File name: Pandora142s1_MexicoCity-UNAM_20180812_L2Fit_fwvt1c13d20180420p1-8.txt File generation date: 20251127T083154.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Michel de Grutter Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 142 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora142_of_v1d20171226.txt Instrument calibration file used: Pandora142s1_CF_v13d20180420.txt Level 1 file used: Pandora142s1_MexicoCity-UNAM_20180812_L1_smca1c13d20180420p1-8.txt Full location name: Centro de Ciencias de la Atmosfera, UNAM Short location name: MexicoCity-UNAM Country of location: Mexico Location latitude [deg]: 19.3262 Location longitude [deg]: -99.1761 Location altitude [m]: 2280 Local noon date: 20180812 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1654 1803 Nominal wavelengths inside fitting window [nm]: 492.0414 492.1628 492.2842 492.4056 492.5270 492.6483 492.7696 492.8909 493.0122 493.1335 493.2548 493.3760 493.4972 493.6184 493.7396 493.8608 493.9820 494.1031 494.2242 494.3453 494.4664 494.5875 494.7086 494.8296 494.9506 495.0717 495.1927 495.3136 495.4346 495.5555 495.6765 495.7974 495.9183 496.0392 496.1600 496.2809 496.4017 496.5225 496.6433 496.7641 496.8849 497.0056 497.1264 497.2471 497.3678 497.4885 497.6091 497.7298 497.8504 497.9710 498.0916 498.2122 498.3328 498.4534 498.5739 498.6944 498.8149 498.9354 499.0559 499.1763 499.2968 499.4172 499.5376 499.6580 499.7784 499.8987 500.0191 500.1394 500.2597 500.3800 500.5003 500.6205 500.7408 500.8610 500.9812 501.1014 501.2216 501.3417 501.4619 501.5820 501.7021 501.8222 501.9423 502.0623 502.1824 502.3024 502.4224 502.5424 502.6624 502.7824 502.9023 503.0222 503.1421 503.2620 503.3819 503.5018 503.6216 503.7415 503.8613 503.9811 504.1008 504.2206 504.3403 504.4601 504.5798 504.6995 504.8192 504.9388 505.0585 505.1781 505.2977 505.4173 505.5369 505.6564 505.7760 505.8955 506.0150 506.1345 506.2540 506.3734 506.4929 506.6123 506.7317 506.8511 506.9705 507.0899 507.2092 507.3285 507.4478 507.5671 507.6864 507.8057 507.9249 508.0441 508.1633 508.2825 508.4017 508.5209 508.6400 508.7591 508.8782 508.9973 509.1164 509.2354 509.3545 509.4735 509.5925 509.7115 509.8305 509.9494 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180812T122153.0Z 6798.515197 383 1 32.01 2 89.66 74.33 106.01 71.23 0.00 1 0.00 1 0 55 1.054e+00 4.765e-01 5.489e-01 3.582e-01 3.354030e+04 2.950790e+04 1.748029e+03 -6.000000e+00 7.487519e+04 282.61 -2.00 20.00 -2.00 504.98 0.00e+00 -8.719209e-03 1.079440e-02 6.883604e-04 -6.000000e+00 3.436545e-02 282.61 -2.00 20.00 -2.00 500.15 0.00e+00 -1.447051e+01 7.733317e+00 4.188066e-01 -6.000000e+00 2.448550e+01 226.41 -2.00 3.11 -2.00 501.72 0.00e+00 20.217 0.037 489.00 513.00 1 1.3336e+01 5.8568e-01 4.3469e-02 -6.0000e+00 1.8723e+00 3.2177e-01 1.5546e-01 7.4181e-03 -6.0000e+00 4.9199e-01 6.6442e-07 1.0573e-01 2.8517e-02 3.7630e-04 -6.0000e+00 1.3121e-01 -7.1598e-02 -1.5015e-03 12 13 8 11 8 0 91.13 19.12 47.90 -0.07160 0.66179 8 2 1 4 0 4000.000 21.69 15.00 19.12 900000 900000 900000 89011 -8698 -22684 -5586 17526 19908 58719 108697 42520 69649 12245 162039 20590 173431 10088 900000 -34469 900000 13206 900000 -8609 216491 -26495 900000 68001 900000 -1527 148546 -18195 11524 -36196 91814 -5315 -23667 57633 -387 31524 