File name: Pandora142s1_MexicoCity-UNAM_20181022_L2Fit_fout2c13d20180420p1-8.txt File generation date: 20251127T084652.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c13p1-8 Local principal investigator: Michel de Grutter Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 142 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora142_of_v1d20171226.txt Instrument calibration file used: Pandora142s1_CF_v13d20180420.txt Level 1 file used: Pandora142s1_MexicoCity-UNAM_20181022_L1_smca1c13d20180420p1-8.txt Full location name: Centro de Ciencias de la Atmosfera, UNAM Short location name: MexicoCity-UNAM Country of location: Mexico Location latitude [deg]: 19.3262 Location longitude [deg]: -99.1761 Location altitude [m]: 2280 Local noon date: 20181022 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 237 378 Nominal wavelengths inside fitting window [nm]: 305.0911 305.2324 305.3736 305.5149 305.6561 305.7973 305.9385 306.0797 306.2209 306.3620 306.5032 306.6443 306.7854 306.9265 307.0676 307.2087 307.3498 307.4909 307.6319 307.7730 307.9140 308.0550 308.1960 308.3370 308.4780 308.6189 308.7599 308.9008 309.0418 309.1827 309.3236 309.4645 309.6054 309.7463 309.8871 310.0280 310.1688 310.3096 310.4504 310.5912 310.7320 310.8728 311.0136 311.1543 311.2951 311.4358 311.5765 311.7172 311.8579 311.9986 312.1392 312.2799 312.4205 312.5612 312.7018 312.8424 312.9830 313.1236 313.2642 313.4047 313.5453 313.6858 313.8263 313.9668 314.1073 314.2478 314.3883 314.5287 314.6692 314.8096 314.9501 315.0905 315.2309 315.3713 315.5116 315.6520 315.7923 315.9327 316.0730 316.2133 316.3536 316.4939 316.6342 316.7744 316.9147 317.0549 317.1952 317.3354 317.4756 317.6158 317.7559 317.8961 318.0362 318.1764 318.3165 318.4566 318.5967 318.7368 318.8769 319.0169 319.1570 319.2970 319.4370 319.5770 319.7170 319.8570 319.9970 320.1370 320.2769 320.4168 320.5568 320.6967 320.8366 320.9764 321.1163 321.2562 321.3960 321.5359 321.6757 321.8155 321.9553 322.0951 322.2348 322.3746 322.5143 322.6541 322.7938 322.9335 323.0732 323.2129 323.3525 323.4922 323.6318 323.7715 323.9111 324.0507 324.1903 324.3299 324.4694 324.6090 324.7485 324.8881 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-238: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 239-380: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20181022T184600.7Z 6869.781952 5 1 33.35 2 31.17 191.83 149.52 58.38 0.00 1 0.00 1 0 17 6.856e-03 5.763e-03 7.218e-04 5.129e-04 1.269341e-01 2.625061e-04 1.435518e-03 -6.000000e+00 3.920575e-03 225.75 -2.00 3.11 -2.00 314.71 0.00e+00 1.478090e-04 2.140221e-05 2.749762e-05 -6.000000e+00 1.728580e-04 281.51 -2.00 20.00 -2.00 314.17 0.00e+00 1.168 0.000 302.00 328.00 3 3.5496e+00 6.6939e-04 1.0654e-02 -6.0000e+00 9.7027e-03 3.9542e-03 7.4165e-04 5.8484e-03 -6.0000e+00 1.0519e-02 1.1132e-03 4.2586e-04 2.9039e-03 -6.0000e+00 6.2686e-03 -2.6871e-03 