File name: Pandora142s1_MexicoCity-UNAM_20200130_L2Fit_fout2c15d20190823p1-8.txt File generation date: 20251127T103147.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Michel de Grutter Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 142 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora142_of_v2d20171226.txt Instrument calibration file used: Pandora142s1_CF_v15d20190823.txt Level 1 file used: Pandora142s1_MexicoCity-UNAM_20200130_L1_smca1c15d20190823p1-8.txt Full location name: Centro de Ciencias de la Atmosfera, UNAM Short location name: MexicoCity-UNAM Country of location: Mexico Location latitude [deg]: 19.3262 Location longitude [deg]: -99.1761 Location altitude [m]: 2280 Local noon date: 20200130 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 237 378 Nominal wavelengths inside fitting window [nm]: 305.1232 305.2643 305.4054 305.5465 305.6875 305.8286 305.9696 306.1107 306.2517 306.3927 306.5337 306.6747 306.8157 306.9567 307.0976 307.2386 307.3795 307.5205 307.6614 307.8023 307.9432 308.0841 308.2249 308.3658 308.5067 308.6475 308.7883 308.9292 309.0700 309.2108 309.3516 309.4923 309.6331 309.7738 309.9146 310.0553 310.1960 310.3368 310.4775 310.6181 310.7588 310.8995 311.0402 311.1808 311.3214 311.4621 311.6027 311.7433 311.8839 312.0244 312.1650 312.3056 312.4461 312.5866 312.7272 312.8677 313.0082 313.1487 313.2891 313.4296 313.5701 313.7105 313.8509 313.9914 314.1318 314.2722 314.4126 314.5529 314.6933 314.8337 314.9740 315.1143 315.2547 315.3950 315.5353 315.6755 315.8158 315.9561 316.0963 316.2366 316.3768 316.5170 316.6572 316.7974 316.9376 317.0778 317.2179 317.3581 317.4982 317.6383 317.7785 317.9186 318.0587 318.1987 318.3388 318.4789 318.6189 318.7589 318.8990 319.0390 319.1790 319.3189 319.4589 319.5989 319.7388 319.8788 320.0187 320.1586 320.2985 320.4384 320.5783 320.7182 320.8580 320.9979 321.1377 321.2775 321.4173 321.5571 321.6969 321.8367 321.9765 322.1162 322.2560 322.3957 322.5354 322.6751 322.8148 322.9545 323.0941 323.2338 323.3734 323.5131 323.6527 323.7923 323.9319 324.0715 324.2111 324.3506 324.4902 324.6297 324.7693 324.9088 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-238: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 239-380: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200130T134045.0Z 7334.569966 456 1 50.08 2 84.43 110.98 135.47 69.14 0.00 1 0.00 1 0 25 6.321e-01 2.593e-02 3.119e-01 7.865e-03 8.261435e-01 4.550448e-03 8.747049e-03 -6.000000e+00 3.620590e-01 223.61 -2.00 3.11 -2.00 322.03 0.00e+00 5.082581e-03 2.604422e-03 9.062084e-03 -6.000000e+00 1.778508e-02 279.44 -2.00 20.00 -2.00 321.58 0.00e+00 9.107 0.003 302.00 328.00 3 4.0228e-01 1.7547e-02 9.5470e-02 -6.0000e+00 8.9608e-01 4.2866e-01 2.6205e-02 8.2849e-02 -6.0000e+00 9.8024e-01 -5.1785e-01 2.7422e-02 3.3963e-02 -6.0000e+00 5.7646e-01 2.0321e-01 1.2483e-02 