File name: Pandora142s1_MexicoCity-UNAM_20181024_L2Fit_fout2c13d20180420p1-8.txt File generation date: 20251127T084903.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c13p1-8 Local principal investigator: Michel de Grutter Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 142 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora142_of_v1d20171226.txt Instrument calibration file used: Pandora142s1_CF_v13d20180420.txt Level 1 file used: Pandora142s1_MexicoCity-UNAM_20181024_L1_smca1c13d20180420p1-8.txt Full location name: Centro de Ciencias de la Atmosfera, UNAM Short location name: MexicoCity-UNAM Country of location: Mexico Location latitude [deg]: 19.3262 Location longitude [deg]: -99.1761 Location altitude [m]: 2280 Local noon date: 20181024 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 237 378 Nominal wavelengths inside fitting window [nm]: 305.0911 305.2324 305.3736 305.5149 305.6561 305.7973 305.9385 306.0797 306.2209 306.3620 306.5032 306.6443 306.7854 306.9265 307.0676 307.2087 307.3498 307.4909 307.6319 307.7730 307.9140 308.0550 308.1960 308.3370 308.4780 308.6189 308.7599 308.9008 309.0418 309.1827 309.3236 309.4645 309.6054 309.7463 309.8871 310.0280 310.1688 310.3096 310.4504 310.5912 310.7320 310.8728 311.0136 311.1543 311.2951 311.4358 311.5765 311.7172 311.8579 311.9986 312.1392 312.2799 312.4205 312.5612 312.7018 312.8424 312.9830 313.1236 313.2642 313.4047 313.5453 313.6858 313.8263 313.9668 314.1073 314.2478 314.3883 314.5287 314.6692 314.8096 314.9501 315.0905 315.2309 315.3713 315.5116 315.6520 315.7923 315.9327 316.0730 316.2133 316.3536 316.4939 316.6342 316.7744 316.9147 317.0549 317.1952 317.3354 317.4756 317.6158 317.7559 317.8961 318.0362 318.1764 318.3165 318.4566 318.5967 318.7368 318.8769 319.0169 319.1570 319.2970 319.4370 319.5770 319.7170 319.8570 319.9970 320.1370 320.2769 320.4168 320.5568 320.6967 320.8366 320.9764 321.1163 321.2562 321.3960 321.5359 321.6757 321.8155 321.9553 322.0951 322.2348 322.3746 322.5143 322.6541 322.7938 322.9335 323.0732 323.2129 323.3525 323.4922 323.6318 323.7715 323.9111 324.0507 324.1903 324.3299 324.4694 324.6090 324.7485 324.8881 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-238: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 239-380: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20181024T124126.0Z 6871.528773 300 1 32.01 2 89.16 102.86 93.85 277.84 0.00 1 0.00 1 0 80 1.415e+00 8.890e-01 8.108e-01 5.766e-01 1.307417e+00 4.397031e-01 3.449730e-02 -6.000000e+00 1.015906e+00 225.68 -2.00 3.11 -2.00 311.64 0.00e+00 1.259512e-02 2.267281e-02 3.209000e-03 -6.000000e+00 5.070526e-02 281.46 -2.00 20.00 -2.00 311.32 0.00e+00 19.317 0.032 302.00 328.00 3 -4.0377e+00 1.0782e+00 1.6925e-01 -6.0000e+00 2.4892e+00 4.8866e+00 1.1894e+00 8.8502e-02 -6.0000e+00 2.7633e+00 -2.4933e+00 6.7890e-01 5.0872e-02 -6.0000e+00 1.6488e+00 9.4646e-01 2.8971e-01 1.6058e-02 -6.0000e+00 6.7391e-01 2.8377e-07 -4.5083e-02 1.2911e-02 8.3452e-04 -6.0000e+00 4.8729e-02 1.2260e-03 -1.2338e-03 12 9 8 11 8 0 -93.02 18.90 15.38 0.00123 -0.33755 8 2 1 5 0 4000.000 21.48 15.01 18.90 900000 -40035 900000 90158 900000 116086 197271 -64741 900000 -65560 900000 -102245 900000 399448 900000 900000 106944 900000 217978 900000 73670 284996 202995 900000 141570 900000 900000 131056 -3221 900000 -52644 193270 -49198 900000 -57818 900000 -27598 -21232 -49096 900000 2863 900000 108648 481297 34883 900000 900000 900000 -20982 -2663 62540 900000 303395 900000 900000 900000 900000 22446 900000 58157 900000 -90436 900000 154959 298688 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900000 900000 900000 900000 900000 5747 8085 900000 900000 900000 -166426 900000 23859 900000 -41082 900000 13638 900000 -10235 900000 -61593 900000 86881 898 55284 900000 -718 38657 36030 900000 900000 900000 188166 156031 46873 170557 27275 41798 900000 87486 74565 -8776 78658 51298 900000 -21549 900000 -59890 900000 21465 900000 19661 103468 -112055 900000 900000 112482 3731 13626 -8944 900000 15127 -60044 29663 51128 65621 -68833 -795 -9849 53212 SU 20181024T124528.0Z 6871.531574 304 1 32.01 2 88.24 103.20 94.75 278.18 0.00 1 0.00 1 0 37 9.820e-01 4.403e-01 7.096e-01 3.457e-01 7.020670e-01 2.257977e-01 2.080806e-02 -6.000000e+00 6.624504e-01 225.68 -2.00 3.11 -2.00 318.77 0.00e+00 7.075100e-03 3.208243e-02 1.528900e-02 -6.000000e+00 4.002399e-02 281.46 -2.00 20.00 -2.00 317.76 0.00e+00 16.920 0.022 302.00 328.00 3 -4.1335e-01 6.2170e-01 1.4476e-01 -6.0000e+00 1.6404e+00 2.5381e+00 7.1969e-01 7.9038e-02 -6.0000e+00 1.8181e+00 -1.8574e+00 3.6979e-01 2.2653e-02 -6.0000e+00 1.0744e+00 5.2920e-01 1.8484e-01 3.3538e-02 -6.0000e+00 4.8600e-01 5.2487e-07 2.3278e-02 1.2309e-02 2.9331e-04 -6.0000e+00 3.6275e-02 -4.6530e-03 -1.7317e-03 12 9 8 11 8 0 99.80 18.90 11.43 -0.00465 0.17027 8 2 1 5 0 4000.000 21.48 15.00 18.90 213723 38826 900000 900000 48945 900000 900000 -41220 900000 900000 900000 900000 900000 900000 900000 900000 900000 -82345 900000 47432 900000 900000 900000 900000 147066 -51298 37388 19460 900000 900000 900000 900000 -20406 900000 900000 900000 900000 900000 900000 900000 -37443 900000 -66216 900000 900000 900000 900000 900000 900000 900000 900000 152752 900000 -71086 900000 100042 900000 -61486 119507 138932 900000 900000 900000 47487 900000 48695 900000 258820 900000 -30285 30331 205804 900000 33507 89568 -53918 -30693 58448 126204 900000 146851 -25922 900000 82502 -27092 900000 9008 -23509 -52618 900000 900000 113637 -21763 900000 140733 537550 -21452 122331 66037 70513 47919 -2656 -74312 -27445 20981 100188 30333 84291 12805 84552 21690 12653 -8024 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