File name: Pandora142s1_MexicoCity-UNAM_20200421_L2Fit_fout2c15d20190823p1-8.txt File generation date: 20251127T105117.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Michel de Grutter Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 142 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora142_of_v3d20171226.txt Instrument calibration file used: Pandora142s1_CF_v15d20190823.txt Level 1 file used: Pandora142s1_MexicoCity-UNAM_20200421_L1_smca1c15d20190823p1-8.txt Full location name: Centro de Ciencias de la Atmosfera, UNAM Short location name: MexicoCity-UNAM Country of location: Mexico Location latitude [deg]: 19.3262 Location longitude [deg]: -99.1761 Location altitude [m]: 2280 Local noon date: 20200421 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 237 378 Nominal wavelengths inside fitting window [nm]: 305.1232 305.2643 305.4054 305.5465 305.6875 305.8286 305.9696 306.1107 306.2517 306.3927 306.5337 306.6747 306.8157 306.9567 307.0976 307.2386 307.3795 307.5205 307.6614 307.8023 307.9432 308.0841 308.2249 308.3658 308.5067 308.6475 308.7883 308.9292 309.0700 309.2108 309.3516 309.4923 309.6331 309.7738 309.9146 310.0553 310.1960 310.3368 310.4775 310.6181 310.7588 310.8995 311.0402 311.1808 311.3214 311.4621 311.6027 311.7433 311.8839 312.0244 312.1650 312.3056 312.4461 312.5866 312.7272 312.8677 313.0082 313.1487 313.2891 313.4296 313.5701 313.7105 313.8509 313.9914 314.1318 314.2722 314.4126 314.5529 314.6933 314.8337 314.9740 315.1143 315.2547 315.3950 315.5353 315.6755 315.8158 315.9561 316.0963 316.2366 316.3768 316.5170 316.6572 316.7974 316.9376 317.0778 317.2179 317.3581 317.4982 317.6383 317.7785 317.9186 318.0587 318.1987 318.3388 318.4789 318.6189 318.7589 318.8990 319.0390 319.1790 319.3189 319.4589 319.5989 319.7388 319.8788 320.0187 320.1586 320.2985 320.4384 320.5783 320.7182 320.8580 320.9979 321.1377 321.2775 321.4173 321.5571 321.6969 321.8367 321.9765 322.1162 322.2560 322.3957 322.5354 322.6751 322.8148 322.9545 323.0941 323.2338 323.3734 323.5131 323.6527 323.7923 323.9319 324.0715 324.2111 324.3506 324.4902 324.6297 324.7693 324.9088 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200421T130821.0Z 7416.547466 410 1 50.04 2 78.35 81.08 69.31 96.40 0.00 1 0.00 1 0 25 1.572e-01 5.092e-03 1.297e-01 3.143e-03 5.362224e-01 1.649328e-03 5.412573e-03 -6.000000e+00 9.018423e-02 228.31 -2.00 3.11 -2.00 320.70 0.00e+00 1.227811e-03 6.625579e-04 5.307743e-04 -6.000000e+00 3.947929e-03 281.06 -2.00 20.00 -2.00 320.12 0.00e+00 4.800 0.000 302.00 328.00 3 2.8092e+00 5.1578e-03 4.4494e-02 -6.0000e+00 2.2453e-01 -6.8204e-03 6.6430e-03 2.5733e-02 -6.0000e+00 2.4349e-01 -9.6450e-03 6.3757e-03 1.2940e-02 -6.0000e+00 1.4476e-01 -6.3635e-03 3.1766e-03 4.3048e-03 -6.0000e+00 6.1946e-02 4.4155e-04 -5.4832e-04 9.1744e-05 4.3761e-05 -6.0000e+00 4.2517e-03 2.9176e-03 -1.3103e-05 10 0 0 10 0 0 42.29 18.62 0.18 0.00292 -0.00120 74 15 1 5 0 676.127 21.27 15.00 18.62 25.89 46.6 782.36 -38276 -32923 -35511 -34060 -54375 -33893 -43763 102058 -65720 -4708 -63110 2155 -35289 -2812 -17370 -1821 -29136 13412 -12421 -2484 -8461 712 -16035 9402 -12107 9162 -4002 6209 -2874 1708 2348 -829 -584 -4129 1462 -4366 -1201 -3660 -247 -5238 105 -827 775 -2670 1004 -1821 1448 -695 -272 374 1679 1120 3391 578 1196 11 1405 441 -260 325 1450 2103 1132 1166 388 299 -549 2255 667 616 20 1071 -302 881 -447 13 -1328 60 -433 137 -1212 -1476 -1527 -958 -1190 -9 173 67 1045 944 1222 -303 855 450 540 264 706 60 147 -462 -577 27 -307 -1143 -504 -1318 -702 -371 215 -105 422 311 25 -345 320 55 508 143 -434 -331 -443 -18 375 709 133 638 -75 819 393 180 -263 -25 136 -155 -419 