File name: Pandora142s1_MexicoCity-UNAM_20191025_L2Fit_fwvt1c15d20190823p1-8.txt File generation date: 20251127T100057.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c15p1-8 Local principal investigator: Michel de Grutter Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 142 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora142_of_v2d20171226.txt Instrument calibration file used: Pandora142s1_CF_v15d20190823.txt Level 1 file used: Pandora142s1_MexicoCity-UNAM_20191025_L1_smca1c15d20190823p1-8.txt Full location name: Centro de Ciencias de la Atmosfera, UNAM Short location name: MexicoCity-UNAM Country of location: Mexico Location latitude [deg]: 19.3262 Location longitude [deg]: -99.1761 Location altitude [m]: 2280 Local noon date: 20191025 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1654 1803 Nominal wavelengths inside fitting window [nm]: 492.0475 492.1689 492.2903 492.4117 492.5330 492.6544 492.7757 492.8970 493.0183 493.1396 493.2608 493.3821 493.5033 493.6245 493.7457 493.8668 493.9880 494.1091 494.2303 494.3514 494.4725 494.5935 494.7146 494.8357 494.9567 495.0777 495.1987 495.3197 495.4406 495.5616 495.6825 495.8034 495.9243 496.0452 496.1661 496.2869 496.4077 496.5286 496.6494 496.7701 496.8909 497.0117 497.1324 497.2531 497.3738 497.4945 497.6152 497.7358 497.8565 497.9771 498.0977 498.2183 498.3388 498.4594 498.5799 498.7005 498.8210 498.9415 499.0619 499.1824 499.3028 499.4233 499.5437 499.6641 499.7844 499.9048 500.0251 500.1455 500.2658 500.3861 500.5064 500.6266 500.7469 500.8671 500.9873 501.1075 501.2277 501.3478 501.4680 501.5881 501.7082 501.8283 501.9484 502.0685 502.1885 502.3086 502.4286 502.5486 502.6686 502.7885 502.9085 503.0284 503.1483 503.2682 503.3881 503.5080 503.6279 503.7477 503.8675 503.9873 504.1071 504.2269 504.3466 504.4664 504.5861 504.7058 504.8255 504.9452 505.0648 505.1845 505.3041 505.4237 505.5433 505.6629 505.7824 505.9019 506.0215 506.1410 506.2605 506.3799 506.4994 506.6189 506.7383 506.8577 506.9771 507.0965 507.2158 507.3352 507.4545 507.5738 507.6931 507.8124 507.9316 508.0509 508.1701 508.2893 508.4085 508.5277 508.6469 508.7660 508.8851 509.0042 509.1233 509.2424 509.3615 509.4805 509.5996 509.7186 509.8376 509.9566 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20191025T123934.0Z 7237.527477 358 1 32.01 2 89.66 102.96 54.10 96.64 0.00 1 0.00 1 0 15 1.441e-01 1.315e-01 1.712e-01 1.642e-01 -1.939018e+03 9.894135e+03 3.681353e+02 -6.000000e+00 8.247682e+03 281.43 -2.00 20.00 -2.00 505.21 0.00e+00 -2.265726e-03 4.518266e-03 1.592815e-04 -6.000000e+00 4.090211e-03 281.43 -2.00 20.00 -2.00 500.00 0.00e+00 9.335608e-01 3.381934e+00 3.879255e-02 -6.000000e+00 2.897728e+00 225.65 -2.00 3.11 -2.00 501.66 0.00e+00 20.262 0.037 489.00 513.00 1 1.0835e+01 2.5877e-01 2.3047e-02 -6.0000e+00 2.2266e-01 1.3306e-01 6.6547e-02 1.2624e-03 -6.0000e+00 5.6970e-02 4.0148e-06 -4.6195e-03 1.8009e-02 9.2692e-05 -6.0000e+00 1.6181e-02 2.0707e-02 -1.9843e-04 12 8 8 10 0 0 99.59 18.62 8.86 0.02071 -0.01134 8 2 1 4 0 4000.000 21.27 15.00 18.62 16662 -9975 -15360 24155 3777 -11776 -12135 -5077 18670 3061 -16727 -2393 -4778 9892 -7682 15235 16578 -10439 22454 29853 1488 8593 -22016 -32 17156 17151 -11146 4216 -3403 -14953 -10189 16716 -1400 12389 11129 9676 -8735 -5697 14531 5225 3862 10537 -4154 -7360 20053 -9442 7914 1355 2516 113 32527 3080 3297 1434 14680 -4201 9890 1466 10202 -14231 -4381 -22864 16963 -12188 9875 -1899 2906 18949 23750 12642 -14291 -13800 12757 18175 -23481 23571 21766 2434 6529 15077 -40 -7160 -14817 60408 -465 -427 -4087 22314 -17125 -810 -3286 -10492 1548 16981 12324 -10051 -9377 22528 34881 -1876 -4554 -10125 11642 -7234 7602 -2081 -8402 4842 23053 -18955 13449 -4831 14176 -11964 651 -1168 24825 