File name: Pandora142s1_MexicoCity-UNAM_20200214_L2Fit_fout2c15d20190823p1-8.txt File generation date: 20251127T103214.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Michel de Grutter Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 142 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora142_of_v2d20171226.txt Instrument calibration file used: Pandora142s1_CF_v15d20190823.txt Level 1 file used: Pandora142s1_MexicoCity-UNAM_20200214_L1_smca1c15d20190823p1-8.txt Full location name: Centro de Ciencias de la Atmosfera, UNAM Short location name: MexicoCity-UNAM Country of location: Mexico Location latitude [deg]: 19.3262 Location longitude [deg]: -99.1761 Location altitude [m]: 2280 Local noon date: 20200214 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 237 378 Nominal wavelengths inside fitting window [nm]: 305.1232 305.2643 305.4054 305.5465 305.6875 305.8286 305.9696 306.1107 306.2517 306.3927 306.5337 306.6747 306.8157 306.9567 307.0976 307.2386 307.3795 307.5205 307.6614 307.8023 307.9432 308.0841 308.2249 308.3658 308.5067 308.6475 308.7883 308.9292 309.0700 309.2108 309.3516 309.4923 309.6331 309.7738 309.9146 310.0553 310.1960 310.3368 310.4775 310.6181 310.7588 310.8995 311.0402 311.1808 311.3214 311.4621 311.6027 311.7433 311.8839 312.0244 312.1650 312.3056 312.4461 312.5866 312.7272 312.8677 313.0082 313.1487 313.2891 313.4296 313.5701 313.7105 313.8509 313.9914 314.1318 314.2722 314.4126 314.5529 314.6933 314.8337 314.9740 315.1143 315.2547 315.3950 315.5353 315.6755 315.8158 315.9561 316.0963 316.2366 316.3768 316.5170 316.6572 316.7974 316.9376 317.0778 317.2179 317.3581 317.4982 317.6383 317.7785 317.9186 318.0587 318.1987 318.3388 318.4789 318.6189 318.7589 318.8990 319.0390 319.1790 319.3189 319.4589 319.5989 319.7388 319.8788 320.0187 320.1586 320.2985 320.4384 320.5783 320.7182 320.8580 320.9979 321.1377 321.2775 321.4173 321.5571 321.6969 321.8367 321.9765 322.1162 322.2560 322.3957 322.5354 322.6751 322.8148 322.9545 323.0941 323.2338 323.3734 323.5131 323.6527 323.7923 323.9319 324.0715 324.2111 324.3506 324.4902 324.6297 324.7693 324.9088 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-238: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 239-380: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200214T140032.0Z 7349.583704 227 1 50.02 2 78.45 108.44 48.25 235.25 0.00 1 0.00 1 0 17 1.120e-01 7.716e-03 8.107e-02 2.735e-03 4.988646e-01 1.419202e-03 5.146951e-03 -6.000000e+00 6.313301e-02 223.94 -2.00 3.11 -2.00 320.60 0.00e+00 4.512834e-03 5.492417e-04 3.222674e-04 -6.000000e+00 2.793812e-03 279.52 -2.00 20.00 -2.00 320.02 0.00e+00 4.841 0.000 302.00 328.00 3 2.5895e+00 4.3695e-03 4.3427e-02 -6.0000e+00 1.5569e-01 -5.1065e-02 5.5497e-03 2.3758e-02 -6.0000e+00 1.6946e-01 1.6846e-03 5.2990e-03 1.3026e-02 -6.0000e+00 1.0101e-01 -8.4724e-03 2.6646e-03 