File name: Pandora142s1_MexicoCity-UNAM_20180911_L2Fit_fwvt1c13d20180420p1-8.txt File generation date: 20251127T084754.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Michel de Grutter Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 142 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora142_of_v1d20171226.txt Instrument calibration file used: Pandora142s1_CF_v13d20180420.txt Level 1 file used: Pandora142s1_MexicoCity-UNAM_20180911_L1_smca1c13d20180420p1-8.txt Full location name: Centro de Ciencias de la Atmosfera, UNAM Short location name: MexicoCity-UNAM Country of location: Mexico Location latitude [deg]: 19.3262 Location longitude [deg]: -99.1761 Location altitude [m]: 2280 Local noon date: 20180911 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1654 1803 Nominal wavelengths inside fitting window [nm]: 492.0414 492.1628 492.2842 492.4056 492.5270 492.6483 492.7696 492.8909 493.0122 493.1335 493.2548 493.3760 493.4972 493.6184 493.7396 493.8608 493.9820 494.1031 494.2242 494.3453 494.4664 494.5875 494.7086 494.8296 494.9506 495.0717 495.1927 495.3136 495.4346 495.5555 495.6765 495.7974 495.9183 496.0392 496.1600 496.2809 496.4017 496.5225 496.6433 496.7641 496.8849 497.0056 497.1264 497.2471 497.3678 497.4885 497.6091 497.7298 497.8504 497.9710 498.0916 498.2122 498.3328 498.4534 498.5739 498.6944 498.8149 498.9354 499.0559 499.1763 499.2968 499.4172 499.5376 499.6580 499.7784 499.8987 500.0191 500.1394 500.2597 500.3800 500.5003 500.6205 500.7408 500.8610 500.9812 501.1014 501.2216 501.3417 501.4619 501.5820 501.7021 501.8222 501.9423 502.0623 502.1824 502.3024 502.4224 502.5424 502.6624 502.7824 502.9023 503.0222 503.1421 503.2620 503.3819 503.5018 503.6216 503.7415 503.8613 503.9811 504.1008 504.2206 504.3403 504.4601 504.5798 504.6995 504.8192 504.9388 505.0585 505.1781 505.2977 505.4173 505.5369 505.6564 505.7760 505.8955 506.0150 506.1345 506.2540 506.3734 506.4929 506.6123 506.7317 506.8511 506.9705 507.0899 507.2092 507.3285 507.4478 507.5671 507.6864 507.8057 507.9249 508.0441 508.1633 508.2825 508.4017 508.5209 508.6400 508.7591 508.8782 508.9973 509.1164 509.2354 509.3545 509.4735 509.5925 509.7115 509.8305 509.9494 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180911T122835.0Z 6828.519850 397 1 32.01 2 89.65 85.40 114.70 81.85 0.00 1 0.00 1 0 41 1.563e-01 1.398e-01 1.124e-01 1.063e-01 3.387473e+04 9.655928e+03 1.962017e+03 -6.000000e+00 9.016226e+03 282.50 -2.00 20.00 -2.00 505.29 0.00e+00 -2.149923e-03 2.979101e-03 1.653644e-04 -6.000000e+00 4.507767e-03 282.50 -2.00 20.00 -2.00 499.94 0.00e+00 -8.097283e-01 2.199360e+00 2.189715e-01 -6.000000e+00 3.168128e+00 226.28 -2.00 3.11 -2.00 501.59 0.00e+00 20.213 0.037 489.00 513.00 1 1.1060e+01 1.6783e-01 2.9231e-02 -6.0000e+00 2.4366e-01 1.0890e-01 4.2014e-02 5.2189e-03 -6.0000e+00 6.2755e-02 3.3948e-06 1.0586e-02 8.9292e-03 7.0553e-05 -6.0000e+00 1.7734e-02 -7.2039e-02 1.4086e-04 12 8 8 10 0 0 -11.65 19.24 12.04 -0.07204 0.00139 8 2 1 4 0 4000.000 21.79 15.00 19.24 900000 3689 -19617 -6673 -6401 15324 9783 47188 5168 525 11543 35420 8268 9564 -7524 11323 -10817 -15832 -8220 958 -13459 -1573 20014 -13275 4426 -5946 23926 -5377 28156 -6987 184 25782 19484 -14992 25702 -7249 4410 9489 25765 -5012 -11031 3405 9158 7876 -19625 7592 -10682 -2785 -13330 26615 -16237 4367 -5898 10644 -824 -4287 -13487 -839 -521 31113 -10137 900000 7080 -6884 14096 8583 -19963 -2532 30582 29195 -5888 -4282 6302 16653 21223 8198 11826 -13093 -3048 20450 -10536 -12035 17506 7927 9371 -24769 27649 10586 -1149 -3225 13115 -10112 17967 -14868 2835 3609 16868 -27543 6557 18411 23936 -194 -1764 14425 4793 -3662 -2063 27191 -20313 -10250 -9313 21592 -13223 -1769 19465 5412 -650 12625 -14431 