 -824 -164 -67 -86 -345 -34 121 420 748 793 638 -152 -433 -843 -196 54 -55 164 334 727 1192 702 80 -105 -166 -83 193 -316 -259 -150 -12 -110 -176 152 135 188 192 -469 -29 65 -214 -70 -318 -149 -227 -562 -288 -534 -117 -659 -114 -283 -226 -36 -442 -174 -353 66 -457 -42 -303 -493 -162 -291 -377 -266 -25 83 -291 76 -323 -15 -352 70 33 -312 -304 -345 -5 -235 64 30 -27 109 143 191 125 325 267 -16 309 -76 106 -109 -87 -32 -10 394 293 483 178 246 441 268 596 245 354 -6 -86 55 -4 -40 -105 328 -60 85 -182 -480 -592 -960 -658 -637 -317 -183 -282 207 151 733 482 638 820 479 951 486 50 -386 -199 -147 318 455 -680 -1276 -1138 -1014 -220 -92 -131 -563 -56 195 647 1105 1167 970 -244 -720 -1402 -313 82 -81 234 457 1052 1638 1072 138 -200 -341 -169 414 -725 -624 -372 -29 -275 -426 346 291 391 SS 20211209T174302.3Z 8013.738221 59 1 49.95 2 78.70 119.43 148.66 88.76 0.00 1 0.00 1 0 25 8.057e-02 5.267e-03 1.650e-02 6.059e-04 5.331076e-01 3.202364e-04 5.488803e-03 -6.000000e+00 4.804855e-02 222.96 -2.00 3.11 -2.00 320.07 0.00e+00 1.186075e-03 1.041094e-04 6.272770e-04 -6.000000e+00 2.060113e-03 269.69 -2.00 20.00 -2.00 319.63 0.00e+00 4.949 0.001 302.00 328.00 3 8.4911e-01 9.1632e-04 3.8677e-02 -6.0000e+00 1.1843e-01 -2.0442e-02 1.1158e-03 2.4735e-02 -6.0000e+00 1.2892e-01 -1.2226e-03 1.0519e-03 1.2525e-02 -6.0000e+00 7.6530e-02 -6.5201e-03 5.4626e-04 4.0365e-03 -6.0000e+00 3.2036e-02 5.8549e-03 -2.7210e-04 1.9082e-05 5.2712e-05 -6.0000e+00 2.5611e-03 6.8772e-04 0.0000e+00 10 0 0 10 0 0 -7.26 20.30 0.31 0.00069 -0.00136 498 98 1 5 0 100.280 25.39 20.00 20.30 12.73 12.5 704.39 -38837 -18272 -34205 -15575 -26273 -27674 -24136 -30560 -9132 -30932 -16945 -21515 -15502 -8737 -10874 -2191 -9296 -1451 -4312 -2280 -2040 -6950 -1355 -5809 -1338 -4734 -4012 -3466 -4083 -1347 -2779 -146 -1666 -1506 -2861 -3073 -428 -1651 366 -2086 -2410 -1695 -1744 -553 -1398 543 -622 9 666 261 1695 645 1718 1128 882 951 273 26 -569 589 614 1741 1536 722 623 200 1023 839 1396 1208 -13 188 -417 124 -88 199 764 448 818 -23 -363 -1291 -1386 -1364 -1015 -839 -730 -73 -364 41 266 664 995 1263 1253 812 784 309 -170 -271 -405 -159 179 506 -644 -1173 -790 -772 -168 -50 -45 -278 -83 165 254 824 691 593 -84 -581 -672 -409 34 63 351 399 819 1354 695 290 -59 -159 -28 65 -130 -348 -84 -24 -177 -185 -24 117 10 -399 -175 -406 -151 -270 -288 -261 -397 -107 -492 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