File name: Pandora56s1_MaunaLoaHI_20220127_L2Fit_fout2c9d20210409p1-8.txt File generation date: 20250131T202422.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 56 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora56_OF_v5d20200131.txt Instrument calibration file used: Pandora56s1_CF_v9d20210409.txt Level 1 file used: Pandora56s1_MaunaLoaHI_20220127_L1_smca1c9d20210409p1-8.txt Full location name: Mauna Loa Short location name: MaunaLoaHI Country of location: USA Location latitude [deg]: 19.4795 Location longitude [deg]: -155.6027 Location altitude [m]: 4169 Local noon date: 20220127 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 290 432 Nominal wavelengths inside fitting window [nm]: 305.0686 305.2091 305.3497 305.4902 305.6307 305.7712 305.9118 306.0522 306.1927 306.3332 306.4737 306.6141 306.7546 306.8950 307.0354 307.1758 307.3162 307.4566 307.5970 307.7373 307.8777 308.0180 308.1584 308.2987 308.4390 308.5793 308.7196 308.8599 309.0001 309.1404 309.2806 309.4208 309.5611 309.7013 309.8415 309.9817 310.1218 310.2620 310.4022 310.5423 310.6824 310.8226 310.9627 311.1028 311.2429 311.3829 311.5230 311.6631 311.8031 311.9431 312.0832 312.2232 312.3632 312.5032 312.6432 312.7831 312.9231 313.0630 313.2030 313.3429 313.4828 313.6227 313.7626 313.9025 314.0423 314.1822 314.3220 314.4619 314.6017 314.7415 314.8813 315.0211 315.1609 315.3006 315.4404 315.5801 315.7199 315.8596 315.9993 316.1390 316.2787 316.4183 316.5580 316.6977 316.8373 316.9769 317.1166 317.2562 317.3958 317.5354 317.6749 317.8145 317.9540 318.0936 318.2331 318.3726 318.5121 318.6516 318.7911 318.9306 319.0701 319.2095 319.3489 319.4884 319.6278 319.7672 319.9066 320.0460 320.1853 320.3247 320.4640 320.6034 320.7427 320.8820 321.0213 321.1606 321.2999 321.4392 321.5784 321.7177 321.8569 321.9961 322.1353 322.2745 322.4137 322.5529 322.6921 322.8312 322.9704 323.1095 323.2486 323.3877 323.5268 323.6659 323.8050 323.9440 324.0831 324.2221 324.3612 324.5002 324.6392 324.7782 324.9172 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220127T172738.2Z 8062.727526 179 1 50.22 2 84.37 111.72 43.35 165.39 0.00 1 0.00 1 0 25 6.301e-01 6.294e-03 3.644e-01 3.407e-03 9.079196e-01 2.008366e-03 8.554431e-03 -6.000000e+00 3.792470e-01 222.46 -2.00 3.11 -2.00 321.98 0.00e+00 4.278897e-03 1.059706e-03 4.018500e-03 -6.000000e+00 1.759070e-02 269.19 -2.00 20.00 -2.00 321.59 0.00e+00 9.087 0.003 302.00 328.00 3 7.2607e-01 7.1478e-03 7.4573e-02 -6.0000e+00 9.3430e-01 3.9932e-02 1.2713e-02 5.8115e-02 -6.0000e+00 1.0192e+00 -9.9609e-02 1.5727e-02 2.9585e-02 -6.0000e+00 6.0031e-01 3.2177e-02 7.0712e-03 1.0573e-02 -6.0000e+00 2.5315e-01 4.2718e-04 -4.3221e-04 1.0220e-04 1.4271e-04 -6.0000e+00 2.0547e-02 