1.9085e-04 8.4397e-04 -6.0000e+00 2.7134e-03 5.8048e-03 -1.7901e-04 1.4410e-05 1.1331e-05 -6.0000e+00 1.8530e-04 -1.3272e-02 7.4510e-05 11 1 0 11 8 0 70.20 19.11 0.19 -0.01327 -0.01462 156 31 1 5 0 213.647 21.69 15.00 19.11 -1255 -1167 -908 -1651 -918 -656 496 559 854 -88 51 -483 -397 -597 -8 -586 57 -157 785 595 730 700 1313 654 654 504 605 551 832 1556 1554 1743 1113 6 -1131 -1040 -1291 -870 -919 -707 -1091 -840 -991 -610 -698 -259 -729 -259 -618 292 289 633 661 724 450 592 377 293 209 494 561 784 1093 541 89 -310 -165 48 647 429 373 71 390 208 560 269 265 57 283 -456 -693 -1463 -1539 -1437 -1018 -849 -526 -282 -142 96 191 396 360 917 717 844 818 706 -138 -35 -510 -330 -158 -17 -510 -622 -659 -511 -190 44 94 -58 -307 -335 82 -24 353 290 258 -224 -63 -120 159 301 720 424 999 988 874 400 426 60 269 -19 234 -198 2 -207 -285 -396 -627 -605 -461 -452 -348 -581 -306 -208 163 205 313 -33 20 -193 -157 -262 -4 -299 29 -81 412 321 395 373 706 368 382 302 354 297 410 803 822 880 596 3 -616 -561 -704 -551 -638 -558 -922 -729 -877 -536 -609 -222 -604 -204 -468 218 225 516 561 637 403 535 345 266 186 441 520 776 1068 550 86 -293 -142 40 581 435 378 74 405 208 555 238 228 47 244 -407 -685 -1580 -1619 -1583 -1205 -1001 -649 -356 -178 121 220 442 365 903 750 964 954 897 -182 -44 -602 -361 -182 -20 -637 -813 -840 -674 -261 63 139 -83 -415 -443 98 -28 409 356 344 -297 -85 -160 220 394 887 495 1194 1205 1048 505 553 78 358 -26 322 -285 3 -313 -429 -580 -897 -839 SU 20181022T185102.7Z 6869.785448 8 1 33.41 2 31.44 194.15 148.54 59.73 0.00 1 0.00 1 0 17 6.792e-03 5.689e-03 1.056e-03 7.138e-04 1.283209e-01 3.645707e-04 1.451107e-03 -6.000000e+00 3.884096e-03 225.75 -2.00 3.11 -2.00 314.99 0.00e+00 8.798305e-05 3.134143e-05 2.278012e-05 -6.000000e+00 1.712419e-04 281.51 -2.00 20.00 -2.00 314.43 0.00e+00 1.171 0.000 302.00 328.00 3 4.0494e+00 9.3102e-04 1.0715e-02 -6.0000e+00 9.6125e-03 8.4564e-03 1.0324e-03 5.9181e-03 -6.0000e+00 1.0421e-02 2.7031e-04 5.9318e-04 2.9369e-03 -6.0000e+00 6.2102e-03 -2.8490e-03 2.6783e-04 8.4492e-04 -6.0000e+00 2.6883e-03 3.4989e-03 -1.5571e-04 2.0124e-05 1.1449e-05 -6.0000e+00 1.8355e-04 -1.3491e-02 8.6575e-05 10 0 0 10 0 0 99.98 19.12 0.20 -0.01349 -0.01466 142 28 1 5 0 235.244 21.69 15.00 19.12 -1189 -1065 -1337 -1538 -1203 -427 110 707 718 13 156 -786 -28 -664 117 -468 164 143 551 634 735 708 1273 501 793 477 708 391 789 1253 1514 1596 1071 -21 -1221 -1127 -1441 -939 -763 -772 -1048 -806 -829 -592 -682 -230 -525 -269 -681 147 336 460 506 795 384 707 239 209 175 485 487 776 1070 527 259 -314 -268 55 725 510 466 137 381 350 638 248 405 175 244 -622 -599 -1426 -1495 -1461 -928 -817 -521 -231 -11 94 62 240 240 884 595 942 930 715 -55 -8 -530 -362 -214 -98 -530 -573 -724 -561 -124 75 23 -83 -220 -329 -91 -16 296 243 164 -294 -24 -51 245 360 733 415 1105 990 876 449 483 51 255 16 286 -224 41 -269 -327 -381 -623 -596 -409 -387 -483 -507 -346 -126 34 223 248 5 53 -294 -10 -274 52 -224 79 70 273 321 374 354 644 266 435 269 389 198 397 606 748 823 540 -12 -622 -569 -802 -559 -539 -578 -838 -662 -694 -493 -563 -187 -411 -216 -527 112 266 383 407 662 326 604 207 180 148 410 428 727 1066 546 256 -281 -236 47 663 488 481 147 403 356 597 224 329 135 198 -567 -603 -1457 -1602 -1641 -1118 -982 -655 -297 -14 113 74 254 249 888 635 1017 1104 925 -69 -11 -638 -403 -233 -115 -673 -763 -941 -754 -172 110 35 -122 -303 -443 -111 -18 349 304 222 -398 -33 -69 345 478 920 494 1343 1141 1069 576 639 68 346 22 401 -329 62 -414 -502 -569 -906 -841 SU 20181022T185613.0Z 6869.789039 11 1 32.01 2 31.76 196.50 147.51 61.04 0.00 1 0.00 1 0 17 8.183e-03 6.269e-03 3.713e-03 2.606e-03 1.348698e-01 1.336070e-03 1.505012e-03 -6.000000e+00 4.679180e-03 225.75 -2.00 3.11 -2.00 314.75 0.00e+00 1.964838e-04 1.097125e-04 1.931086e-05 -6.000000e+00 2.063058e-04 281.51 -2.00 20.00 -2.00 314.21 0.00e+00 1.175 0.000 302.00 328.00 3 6.5148e+00 3.4076e-03 1.0889e-02 -6.0000e+00 1.1580e-02 7.7740e-02 3.7762e-03 6.1660e-03 -6.0000e+00 1.2555e-02 -4.0194e-03 2.1678e-03 3.0573e-03 -6.0000e+00 7.4816e-03 -2.8001e-03 9.7149e-04 8.8490e-04 -6.0000e+00 3.2384e-03 2.8623e-04 -2.6871e-04 7.3345e-05 1.1890e-05 -6.0000e+00 2.2116e-04 -1.3199e-02 7.5389e-05 10 0 0 10 0 0 99.94 19.13 0.18 -0.01320 -0.01522 8 2 1 5 0 4000.000 21.69 15.00 19.13 136 -650 313 -1163 -877 -3724 155 -2463 1241 -1013 113 -1749 -538 358 37 -722 395 -23 927 1705 495 1403 409 1207 647 1080 738 402 -706 1865 -822 1007 570 267 -1410 -1245 -2240 -339 -882 8 -594 318 -886 -77 -608 266 -470 -430 -987 545 155 634 465 -13 519 -397 607 -183 -119 -131 836 973 1043 690 627 -835 -774 -588 243 725 692 353 1243 398 459 147 -186 -1027 -569 -626 -835 -1175 -1685 -1272 -1040 -24 -779 308 95 535 114 -44 -357 335 -9 792 906 818 644 544 -654 -749 -394 -353 -721 -1086 -425 33 252 298 454 190 -37 -328 -437 -994 343 -193 282 -254 229 331 111 108 519 440 691 525 754 168 430 139 -4 139 -80 -283 540 33 54 -502 -699 -659 49 -247 117 -409 -274 -1146 48 -864 458 -391 42 -660 -216 156 17 -363 199 -12 482 901 267 741 221 670 373 631 427 217 -360 903 -417 523 311 145 -727 -636 -1252 -212 -636 6 -499 271 -775 -67 -527 228 -392 -347 -772 419 123 525 398 -11 463 -360 550 -166 -106 -118 766 938 1056 718 632 -785 -682 -507 221 717 725 379 1318 413 450 132 -155 -826 -476 -568 -819 -1226 -1828 -1424 -1226 -29 -995 397 122 661 133 -48 -361 331 -9 871 1065 1024 820 675 -777 -846 -437 -411 -891 -1393 -558 44 348 426 658 272 -50 -424 -530 -1170 405 -237 367 -346 314 450 148 139 642 522 794 613 915 212 552 180 -5 187 -113 -409 789 49 80 -735 -1005 -928 SU 20181022T190118.7Z 6869.792578 14 1 33.45 2 32.12 198.75 146.49 62.26 0.00 1 0.00 1 0 17 6.606e-03 5.670e-03 7.617e-04 5.369e-04 1.279938e-01 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