7.3913e-03 -6.0000e+00 2.5088e-01 1.5249e-04 -2.9812e-03 2.2604e-04 1.4117e-04 -6.0000e+00 1.7570e-02 9.5095e-03 -1.1338e-04 12 8 8 10 0 0 11.41 18.18 0.23 0.00951 -0.01289 103 20 1 5 0 486.140 20.96 15.00 18.18 900000 -123361 900000 -207300 900000 -280754 900000 -273734 900000 -250852 900000 -242123 154983 -147811 900000 -111579 7004 -90425 74154 -96940 108837 -38472 -37168 -16553 -27341 5979 -64851 157 -83157 57915 -33154 900000 -25757 146348 8611 127202 -23599 63072 -4166 53971 -2778 20693 -1798 45304 -813 46419 6037 22881 31741 30066 36152 13120 35163 18879 26258 15075 27065 8951 28460 2459 17616 1932 21807 5087 21007 964 17298 3567 12721 3825 12719 3881 8286 799 8170 5447 2742 804 2308 1317 -1247 -365 -1428 1122 -1284 911 -1534 697 -938 3511 -1286 5135 -4051 -1880 -4976 -1311 -2560 -237 -403 874 -1606 -551 -953 -3071 -3324 -2764 -2650 -3232 -1145 -1603 636 59 1276 -237 1168 -229 1019 -1186 571 -587 741 -611 1224 -840 757 145 19563 -73 132 -612 -204 335 409 -321 -351 96 -181 337 268 -396 -1327 -445 900000 -945 900000 -2404 900000 -5919 900000 -6474 900000 -5522 900000 -6469 1187 -2878 900000 -2294 54 -1884 568 -2337 833 -544 -550 -219 -422 70 -1435 2 -2201 500 -813 900000 -796 1121 189 974 -799 1167 -168 1491 -138 882 -97 1639 -45 1747 337 1165 1607 1701 2181 1072 2572 1717 2345 1541 2506 945 2436 265 1774 252 2738 826 3025 167 2660 669 2507 920 3004 1003 1959 186 1600 1007 519 171 573 394 -445 -146 -620 504 -628 459 -822 368 -495 1678 -603 2189 -1925 -978 -3114 -937 -2150 -220 -393 808 -1388 -419 -693 -2391 -2775 -2415 -2489 -3348 -1319 -2113 906 88 1869 -339 1587 -312 1429 -1800 890 -917 1096 -878 1684 -1137 979 183 20918 -107 221 -1164 -421 735 949 -804 -933 261 -498 929 716 -996 -3147 -992 SS 20200130T135317.1Z 7334.578670 459 1 50.18 2 81.68 112.15 132.78 71.03 0.00 1 0.00 1 0 25 3.110e-01 6.918e-03 1.694e-01 2.790e-03 6.315730e-01 1.483387e-03 6.419164e-03 -6.000000e+00 1.750671e-01 223.61 -2.00 3.11 -2.00 321.21 0.00e+00 2.364865e-03 7.000502e-04 2.026273e-03 -6.000000e+00 7.756098e-03 279.45 -2.00 20.00 -2.00 320.69 0.00e+00 6.513 0.001 302.00 328.00 3 1.0524e+00 4.9537e-03 5.8763e-02 -6.0000e+00 4.3141e-01 4.6793e-02 6.8760e-03 3.4453e-02 -6.0000e+00 4.6972e-01 -1.9477e-02 7.2375e-03 1.6094e-02 -6.0000e+00 2.8003e-01 -3.5464e-03 3.4786e-03 5.9429e-03 -6.0000e+00 1.2075e-01 6.6416e-04 -1.0443e-03 8.0017e-05 6.0884e-05 -6.0000e+00 8.4010e-03 8.5614e-03 -8.9060e-05 11 8 0 10 0 0 99.85 18.17 0.10 0.00856 0.00071 185 36 1 5 0 271.201 20.87 15.02 18.17 -34983 -137618 -56303 -102292 -87703 97725 -98976 -69830 -129094 -20579 -101289 25162 -101196 24153 -79309 30095 -44913 44512 -52175 37145 -50215 52327 -34638 35745 -10714 23654 -24350 2598 -11631 12041 17016 -10762 9163 -2909 8847 -7290 1930 -5731 5529 -7621 6711 -6704 7894 -3127 11238 -6745 10652 -3774 7484 -27 5036 213 5549 982 2647 453 362 1161 