7.9676e-05 0.0000e+00 10 0 0 10 0 0 17.89 20.00 0.42 0.00008 -0.00317 168 33 1 5 0 298.890 25.17 20.00 20.00 7.17 12.8 674.18 -345127 900000 -277511 900000 900000 -294275 900000 -210666 -225982 900000 -100696 -37104 -5809 -42577 -179018 -58442 7303 44477 -105465 -82046 44720 -116395 8575 -67719 -58152 -106263 -116564 -68213 -107646 41738 -41140 19326 27600 -24969 -20190 -35178 13013 -2188 -7911 -4438 -17335 -12533 5408 -1885 -10702 3264 7223 4952 8819 -4809 8934 -6002 11183 864 -370 8058 -4461 4243 5419 4005 5026 869 -13 1669 2893 1443 6179 1706 1349 2966 -92 1896 2055 3291 -749 -897 1163 -1114 1320 694 1185 587 -3067 -1745 -1341 373 -1042 264 161 -80 1470 -725 1175 192 1405 -408 1106 413 -306 -56 -8 -82 658 -129 -967 -2142 -581 -1298 21 -317 -531 -260 -464 262 492 652 1005 676 -46 -758 -366 -111 352 -71 -144 162 670 1730 463 32 62 -60 188 8 -325 -337 34 -78 -75 -248 -104 434 45 -1489 900000 -921 900000 900000 -1074 900000 -699 -750 900000 -334 -123 -19 -141 -1248 -194 24 148 -700 -463 148 -1005 28 -427 -367 -1164 -1470 -543 -1358 139 -396 128 202 -340 -268 -560 143 -33 -158 -103 -529 -404 156 -61 -394 109 247 187 354 -226 463 -377 668 64 -30 635 -412 360 445 330 426 85 -2 217 408 215 914 284 252 623 -22 465 498 741 -160 -175 213 -219 292 186 379 220 -1334 -809 -661 191 -566 145 88 -42 728 -351 555 98 808 -282 893 388 -292 -55 -7 -75 543 -104 -812 -1922 -546 -1227 21 -380 -722 -384 -713 398 725 934 1436 1003 -72 -1214 -573 -166 499 -97 -190 207 846 2282 702 57 123 -130 439 19 -809 -882 92 -211 -201 -639 -251 1051 104 SS 20220127T173925.7Z 8062.735715 182 1 50.08 2 81.80 112.82 42.78 169.20 0.00 1 0.00 1 0 25 2.819e-01 5.075e-03 8.982e-02 1.036e-03 7.057944e-01 5.709624e-04 6.961167e-03 -6.000000e+00 1.677926e-01 222.46 -2.00 3.11 -2.00 321.10 0.00e+00 2.738891e-03 2.473365e-04 1.482182e-03 -6.000000e+00 7.192853e-03 269.19 -2.00 20.00 -2.00 320.70 0.00e+00 6.618 0.001 302.00 328.00 3 4.9455e-01 1.7826e-03 5.2424e-02 -6.0000e+00 4.1318e-01 1.0304e-02 2.5124e-03 3.5576e-02 -6.0000e+00 4.4995e-01 -3.5811e-02 2.8758e-03 1.8558e-02 -6.0000e+00 2.6712e-01 4.9780e-03 1.4023e-03 7.1581e-03 -6.0000e+00 1.1191e-01 2.6318e-03 -2.6822e-04 3.1368e-05 8.6477e-05 -6.0000e+00 8.9574e-03 -4.8184e-04 0.0000e+00 10 0 0 10 0 0 -2.71 20.00 0.33 -0.00048 -0.00250 434 86 1 5 0 115.360 25.17 20.00 20.00 7.85 12.8 677.39 -95051 -133313 -47873 -123034 -42138 -100879 -99749 -44193 -116081 -52217 -88727 -61173 -66150 -39677 -28213 -30012 1563 -25665 -15136 -14405 -15729 -11371 -25019 2397 -22677 -14583 -17619 -18849 -10672 -20234 3310 -9987 3527 -5965 -5844 -3020 -11364 104 -4717 -1193 -3770 -3185 -1074 -2797 1164 -2321 1959 -884 458 1919 1068 3854 1450 3154 1376 460 435 -1202 -250 -113 837 1499 