16649 9795 17953 5348 13766 -20788 -5333 -6234 1338 22595 19234 4925 5518 -20422 11246 -13687 3428 -20516 9107 -3741 20584 -13228 20365 2590 12999 9248 -4571 22801 -8990 -12524 -9403 -3085 -3341 14391 -11045 -18252 20419 3952 -14548 -15335 -6070 17952 3384 -21917 -2708 -5445 9718 -8831 14126 15343 -12651 20487 25871 1685 9133 -31054 -37 16829 16809 -14109 4571 -3883 -18556 -11834 15086 -1508 12035 11204 9987 -10681 -6691 13986 5417 4038 10343 -4700 -8641 18344 -11346 8055 1447 2606 117 24373 2948 3100 1376 12659 -4408 9283 1503 9683 -16867 -4737 -29330 15052 -14154 9274 -1961 2830 15684 18595 10823 -15569 -14949 10871 14882 -28490 18458 17082 2247 5758 12231 -37 -7176 -16098 33274 -449 -416 -4132 17758 -19676 -803 -3356 -11552 1537 14673 11091 -10986 -10032 17603 23898 -1771 -4373 -10353 9975 -7562 7038 -2105 -8932 4491 17932 -21681 11514 -4945 12311 -13362 650 -1188 19872 14295 8875 14894 4911 11586 -23962 -5323 -6272 1255 17393 15227 4429 4914 -22883 9286 -14031 2973 -22163 7563 -3551 15875 -14095 16091 2418 11071 8177 -4600 17818 -9337 -13214 -9436 -2878 -3109 SO 20191025T124337.0Z 7237.530289 362 1 32.01 2 88.73 103.30 53.18 97.06 0.00 1 0.00 1 0 15 9.589e-02 9.171e-02 1.040e-01 1.009e-01 -9.017037e+02 6.131461e+03 4.451545e+02 -6.000000e+00 5.489928e+03 281.43 -2.00 20.00 -2.00 505.18 0.00e+00 8.215837e-04 2.824804e-03 1.148933e-04 -6.000000e+00 2.725001e-03 281.43 -2.00 20.00 -2.00 499.81 0.00e+00 3.388262e+00 2.100774e+00 8.726465e-02 -6.000000e+00 1.940043e+00 225.65 -2.00 3.11 -2.00 501.49 0.00e+00 18.257 0.027 489.00 513.00 1 1.0315e+01 1.6241e-01 2.1333e-02 -6.0000e+00 1.4885e-01 8.7548e-02 4.0929e-02 1.5043e-03 -6.0000e+00 3.8479e-02 6.7623e-06 8.3451e-03 1.0962e-02 1.0426e-04 -6.0000e+00 1.0791e-02 5.2311e-03 -4.0149e-04 12 9 8 11 8 0 99.51 18.64 1.42 0.00523 0.06312 8 2 1 4 0 4000.000 21.27 15.00 18.64 900000 14146 -10423 21712 -1922 8642 -13759 8412 -4103 1149 -9509 194 -10899 -8964 -15278 579 -3547 10597 -4331 -3175 -2437 2717 2243 14359 2213 -3437 3381 4802 6218 1128 14218 1087 3423 -14001 12829 -14028 2447 5232 7278 9167 17413 -13835 13437 3514 12234 -784 6232 3210 8353 2036 12069 7230 -7383 -10149 -1269 -802 2395 17254 -6012 5520 -1799 4022 -4105 6184 -6865 -726 -3918 10273 5538 892 -11954 9553 -9125 11556 -14928 -2300 -877 7342 -13619 3694 866 7860 3671 -2753 16101 -6594 6338 -4740 6536 -4559 4168 -10419 6005 -14329 17509 -3782 -527 -5274 4708 -10944 4737 11759 -9074 20608 13471 -2398 11042 -6898 31815 -4648 -4743 3283 814 14955 -13305 3138 -4163 6475 -10396 2547 3595 7330 -10164 18762 -7679 23442 1789 7202 -8130 829 -1092 5049 15042 -5865 12153 4535 2212 6956 2837 -2415 3375 5218 11632 -17872 -2963 -15545 19260 -13917 -6426 -2797 900000 12694 -12067 19107 -2167 8991 -17974 8972 -4928 1300 -11710 214 -13222 -10545 -18992 620 -4006 10675 -5132 -3757 -2876 3058 2534 14478 2507 -4104 3756 5198 6483 1202 13181 1143 3577 -17734 12862 -18249 2706 5564 7514 9220 16195 -17363 13114 3793 12239 -884 6535 3410 8277 2088 10975 6727 -7814 -11099 -1302 -837 2465 15546 -6752 5541 -1932 4092 -4507 6129 -7614 -747 -4094 9240 5137 852 -12791 8350 -9569 10067 -16691 -2262 -837 6400 -14325 3282 792 6746 3300 -2645 13027 -6628 5652 -4689 5811 -4513 3832 -11102 5519 -15978 14379 -3730 -495 -5072 4030 -10682 3985 9383 -9016 15845 11187 -2297 9200 -6731 21525 -4437 -4596 2991 769 12489 -14591 2952 -4194 5865 -10927 2342 3230 6313 -10298 14523 -7622 17403 1625 6202 -8069 753 -1001 4311 11542 -5432 9560 3878 1967 6016 2578 -2324 3090 4714 9926 -20151 -2889 -16868 14827 -14327 -6092 -2566 SO 20191025T124729.0Z 7237.532975 366 1 32.01 2 87.84 103.63 52.30 97.48 0.00 1 0.00 1 0 22 5.824e-02 5.484e-02 6.516e-02 6.424e-02 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