File name: Pandora142s1_MexicoCity-UNAM_20200220_L2Fit_fout2c15d20190823p1-8.txt File generation date: 20251127T103207.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Michel de Grutter Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 142 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora142_of_v2d20171226.txt Instrument calibration file used: Pandora142s1_CF_v15d20190823.txt Level 1 file used: Pandora142s1_MexicoCity-UNAM_20200220_L1_smca1c15d20190823p1-8.txt Full location name: Centro de Ciencias de la Atmosfera, UNAM Short location name: MexicoCity-UNAM Country of location: Mexico Location latitude [deg]: 19.3262 Location longitude [deg]: -99.1761 Location altitude [m]: 2280 Local noon date: 20200220 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 237 378 Nominal wavelengths inside fitting window [nm]: 305.1232 305.2643 305.4054 305.5465 305.6875 305.8286 305.9696 306.1107 306.2517 306.3927 306.5337 306.6747 306.8157 306.9567 307.0976 307.2386 307.3795 307.5205 307.6614 307.8023 307.9432 308.0841 308.2249 308.3658 308.5067 308.6475 308.7883 308.9292 309.0700 309.2108 309.3516 309.4923 309.6331 309.7738 309.9146 310.0553 310.1960 310.3368 310.4775 310.6181 310.7588 310.8995 311.0402 311.1808 311.3214 311.4621 311.6027 311.7433 311.8839 312.0244 312.1650 312.3056 312.4461 312.5866 312.7272 312.8677 313.0082 313.1487 313.2891 313.4296 313.5701 313.7105 313.8509 313.9914 314.1318 314.2722 314.4126 314.5529 314.6933 314.8337 314.9740 315.1143 315.2547 315.3950 315.5353 315.6755 315.8158 315.9561 316.0963 316.2366 316.3768 316.5170 316.6572 316.7974 316.9376 317.0778 317.2179 317.3581 317.4982 317.6383 317.7785 317.9186 318.0587 318.1987 318.3388 318.4789 318.6189 318.7589 318.8990 319.0390 319.1790 319.3189 319.4589 319.5989 319.7388 319.8788 320.0187 320.1586 320.2985 320.4384 320.5783 320.7182 320.8580 320.9979 321.1377 321.2775 321.4173 321.5571 321.6969 321.8367 321.9765 322.1162 322.2560 322.3957 322.5354 322.6751 322.8148 322.9545 323.0941 323.2338 323.3734 323.5131 323.6527 323.7923 323.9319 324.0715 324.2111 324.3506 324.4902 324.6297 324.7693 324.9088 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-238: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 239-380: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200220T134243.0Z 7355.571331 400 1 49.95 2 81.59 104.83 59.94 132.95 0.00 1 0.00 1 0 17 3.945e-01 1.932e-02 2.096e-01 5.627e-03 6.238947e-01 3.049395e-03 6.811974e-03 -6.000000e+00 2.257204e-01 224.37 -2.00 3.11 -2.00 321.37 0.00e+00 7.365202e-03 1.499308e-03 3.740884e-03 -6.000000e+00 1.060852e-02 279.64 -2.00 20.00 -2.00 320.86 0.00e+00 6.451 0.001 302.00 328.00 3 2.3982e+00 1.0449e-02 5.8356e-02 -6.0000e+00 5.5873e-01 2.7546e-02 1.4594e-02 3.3520e-02 -6.0000e+00 6.0920e-01 -1.2615e-01 1.5224e-02 2.2797e-02 -6.0000e+00 3.5909e-01 5.8838e-02 7.2359e-03 1.0410e-02 -6.0000e+00 1.5415e-01 1.8860e-04 -5.6899e-04 1.6582e-04 1.4715e-04 -6.0000e+00 1.1039e-02 9.2845e-03 -9.3577e-05 12 8 8 10 0 0 19.59 18.31 0.13 0.00928 0.00501 55 11 1 5 0 907.854 21.06 15.00 18.31 -153873 -10909 -155866 900000 -172859 900000 -129080 900000 -152503 900000 -154696 -37983 -142754 23569 -74963 67422 -53885 104810 -37238 12574 -22224 42313 -18961 52223 539 -29811 -9043 789 5163 -13425 36273 -10331 25430 -14378 30179 -11444 32579 -1134 21228 -6873 20026 -3127 20290 -1184 23537 3684 18799 670 14203 5901 8694 8534 2766 5034 7506 6184 475 5333 -259 6022 -692 8787 1173 3075 -1237 3005 -3424 3204 -2496 2299 -1775 1511 -1176 3152 -1711 2867 -2775 -361 -1415 862 -1168 -2820 -2255 -2304 -1642 -907 1381 -584 1031 -908 1348 -1427 1222 -274 787 -507 927 -391 -177 -2065 -850 -1077 100 -743 86 -399 374 845 760 672 380 512 -530 -432 -569 512 326 860 -244 439 -176 1132 1140 2163 618 1702 -11687 2766 1331 930 179 565 331 -197 -418 9 -316 -200 178 -344 214 335 -1876 -60 -2218 900000 -2541 900000 -1434 900000 -2476 900000 -2838 -307 -3639 179 -1632 488 -1241 661 -860 196 -470 520 -418 656 11 -824 -209 17 109 -382 799 -396 793 -633 868 -495 1090 -60 1103 -522 1290 -264 1452 -105 1723 333 1528 67 1322 647 1037 1121 416 792 1198 1032 84 885 -45 999 -132 1738 284 795 -331 757 -927 870 -820 809 -692 575 -442 1053 -542 801 -807 -111 -517 363 -573 -1568 -1323 -1440 -1090 -632 978 -427 727 -615 834 -864 721 -179 587 -441 915 -432 -200 -2277 -847 -978 88 -699 86 -419 417 1015 1012 992 601 820 -833 -646 -811 720 477 1322 -398 716 -281 1724 1694 3063 857 2255 -17853 4095 2237 1717 354 1162 718 -457 -1019 23 -802 -510 441 -811 478 720 SS 20200220T135635.0Z 7355.580961 405 1 50.06 2 78.44 106.13 57.65 135.42 0.00 1 0.00 1 0 25 6.336e-02 4.920e-03 5.368e-02 1.765e-03 5.092225e-01 9.160041e-04 5.308100e-03 -6.000000e+00 3.577552e-02 224.37 -2.00 3.11 -2.00 320.47 0.00e+00 2.884784e-03 3.441201e-04 1.141850e-03 -6.000000e+00 1.581727e-03 279.64 -2.00 20.00 -2.00 319.89 0.00e+00 4.834 0.000 302.00 328.00 3 1.8390e+00 2.7843e-03 4.4231e-02 -6.0000e+00 8.8303e-02 -2.6882e-03 3.5111e-03 2.6020e-02 -6.0000e+00 9.6091e-02 1.0407e-02 3.3193e-03 1.2146e-02 -6.0000e+00 5.7259e-02 -1.6206e-02 1.6795e-03 5.1892e-03 -6.0000e+00 2.4653e-02 1.1740e-03 -7.5204e-04 5.1337e-05 4.6387e-05 -6.0000e+00 1.7121e-03 9.0119e-03 -7.1394e-05 10 0 0 10 0 0 33.72 18.30 0.16 0.00901 0.00336 178 35 1 5 0 281.171 20.96 15.00 18.30 -11853 -25352 -12980 -12668 -10878 -22137 -32859 -6612 -21840 -31941 -7140 -22830 6677 -9063 -1141 -3655 6069 -9610 2587 -2285 1340 -3180 781 -3265 -1185 -4444 2662 -5669 4234 5120 1422 1777 -969 -47 -2775 152 -1773 -865 -2488 -1309 -3200 -863 -2577 -1053 -2206 375 -1594 -367 -986 1522 780 1173 -148 507 1307 665 -75 355 -427 725 758 1220 1366 849 1400 -551 809 892 1009 476 607 -169 511 -44 63 -207 -253 -851 -71 -824 -888 -1514 -1641 -1270 -486 -176 91 155 614 1463 916 972 881 958 481 611 331 478 -139 -323 -778 282 -136 -866 -965 -917 -1025 -287 11 2 135 197 168 55 566 224 239 -237 -446 -730 -439 -281 275 598 341 347 962 614 843 22 39 -76 253 -225 -131 -60 -122 -23 144 -322 -350 249 -99 -269 -125 -113 -89 -210 -386 -68 -291 -457 -91 -372 102 -202 -28 -99 163 -330 84 -81 46 -117 30 -139 -53 -213 117 -261 179 239 81 116 -72 -3 -200 11 -154 -84 -300 -180 -486 -135 -427 -175 -377 64 -279 -65 -182 296 170 278 -39 140 371 196 -22 104 -124 211 237 424 532 356 572 -219 315 367 472 253 342 -97 281 -23 29 -87 -103 -367 -35 -479 -589 -1116 -1284 -1053 -429 -164 82 142 582 1289 750 744 662 770 440 640 371 590 -177 -389 -859 298 -142 -978 -1092 -1088 -1292 -384 16 3 230 337 275 85 813 318 352 -372 -743 -1240 -725 -448 421 873 480 467 1290 905 1380 39 74 -151 492 -470 -288 -135 -283 -54 327 -696 -718 520 SS 20200220T140250.0Z 7355.585302 408 1 50.10 2 77.02 106.73 56.65 136.60 0.00 1 0.00 1 0 25 3.846e-02 5.052e-03 2.443e-02 1.197e-03 4.614289e-01 6.113737e-04 4.839186e-03 -6.000000e+00 2.172031e-02 224.37 -2.00 3.11 -2.00 320.08 0.00e+00 2.648765e-03 2.021446e-04 8.490539e-04 -6.000000e+00 9.601939e-04 279.64 -2.00 20.00 -2.00 319.48 0.00e+00 4.343 0.000 302.00 328.00 3 1.6183e+00 1.7872e-03 3.9582e-02 -6.0000e+00 5.3612e-02 3.6151e-04 2.1782e-03 2.2841e-02 -6.0000e+00 5.8337e-02 3.1430e-03 1.9267e-03 1.0815e-02 -6.0000e+00 3.4762e-02 -1.1441e-02 9.9748e-04 4.5095e-03 -6.0000e+00 1.4968e-02 2.2130e-03 -6.7781e-04 3.4861e-05 4.0232e-05 -6.0000e+00 1.0394e-03 8.8069e-03 -5.2397e-05 10 0 0 10 0 0 56.11 18.30 0.13 0.00881 0.00371 266 52 1 5 0 188.288 20.96 15.00 18.30 -2799 -15903 -10409 -14353 -17818 -8468 -16152 -7242 -10513 -10997 -15527 -1461 -10604 -110 -3297 -2542 -726 1740 -2302 961 -1730 1216 -1944 1013 -845 -1183 -1598 -2063 -445 1124 3013 1682 1286 -518 -2350 -2749 -1063 -1301 -1739 -2057 -1646 -1910 -1100 -1255 -532 -943 -453 -1065 -196 29 521 797 793 583 732 892 420 212 41 275 447 1560 1428 627 872 -110 141 1306 733 437 261 246 14 371 213 20 -343 178 -553 -401 -1134 -1501 -1440 -1283 -858 -265 170 230 793 1092 769 818 1149 896 760 472 417 305 134 -479 -764 -65 127 -870 -850 -1161 -934 -278 55 73 -3 111 39 138 457 341 254 -83 -518 -672 -555 -250 251 641 265 483 1279 788 548 162 -10 11 318 -149 -236 -26 -222 -55 194 -300 -313 96 -35 -245 -155 -207 -250 -112 -252 -117 -191 -209 -318 -30 -288 -3 -120 -102 -31 78 -114 48 -89 62 -108 59 -53 -77 -103 -128 -27 74 224 143 121 -49 -217 -267 -116 -171 -276 -373 -322 -393 -233 -270 -115 -208 -100 -241 -45 7 140 232 248 193 250 314 151 75 14 97 168 641 651 305 414 -50 64 607 387 259 164 156 9 214 113 9 -159 86 -305 -254 -810 -1175 -1188 -1118 -794 -257 169 234 785 1017 668 667 911 754 713 499 492 392 175 -601 -890 -69 135 -987 -1023 -1462 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