1456 2007 244 1551 518 1319 1261 947 841 -210 220 -71 -290 5 167 282 -161 403 -491 -590 -1298 -1339 -720 -915 -269 -601 -207 173 282 878 784 1141 868 939 745 477 -27 -365 -144 -199 560 527 -851 -1263 -1143 -676 -328 -90 -168 -354 -107 80 383 799 979 628 -21 -548 -635 -159 -92 110 168 269 773 1310 844 41 -58 -177 -43 58 -310 -348 -132 74 -195 -118 78 148 239 -288 -701 -116 -634 -94 -408 -433 -125 -763 -201 -547 -340 -495 -297 -239 -315 14 -337 -196 -197 -226 -161 -430 34 -451 -284 -363 -394 -211 -489 75 -312 111 -203 -200 -113 -465 4 -260 -76 -279 -256 -89 -246 101 -214 179 -87 47 214 134 526 225 525 249 88 86 -241 -49 -22 166 324 356 546 72 457 156 410 431 367 358 -95 98 -30 -113 2 56 96 -61 178 -256 -323 -792 -877 -500 -674 -207 -475 -162 131 201 586 509 763 645 804 740 541 -31 -423 -172 -218 558 515 -879 -1386 -1327 -839 -411 -125 -259 -584 -179 132 598 1194 1453 966 -34 -920 -1062 -257 -143 164 240 371 1039 1812 1296 72 -112 -343 -87 125 -716 -846 -330 173 -490 -287 179 320 497 SS 20220127T175357.6Z 8062.745806 187 1 50.00 2 78.66 114.27 42.34 174.00 0.00 1 0.00 1 0 25 7.854e-02 5.230e-03 1.366e-02 4.759e-04 5.451794e-01 2.515836e-04 5.592213e-03 -6.000000e+00 4.675494e-02 222.46 -2.00 3.11 -2.00 320.10 0.00e+00 1.624074e-03 8.245654e-05 5.557013e-04 -6.000000e+00 2.004264e-03 269.19 -2.00 20.00 -2.00 319.67 0.00e+00 4.931 0.001 302.00 328.00 3 3.6219e-01 7.2020e-04 3.8865e-02 -6.0000e+00 1.1513e-01 -6.1964e-03 8.7925e-04 2.5209e-02 -6.0000e+00 1.2538e-01 -1.0025e-02 8.3631e-04 1.2846e-02 -6.0000e+00 7.4433e-02 -4.2818e-03 4.3418e-04 4.4175e-03 -6.0000e+00 3.1183e-02 9.4374e-03 -1.5095e-04 1.4882e-05 5.5320e-05 -6.0000e+00 2.4959e-03 -5.0068e-04 0.0000e+00 10 0 0 10 0 0 -4.79 20.02 0.34 -0.00050 -0.00163 831 164 1 5 0 60.150 25.17 19.99 20.02 8.99 12.9 683.78 -23944 -26246 -27353 -26739 -28757 -28659 -28234 -23660 -20649 -24385 -21679 -19110 -16119 -10573 -6326 -4632 -6627 -2751 -4754 -2520 -4659 -3556 -3857 -3736 -4840 -5382 -5096 -5322 -4983 -1504 -1635 14 -662 -2094 -3121 -1832 -2057 -1582 -901 -1756 -2239 -2089 -1437 -789 -1109 -86 -492 521 335 1033 1606 1077 1477 1110 1085 566 123 -392 -189 522 828 1569 1288 827 383 289 1018 932 1635 1153 267 187 -289 70 -139 179 597 732 808 81 -454 -1159 -1428 -1399 -881 -855 -598 -223 -437 -72 250 663 891 1141 1226 877 833 262 -206 -377 -347 -208 386 491 -732 -1098 -862 -655 -191 -29 -113 -409 -97 189 329 828 788 677 -102 -532 -618 -249 -27 28 279 370 817 1391 723 184 -69 -189 -74 136 -219 -323 -101 -50 -186 -203 8 91 121 -199 -256 -286 -273 -286 -283 -299 -269 -255 -340 -317 -309 -307 -236 -165 -139 -228 -100 -189 -103 -182 -141 -176 -167 -235 -276 -264 -272 -254 -78 -97 1 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