627 1624 2014 2492 340 2588 893 1288 -1698 3083 -650 1464 -1180 1946 -913 1990 -1641 2026 -2096 1640 -1799 1314 -1564 -740 -1654 -1308 -981 92 -148 50 659 938 1260 -66 1103 -364 769 -532 983 -156 606 -1065 100 -426 289 -1212 -422 -1753 -606 -508 205 -75 366 227 252 154 420 337 -168 -163 -579 -287 -597 152 -50 1089 -255 948 220 1136 395 208 -185 191 65 -60 -424 38 -141 38 223 -133 -349 48 -127 -1377 -289 -747 -538 266 -781 -488 -1654 -111 -1176 117 -1747 178 -1705 292 -909 464 -1315 457 -1314 589 -877 543 -258 443 -686 57 -296 284 453 -422 337 -120 317 -317 89 -338 354 -635 535 -639 688 -307 986 -718 995 -420 792 -3 665 33 878 175 486 88 72 225 119 308 411 570 90 729 255 359 -494 916 -228 567 -500 809 -376 740 -571 626 -661 537 -710 591 -832 -434 -1041 -873 -696 68 -114 39 500 669 836 -43 697 -254 608 -489 1015 -181 711 -1217 103 -402 264 -1196 -439 -1933 -705 -638 281 -114 592 373 404 235 610 487 -252 -258 -964 -479 -970 236 -76 1574 -362 1281 304 1710 669 386 -367 393 142 -139 -1033 93 -357 97 551 -313 -782 104 SS 20200130T143102.4Z 7334.604889 476 1 2.90 2 73.55 116.07 124.50 75.86 0.00 1 0.00 1 0 25 1.384e-02 5.943e-03 6.741e-03 1.303e-03 3.591499e-01 6.493924e-04 3.857849e-03 -6.000000e+00 7.793904e-03 223.61 -2.00 3.11 -2.00 318.02 0.00e+00 3.368511e-04 1.158813e-04 1.487794e-04 -6.000000e+00 3.451328e-04 279.45 -2.00 20.00 -2.00 317.36 0.00e+00 3.477 0.000 302.00 328.00 3 5.5989e-01 1.7280e-03 3.0995e-02 -6.0000e+00 1.9206e-02 1.7474e-02 1.9622e-03 1.6277e-02 -6.0000e+00 2.0909e-02 -2.8029e-03 1.2897e-03 8.0876e-03 -6.0000e+00 1.2465e-02 -4.6207e-03 6.7581e-04 2.3588e-03 -6.0000e+00 5.3769e-03 1.3738e-02 -3.9789e-04 3.6627e-05 2.5788e-05 -6.0000e+00 3.7384e-04 6.7132e-03 -4.8962e-05 12 1 1 12 1 1 54.45 18.18 0.16 0.00671 0.00372 45 167 1 5 0 58.814 20.96 15.01 18.18 -3880 -2206 -4768 -4237 -6539 -1949 -4786 279 -3347 -4341 -4093 -1867 -1745 593 -1108 -1121 306 -111 373 -1059 136 -806 887 935 -176 -421 -135 -134 74 792 2421 555 1228 -920 -1694 -3060 -902 -705 -816 -1139 -764 -1281 -662 -290 -331 -433 -61 -444 -223 426 479 1287 823 733 961 1110 585 549 293 628 1022 1619 1149 787 303 -395 -238 808 662 319 316 -238 208 -2 214 -78 407 -9 -267 -702 -1008 -1671 -1467 -1524 -1037 -628 -569 -103 130 633 664 747 1269 1120 550 553 385 237 47 -725 -639 87 106 -655 -591 -1072 -941 -218 -50 50 -94 141 -22 -86 531 439 413 91 -330 -433 -447 -433 348 759 510 608 1238 968 799 251 -109 96 352 -14 -75 -131 -301 -160 -6 -378 -536 -185 -230 -139 -307 -246 -358 -113 -292 18 -252 -340 -325 -161 -178 70 -153 -170 48 -17 60 -181 23 -138 159 180 -36 -89 -28 -26 15 155 518 134 320 -239 -420 -805 -266 -233 -325 -485 -347 -610 -321 -141 -161 -211 -29 -213 -107 214 262 707 484 455 612 725 387 357 188 405 698 1139 889 606 237 -290 -169 588 515 280 280 -214 182 -1 166 -58 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