File name: Pandora142s1_MexicoCity-UNAM_20190824_L2Fit_fwvt1c15d20190823p1-8.txt File generation date: 20251127T093211.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c15p1-8 Local principal investigator: Michel de Grutter Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 142 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora142_of_v1d20171226.txt Instrument calibration file used: Pandora142s1_CF_v15d20190823.txt Level 1 file used: Pandora142s1_MexicoCity-UNAM_20190824_L1_smca1c15d20190823p1-8.txt Full location name: Centro de Ciencias de la Atmosfera, UNAM Short location name: MexicoCity-UNAM Country of location: Mexico Location latitude [deg]: 19.3262 Location longitude [deg]: -99.1761 Location altitude [m]: 2280 Local noon date: 20190824 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1654 1803 Nominal wavelengths inside fitting window [nm]: 492.0475 492.1689 492.2903 492.4117 492.5330 492.6544 492.7757 492.8970 493.0183 493.1396 493.2608 493.3821 493.5033 493.6245 493.7457 493.8668 493.9880 494.1091 494.2303 494.3514 494.4725 494.5935 494.7146 494.8357 494.9567 495.0777 495.1987 495.3197 495.4406 495.5616 495.6825 495.8034 495.9243 496.0452 496.1661 496.2869 496.4077 496.5286 496.6494 496.7701 496.8909 497.0117 497.1324 497.2531 497.3738 497.4945 497.6152 497.7358 497.8565 497.9771 498.0977 498.2183 498.3388 498.4594 498.5799 498.7005 498.8210 498.9415 499.0619 499.1824 499.3028 499.4233 499.5437 499.6641 499.7844 499.9048 500.0251 500.1455 500.2658 500.3861 500.5064 500.6266 500.7469 500.8671 500.9873 501.1075 501.2277 501.3478 501.4680 501.5881 501.7082 501.8283 501.9484 502.0685 502.1885 502.3086 502.4286 502.5486 502.6686 502.7885 502.9085 503.0284 503.1483 503.2682 503.3881 503.5080 503.6279 503.7477 503.8675 503.9873 504.1071 504.2269 504.3466 504.4664 504.5861 504.7058 504.8255 504.9452 505.0648 505.1845 505.3041 505.4237 505.5433 505.6629 505.7824 505.9019 506.0215 506.1410 506.2605 506.3799 506.4994 506.6189 506.7383 506.8577 506.9771 507.0965 507.2158 507.3352 507.4545 507.5738 507.6931 507.8124 507.9316 508.0509 508.1701 508.2893 508.4085 508.5277 508.6469 508.7660 508.8851 509.0042 509.1233 509.2424 509.3615 509.4805 509.5996 509.7186 509.8376 509.9566 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190824T122459.0Z 7175.517350 460 1 32.01 2 89.64 78.37 10.67 88.57 0.00 1 0.00 1 0 50 1.107e-01 1.063e-01 1.126e-01 1.093e-01 -2.517866e+03 6.647119e+03 2.212697e+02 -6.000000e+00 6.363683e+03 282.58 -2.00 20.00 -2.00 505.26 0.00e+00 9.298114e-03 3.037099e-03 4.485658e-04 -6.000000e+00 3.150511e-03 282.58 -2.00 20.00 -2.00 500.11 0.00e+00 3.003455e+00 2.255528e+00 7.794824e-02 -6.000000e+00 2.227172e+00 226.35 -2.00 3.11 -2.00 501.75 0.00e+00 20.182 0.037 489.00 513.00 1 1.0058e+01 1.7355e-01 2.5543e-02 -6.0000e+00 1.7118e-01 8.4078e-02 4.3694e-02 1.4587e-03 -6.0000e+00 4.3820e-02 6.4543e-06 1.5590e-02 1.1714e-02 1.9342e-04 -6.0000e+00 1.2431e-02 5.4559e-02 -4.4302e-04 12 9 8 11 8 0 16.28 19.02 14.28 0.05456 0.16269 8 2 1 4 0 4000.000 21.58 15.00 19.02 14577 14838 -14248 11838 3201 10323 -14286 -4740 552 10410 -13922 8222 -8495 184 9164 4511 4778 4095 8265 -6796 14075 -12895 -14822 -6651 16069 2722 2331 -8745 8897 -10499 21643 -1995 -9863 12050 4122 -4857 3811 -4376 4100 5227 2842 804 -10125 -2657 16821 -9514 3834 9754 1340 3108 7471 2130 6650 29568 -4122 3958 -3891 10669 -8152 12571 4686 -29379 -2792 -610 -3731 -6082 15791 30149 6132 104 9370 -5506 -12250 6206 -400 -3687 14066 10997 7490 3032 6138 -12350 3557 -4423 19342 -330 17165 -3779 10558 1754 26545 -4940 690 -8054 -17166 -7164 28602 -661 4513 6629 9684 -1250 14616 -7878 -6163 20422 2148 884 -2624 -12110 -19834 24899 -1266 26372 -2290 9387 1385 6728 -11609 -3744 -3716 