6.7716e-03 -6.0000e+00 4.3531e-02 5.7773e-04 -3.7418e-04 8.0912e-05 6.4244e-05 -6.0000e+00 3.0255e-03 7.8948e-03 -7.0476e-05 11 9 0 11 8 0 0.11 18.26 0.24 0.00789 0.00508 103 20 1 5 0 485.166 20.96 14.99 18.26 -18849 -33074 -13789 -42613 -38233 -71175 4877 -32607 -8295 -47598 -15428 -37542 -10162 -27161 3790 -8059 16696 -2111 9218 -7579 4452 -5037 6712 -5394 -2293 -5039 5088 -9530 4613 -2106 1188 6743 -418 1296 -3311 1971 -5503 2950 -3294 1315 -2080 1657 -3540 3395 224 920 -889 1922 336 2671 1890 3076 -89 1080 881 300 320 -802 -985 599 -141 1361 2287 477 771 -1220 538 -1103 790 -257 758 -465 236 -528 268 61 -566 -443 -35 -1157 -736 -1784 -1305 -1786 -759 65 167 620 659 1654 323 742 8 1195 492 650 551 325 -237 -664 -1571 222 240 -330 -554 -665 -821 125 286 246 366 90 -102 -138 374 231 427 52 -128 -493 -22 -51 570 919 474 578 -4540 781 1061 406 150 -95 212 -315 -203 -40 -65 47 164 -113 -306 388 -160 -361 -127 -486 -389 -1035 37 -403 -88 -719 -195 -642 -182 -664 83 -226 401 -67 277 -281 147 -186 234 -228 -99 -233 210 -441 189 -103 66 379 -28 85 -217 129 -447 266 -383 168 -298 242 -567 517 36 150 -150 322 59 497 393 691 -22 285 241 85 92 -228 -276 168 -43 459 857 195 308 -474 204 -449 360 -133 414 -260 126 -265 120 25 -225 -186 -17 -660 -476 -1288 -995 -1351 -611 55 147 549 570 1431 262 560 6 944 444 624 603 394 -294 -786 -1715 233 248 -343 -616 -778 -1021 165 414 391 615 151 -166 -210 532 324 622 82 -212 -832 -36 -81 872 1339 667 777 -6454 1153 1741 730 285 -189 441 -702 -446 -91 -150 110 373 -262 -674 818 SS 20200214T140652.1Z 7349.588103 230 1 50.16 2 77.04 109.07 49.47 236.46 0.00 1 0.00 1 0 25 7.683e-02 5.166e-03 4.454e-02 1.820e-03 4.636802e-01 9.318275e-04 4.813367e-03 -6.000000e+00 4.332201e-02 223.94 -2.00 3.11 -2.00 320.25 0.00e+00 4.146813e-03 3.245686e-04 6.946659e-04 -6.000000e+00 1.916870e-03 279.52 -2.00 20.00 -2.00 319.66 0.00e+00 4.348 0.000 302.00 328.00 3 2.3296e+00 2.7634e-03 3.9712e-02 -6.0000e+00 1.0683e-01 -2.8915e-02 3.4029e-03 2.3279e-02 -6.0000e+00 1.1628e-01 1.1055e-02 3.0844e-03 1.1247e-02 -6.0000e+00 6.9308e-02 -1.7143e-02 1.5858e-03 6.0201e-03 -6.0000e+00 2.9872e-02 1.0954e-03 -5.1168e-04 5.3372e-05 4.9769e-05 -6.0000e+00 2.0758e-03 7.8049e-03 -4.5886e-05 10 0 0 10 0 0 -2.93 18.25 0.15 0.00780 0.00396 155 30 1 5 0 323.560 20.96 15.00 18.25 -30503 15036 -36231 12689 -41632 24394 -25475 23758 -24802 5800 -22963 8862 -3355 7078 -642 189 -479 -1846 1465 -2035 5429 -7657 3893 -5525 5171 -5564 2836 -7080 579 -7146 7297 -2068 3472 -3777 -184 -4631 -1305 -1109 -1104 -1720 -1288 -1797 -1717 276 -715 -672 -453 693 -1036 1478 -632 1966 95 803 -238 1443 -969 892 -694 680 102 1676 722 1322 276 456 -476 1139 527 685 722 168 325 40 517 -240 608 -622 4 -1055 -926 -1796 -998 -1511 -476 -162 220 -29 1026 817 1268 651 925 809 725 426 620 441 45 -344 -933 -4 -303 -595 -1083 -980 -1146 -252 -222 234 -176 252 -92 118 160 442 333 178 -432 -442 -535 -220 349 724 339 510 726 657 853 14 -79 -159 347 -291 -168 -78 35 -112 163 -407 -100 36 -430 156 -600 129 -638 215 -379 257 -445 83 -440 147 -76 177 -20 7 -18 -77 63 -94 237 -381 184 -304 271 -333 156 -412 32 -463 475 -167 293 -338 -15 -420 -130 -133 -158 -283 -227 -336 -334 54 -143 -136 -93 143 -223 332 -160 526 28 247 -77 470 -326 291 -226 223 36 647 312 605 125 195 -204 504 264 385 429 102 191 22 258 -110 267 -288 2 -643 -637 -1361 -794 -1273 -424 -152 214 -28 984 742 1066 515 713 662 664 441 717 556 58 -425 -1072 -4 -316 -664 -1287 -1215 -1496 -346 -330 374 -295 420 -148 179 230 628 490 275 -711 -738 -881 -352 540 1075 489 704 999 978 1382 24 -145 -301 678 -601 -363 -172 79 -255 363 -879 -207 73 SS 20200214T141237.1Z 7349.592096 233 1 50.18 2 75.76 109.65 50.59 237.51 0.00 1 0.00 1 0 25 3.533e-02 5.036e-03 2.154e-02 1.292e-03 4.268964e-01 6.573744e-04 4.482627e-03 -6.000000e+00 1.992133e-02 223.94 -2.00 3.11 -2.00 319.92 0.00e+00 3.734729e-03 2.046647e-04 6.678082e-04 -6.000000e+00 8.815028e-04 279.52 -2.00 20.00 -2.00 319.31 0.00e+00 3.982 0.000 302.00 328.00 3 2.0947e+00 1.8982e-03 3.6380e-02 -6.0000e+00 4.9127e-02 -2.5389e-02 2.2783e-03 2.1335e-02 -6.0000e+00 5.3472e-02 5.4168e-03 1.9318e-03 1.0091e-02 -6.0000e+00 3.1871e-02 -1.2847e-02 1.0065e-03 5.2069e-03 -6.0000e+00 1.3736e-02 1.8920e-03 -5.4460e-04 3.7871e-05 4.2096e-05 -6.0000e+00 9.5460e-04 7.6196e-03 -6.2009e-05 10 0 0 10 0 0 0.38 18.25 0.19 0.00762 0.00353 222 44 1 5 0 226.003 20.96 15.00 18.25 -10359 -9651 -4221 -7285 -7100 -21992 9865 -10454 -3173 -16604 4878 -11549 4289 -6175 1278 -5246 1739 -3060 1089 562 218 -17 2044 -1054 227 -2075 -3891 960 -3505 464 756 1792 -2473 -376 -3887 -198 -2756 1099 -2238 -579 -2241 -898 -1849 248 -1323 -889 -941 -703 -559 455 392 1403 619 446 1339 300 626 -311 669 -77 1214 1023 1718 796 895 -468 386 701 1219 118 580 -128 768 -209 304 -205 37 2 -262 -502 -1214 -1596 -1381 -1019 -942 -153 -142 292 507 1129 638 952 810 1263 473 731 439 546 -212 -394 -758 98 10 -656 -844 -1083 -1054 -174 -98 -159 -41 54 43 -32 515 139 380 -134 -257 -591 -250 -323 437 659 405 386 925 764 775 -35 -39 -28 393 -86 -190 22 -121 -125 40 -241 -341 62 -185 -175 -79 -129 -116 -426 153 -224 -69 -397 105 -314 122 -239 55 -269 90 -178 64 35 14 -1 133 -76 17 -163 -307 69 -263 37 68 181 -267 -39 -428 -22 -336 155 -393 -114 -485 -202 -434 58 -318 -215 -229 -172 -140 120 113 436 208 159 486 113 237 -117 244 -29 482 451 835 414 450 -225 180 341 668 74 382 -86 495 -127 167 -102 17 1 -148 -327 -902 -1307 -1192 -932 -867 -148 -143 296 502 1110 581 801 660 1084 460 753 514 701 -279 -493 -871 108 11 -732 -1010 -1360 -1400 -244 -150 -263 -67 87 71 -49 733 196 552 -208 -426 -1006 -417 -524 679 975 576 523 1243 1114 1247 -61 -68 -49 729 -171 -400 49 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