7567 -1399 20313 1383 10824 -13904 21373 -2685 11716 -15078 -1779 -14809 -5282 46452 -3808 5190 3954 30669 -3652 -5460 45416 17596 -9036 16873 -21446 906 -10230 14202 -1895 12766 501 900000 3602 -24392 -7559 -7409 14785 10090 34725 5606 590 11542 28022 8303 9396 -8627 10949 -13041 -20429 -10077 1091 -17597 -1843 19183 -17365 4911 -7242 21911 -6372 23920 -8032 195 21669 17689 -19255 23052 -8877 4817 9788 22611 -5806 -13491 3652 9378 8213 -26587 7961 -13170 -3144 -16266 21897 -19380 4215 -6217 9714 -854 -4696 -16376 -912 -565 25125 -12010 900000 7162 -7897 13188 8337 -24894 -2648 23284 22313 -6197 -4453 5997 14532 17779 7659 10497 -14394 -3014 16168 -11064 -12877 14403 7224 8518 -31105 21312 9472 -1136 -3234 11304 -10795 14601 -15854 2444 2931 11621 -27803 4761 11977 15056 -158 -1552 11615 4414 -3723 -2076 20796 -24049 -11062 -9979 17337 -14522 -1733 15651 5009 -647 11246 -16522 6952 -1359 15769 1260 9014 -14578 16209 -2540 9689 -15903 -1646 -15253 -4924 26794 -3512 4474 3506 21597 -3584 -5530 29258 14823 -9803 14404 -25988 885 -10983 12029 -1843 10805 478 SO 20180911T123244.0Z 6828.522732 401 1 32.01 2 88.68 85.74 113.78 82.25 0.00 1 0.00 1 0 79 4.114e-01 5.217e-01 5.460e-02 4.930e-02 6.932715e+04 5.061113e+03 6.221206e+03 -6.000000e+00 2.373291e+04 282.50 -2.00 20.00 -2.00 505.13 0.00e+00 1.121223e-01 1.275888e-03 6.802007e-03 -6.000000e+00 1.172077e-02 282.50 -2.00 20.00 -2.00 500.07 0.00e+00 7.172909e-01 1.108037e+00 1.128159e+00 -6.000000e+00 8.259198e+00 226.28 -2.00 3.11 -2.00 501.42 0.00e+00 18.088 0.027 489.00 513.00 1 8.5933e+00 8.3785e-02 1.8306e-01 -6.0000e+00 6.3539e-01 1.9086e-01 2.0735e-02 9.4433e-03 -6.0000e+00 1.6157e-01 7.3741e-06 2.8285e-02 1.8646e-03 2.8760e-03 -6.0000e+00 4.6483e-02 -3.4310e-02 4.7249e-04 12 8 8 10 0 0 98.02 19.25 1.39 -0.03431 0.16189 8 2 1 4 0 4000.000 21.79 15.00 19.25 44056 48741 46009 45490 32767 31756 27028 23039 7031 14483 15878 5961 1739 6664 -6110 -7735 -11838 -15952 -20128 -30703 -24509 -20011 -11553 -12964 -8906 -18311 -7562 -18092 -14562 -26553 -12319 -11765 -11445 -26071 -13001 -22835 -6601 -10368 13936 13639 27972 32670 39762 41605 53518 41703 42585 47612 64850 58263 59903 55722 59079 82856 89822 74528 84322 85046 87427 93657 89644 -87989 82509 93816 77296 94148 77364 71186 73077 87900 68514 71192 73617 58819 43305 59497 52341 56658 49580 41196 32579 28611 30480 14311 17213 2873 922 -13406 -13190 -15007 3000 -5927 -2425 -3060 -3721 -22824 -13423 -17225 -23420 -40330 -32290 -47203 -45272 -37393 -50022 -40421 -40979 -32635 -19516 -1236 -5523 1884 1181 19102 3118 24692 11678 18621 14071 29084 17336 21173 17559 32708 23532 25156 22369 24639 30436 19779 38138 24008 48534 17523 13058 9122 15037 17273 4224 -10405 8541 -3758 -7205 -22935 8235 -20702 15131 -12859 13090 -2387 37998 42060 42058 42302 34058 32327 27405 22776 7559 13666 14097 5598 1647 5838 -5839 -7258 -11173 -15120 -19246 -31987 -24321 -19732 -11046 -13158 -8925 -20013 -7259 -18385 -13801 -27814 -11407 -11095 -10976 -28951 -12764 -24737 -6286 -10774 12436 13348 26187 31743 38720 41940 50024 44376 45331 48536 56553 54792 56784 56736 60683 70852 74535 73432 77648 79644 82067 84611 85213 -440894 83035 83270 78230 79229 74094 70050 68388 69425 63223 62505 61601 54977 45525 52138 47569 47560 42408 36170 29421 25499 25272 12971 14094 2490 760 -12140 -11946 -14399 2544 -5572 -2165 -2625 -3044 -21230 -10809 -13397 -17846 -33822 -24361 -40745 -38423 -29529 -45113 -34535 -37552 -30009 -17327 -1002 -4981 1666 1094 15537 3055 20281 10938 16173 12493 22011 14644 17653 15709 26381 21366 23039 21299 22893 26255 18361 29052 20551 32593 15433 11674 8254 12652 14088 3831 -10556 7020 -3354 -6427 -22923 5941 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