14335 -9982 -11013 -11159 931 -10896 20489 -7222 9985 -7551 2344 1965 10416 3408 969 13538 -774 6435 -14793 -8915 2171 23230 11858 6910 2006 2307 -15626 1459 3274 12602 13107 -17082 11381 3416 10430 -18366 -5554 608 10257 -16959 7977 -9532 188 8607 4456 4788 4197 8239 -7823 13300 -15749 -18507 -7729 15136 2893 2460 -10065 8416 -11718 17747 -2074 -11348 11502 4285 -5482 3930 -4832 4165 5261 2955 865 -12275 -3028 16035 -11601 4080 9649 1403 3128 7065 2099 6305 23084 -4527 4110 -4402 10555 -9646 12203 4928 -42771 -3140 -667 -4141 -6797 14091 23201 5831 104 8513 -5788 -13811 5893 -401 -3750 11913 9505 6656 2801 5519 -13229 3283 -4408 15400 -316 13870 -3712 9074 1654 20092 -5110 683 -8683 -20034 -7493 20939 -622 3961 5620 7979 -1156 11804 -7913 -6047 15380 1903 791 -2454 -12624 -22733 19137 -1266 20565 -2349 8640 1368 6249 -12660 -3749 -3690 12015 -10580 -11843 -12049 899 -11771 16445 -7506 8758 -7692 2142 1782 8714 3072 907 11389 -754 5890 -16561 -9452 2076 18241 10326 6234 1859 2084 -16479 1309 2921 SO 20190824T122657.0Z 7175.518715 462 1 32.01 2 89.18 78.53 10.22 88.64 0.00 1 0.00 1 0 22 7.281e-02 7.027e-02 8.569e-02 8.431e-02 -2.822741e+03 4.990618e+03 6.338530e+01 -6.000000e+00 4.187272e+03 282.58 -2.00 20.00 -2.00 505.25 0.00e+00 2.998193e-03 2.332224e-03 2.000629e-04 -6.000000e+00 2.073010e-03 282.58 -2.00 20.00 -2.00 500.12 0.00e+00 3.173850e+00 1.704752e+00 7.786398e-02 -6.000000e+00 1.465340e+00 226.35 -2.00 3.11 -2.00 501.76 0.00e+00 19.320 0.032 489.00 513.00 1 9.9616e+00 1.3099e-01 2.2723e-02 -6.0000e+00 1.1263e-01 6.4461e-02 3.3374e-02 1.6549e-03 -6.0000e+00 2.8827e-02 8.5189e-06 1.4295e-02 9.1416e-03 8.5877e-05 -6.0000e+00 8.1784e-03 2.7062e-02 -2.7009e-04 12 8 8 10 0 0 73.51 19.03 11.76 0.02706 0.12622 8 2 1 4 0 4000.000 21.58 15.00 19.03 9510 -3653 -1205 -2483 6291 2748 10399 -2701 12877 4643 5275 -3355 -2363 -7317 12544 -9436 11586 -9584 -1722 -1341 4411 1148 5072 -7712 6138 -1254 13430 -9441 -4031 2896 -1798 1388 -815 5235 -8416 3152 932 2862 -2993 9073 -12996 1384 -3559 -1007 -964 12618 -8547 6415 -70 3362 -8810 2804 -6744 4218 2656 160 1062 8711 -1002 -10022 -6769 2505 1483 7884 -4653 -55 2327 6403 14558 2156 10061 -18184 -4402 -9939 -230 -9714 -6154 4473 4 9835 26708 14199 -5649 -2099 9747 -5959 3939 -1003 2700 4839 -2240 379 3817 6498 -6044 11868 -8796 1851 -6478 17896 -11611 1269 -4925 8493 1598 -163 -12616 -3641 3951 -1398 -6852 9982 8239 9357 1006 2642 4010 2398 259 -6429 4250 -4973 -4455 -4901 -5321 -2044 -3193 -14724 4038 -523 15432 -6817 1114 6720 7866 1710 4774 -1622 9753 5583 -8713 -983 7681 4972 2708 -3905 12325 4547 -7838 1228 8453 -3766 -1252 -2685 6385 2937 10439 -3072 12533 4814 5353 -3647 -2512 -8090 11468 -10728 10999 -11346 -1918 -1498 4662 1253 5340 -9223 6437 -1404 12939 -11094 -4382 2884 -1866 1416 -872 5409 -10018 3354 1003 2995 -3288 8851 -15739 1473 -4018 -1117 -1072 12265 -10049 6429 -73 3305 -9504 2671 -7058 4045 2649 167 1108 8489 -1070 -11627 -7639 2586 1544 7640 -5018 -56 2272 5935 12311 2036 8779 -20912 -4475 -10683 -224 -10217 -6164 4006 4 8324 19321 11623 -5621 -2029 8450 -6016 3614 -965 2514 4448 -2228 372 3655 6061 -6307 10274 -9108 1693 -6288 13657 -11788 1161 -4875 7468 1498 -153 -13206 -3475 3524 -1329 -7002 8847 7527 8521 997 2578 3844 2314 252 -6575 3896 -4975 -4441 -4931 -5382 -2002 -3163 -16245 3712 -499 12483 -6721 1006 5768 6750 1581 4355 -1592 8666 5177 -9298 -978 7066 4684 2579 -3896 10307 4038 -7805 1134 SO 20190824T122853.0Z 7175.520058 464 1 32.01 2 88.73 78.69 9.77 88.72 0.00 1 0.00 1 0 22 6.718e-02 6.550e-02 6.522e-02 6.431e-02 1.637356e+03 4.087408e+03 1.919852e+02 -6.000000e+00 3.866411e+03 282.58 -2.00 20.00 -2.00 505.29 0.00e+00 4.803054e-03 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