15665 42640 45117 159749 -48456 107771 74860 177926 27192 57304 -24168 77288 2901 900000 -25363 52932 19375 251141 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30770 900000 -1553 14774 -80067 67315 32803 46385 20188 900000 24815 900000 7360 900000 -15664 900000 -266 900000 -49477 41057 -26107 257227 41420 900000 43143 33173 -33745 28303 36457 -13209 30422 -30951 900000 -31884 900000 9074 900000 -15703 53795 48127 900000 -69464 900000 4154 900000 -619 45622 50669 33428 46421 45264 -57807 45437 24727 42442 24051 44651 16914 -52100 44039 -54879 39603 -33533 900000 30779 40352 4372 900000 -10152 900000 -11285 900000 21487 900000 -77454 49190 17270 69560 41514 1325 -569 31205 900000 41930 120107 SO 20180812T122608.0Z 6798.518148 387 1 32.01 2 88.70 74.67 105.10 71.66 0.00 1 0.00 1 0 41 5.926e-01 3.197e-01 3.323e-01 2.254e-01 -4.419753e+04 1.440003e+04 2.090795e+03 -6.000000e+00 3.424307e+04 282.61 -2.00 20.00 -2.00 505.33 0.00e+00 1.972841e-02 6.699471e-03 8.535807e-04 -6.000000e+00 1.708991e-02 282.61 -2.00 20.00 -2.00 500.04 0.00e+00 1.286765e+01 5.007869e+00 5.713904e-01 -6.000000e+00 1.219187e+01 226.41 -2.00 3.11 -2.00 501.72 0.00e+00 18.131 0.027 489.00 513.00 1 1.0833e+01 3.8517e-01 5.3543e-02 -6.0000e+00 9.3358e-01 -7.0408e-02 9.8142e-02 1.0301e-02 -6.0000e+00 2.4660e-01 1.4373e-06 2.0537e-02 1.3761e-02 1.7346e-04 -6.0000e+00 6.7672e-02 -1.5934e-02 -1.4042e-03 12 9 8 11 8 0 82.79 19.13 21.06 -0.01593 0.12652 8 2 1 4 0 4000.000 21.69 15.00 19.13 900000 900000 -8169 141651 -2858 10573 28039 3356 13852 4970 29564 -7784 39269 -31284 46957 10755 105332 -20031 39126 -33174 199921 1710 53683 -6999 -4699 -26708 88265 16855 38176 8237 36505 34858 4527 -28147 17275 47156 -11155 101225 -509 29069 -37913 36111 -11265 9370 -8625 86556 -34694 94960 -33475 43365 -23191 13359 34258 27650 -8855 7898 26525 69943 -6550 29557 16276 62530 -19497 4644 -3603 17723 80908 25373 119683 18729 32156 -24657 48154 -24027 38938 -22179 76709 -32691 53324 -33126 29761 29513 111238 -30731 26308 -23677 19185 -2627 50122 58357 17728 65097 5962 19984 -19994 34468 27719 128233 27853 150725 -140 212701 -40594 65838 -15719 900000 23104 84621 -21935 259075 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-2051 -26301 30467 -30456 38204 -96048 33016 -21902 46244 -39077 16584 -34325 45588 1531 38829 3093 31028 -12195 6520 21298 17652 26186 41675 -2058 43888 42372 -9123 7658 SO 20180812T123014.0Z 6798.520995 391 1 32.01 2 87.76 75.01 104.23 72.07 0.00 1 0.00 1 0 64 1.116e-01 1.073e-01 9.604e-02 9.371e-02 -5.113490e+03 5.566799e+03 4.440118e+02 -6.000000e+00 6.437629e+03 282.61 -2.00 20.00 -2.00 505.24 0.00e+00 4.883343e-03 2.633865e-03 2.563416e-04 -6.000000e+00 3.180749e-03 282.61 -2.00 20.00 -2.00 500.19 0.00e+00 4.698130e+00 1.913595e+00 4.877979e-02 -6.000000e+00 2.246593e+00 226.41 -2.00 3.11 -2.00 501.81 0.00e+00 15.597 0.017 489.00 513.00 1 1.0984e+01 1.4724e-01 1.8594e-02 -6.0000e+00 1.7275e-01 9.8474e-03 3.7270e-02 1.1995e-03 -6.0000e+00 4.4093e-02 3.9878e-06 -1.4438e-02 1.0158e-02 1.2568e-04 -6.0000e+00 1.2614e-02 -7.0117e-02 4.5953e-04 12 8 8 10 0 0 31.65 19.13 5.37 -0.07012 -0.17026 8 2 1 4 0 4000.000 21.69 15.00 19.13 -10310 4985 11124 -9555 12154 4860 -1973 2141 2019 -9989 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