135 34 128 53 -84 -379 7 -323 -294 -336 -296 -542 -286 -458 313 -1023 -46 -1071 24 -666 -48 -414 -42 -912 322 -413 -78 -287 22 -600 321 -511 352 -161 233 -119 70 112 -47 -37 -271 87 -289 -89 -338 -27 -652 14 -114 109 -393 145 -274 214 -108 -44 64 318 234 753 141 304 3 375 117 -68 85 401 645 394 437 145 107 -197 829 284 297 10 557 -154 413 -192 5 -501 24 -197 72 -741 -1005 -1106 -734 -982 -8 156 61 920 781 933 -220 601 340 462 260 790 75 188 -565 -646 28 -304 -1220 -571 -1580 -888 -502 318 -160 684 508 39 -548 475 80 767 229 -697 -540 -706 -29 591 1063 192 880 -104 1234 664 313 -487 -49 274 -333 -963 317 81 309 126 -187 -806 15 SS 20200421T131434.3Z 7416.551786 413 1 50.60 2 76.90 81.54 67.88 96.95 0.00 1 0.00 1 0 25 7.776e-02 5.257e-03 5.288e-02 1.993e-03 4.838643e-01 1.036605e-03 4.972216e-03 -6.000000e+00 4.461284e-02 228.31 -2.00 3.11 -2.00 320.30 0.00e+00 1.668925e-03 3.650051e-04 5.392035e-04 -6.000000e+00 1.952890e-03 281.06 -2.00 20.00 -2.00 319.68 0.00e+00 4.304 0.000 302.00 328.00 3 2.4847e+00 3.1047e-03 4.0028e-02 -6.0000e+00 1.1107e-01 -2.0298e-02 3.8442e-03 2.3333e-02 -6.0000e+00 1.2045e-01 5.3824e-03 3.4822e-03 1.1485e-02 -6.0000e+00 7.1611e-02 -1.1035e-02 1.7767e-03 4.0738e-03 -6.0000e+00 3.0645e-02 9.3159e-04 -4.6131e-04 5.8490e-05 3.9883e-05 -6.0000e+00 2.1031e-03 2.7490e-03 -2.4919e-06 10 0 0 10 0 0 34.39 18.63 0.13 0.00275 -0.00072 123 24 1 5 0 408.001 21.27 15.01 18.63 26.56 46.5 782.55 38250 -29137 -1926 -34576 12395 -31381 -19838 -23584 -10682 3393 -21320 10090 -23637 1728 -15129 16469 -5855 10097 -11221 7208 -8547 7804 -6530 2906 -8934 6518 -5303 3331 -3198 4567 1987 5384 1476 618 -344 -579 -78 -1611 93 -2410 -613 -3477 -524 -926 362 -1884 659 -2855 1783 -1231 1843 -205 2027 -1126 1869 -340 672 -374 1057 -410 705 1056 1702 1282 602 -346 280 1252 354 754 206 469 -383 893 -443 288 -877 420 -1593 -267 -1378 -1366 -1702 -1102 -1044 24 -167 491 749 1261 885 1017 934 748 941 198 656 371 180 -813 -544 -192 273 -942 -530 -1222 -739 -422 358 -30 157 69 -83 -19 302 180 338 -7 -193 -524 -226 -181 476 622 30 576 -821 1021 494 277 -182 94 49 -88 -275 195 -164 121 64 -189 -410 178 264 -401 -21 -478 109 -403 -261 -359 -159 47 -377 155 -596 42 -504 466 -214 350 -499 287 -392 317 -319 140 -518 337 -305 167 -171 248 128 385 119 50 -27 -47 -7 -186 13 -385 -104 -643 -97 -175 68 -369 127 -579 356 -272 436 -54 565 -346 578 -111 221 -122 332 -132 241 399 714 577 267 -147 117 542 176 411 121 278 -222 489 -222 130 -381 188 -834 -160 -929 -1018 -1351 -924 -941 22 -161 476 725 1140 741 811 725 603 854 206 755 473 230 -1021 -623 -205 284 -1038 -623 -1514 -966 -573 528 -48 263 116 -133 -29 433 260 494 -11 -320 -870 -374 -290 734 935 43 792 -1141 1515 800 487 -334 178 98 -183 -604 430 -370 275 143 -409 -846 359 SS 20200421T132031.3Z 7416.555918 416 1 50.65 2 75.51 81.99 66.51 97.48 0.00 1 0.00 1 0 25 4.529e-02 5.082e-03 2.707e-02 1.405e-03 4.468057e-01 7.225960e-04 4.653584e-03 -6.000000e+00 2.598749e-02 228.31 -2.00 3.11 -2.00 319.93 0.00e+00 8.898767e-04 2.252824e-04 5.922595e-04 -6.000000e+00 1.137511e-03 281.06 -2.00 20.00 -2.00 319.29 0.00e+00 3.917 0.000 302.00 328.00 3 2.2488e+00 2.0943e-03 3.6574e-02 -6.0000e+00 6.4701e-02 -1.4921e-02 2.5221e-03 2.1393e-02 -6.0000e+00 7.0162e-02 2.9209e-03 2.1560e-03 1.0457e-02 -6.0000e+00 4.1713e-02 -9.5056e-03 1.1202e-03 3.2788e-03 -6.0000e+00 1.7853e-02 1.6347e-03 -4.6614e-04 4.1200e-05 3.4221e-05 -6.0000e+00 1.2250e-03 2.0983e-03 4.3867e-07 10 0 0 10 0 0 33.19 18.65 0.17 0.00210 -0.00140 177 35 1 5 0 282.899 21.27 14.99 18.65 27.21 46.6 782.67 14901 -9738 5789 -15918 18147 -21869 6641 -22865 1496 -14250 13971 -11927 -3632 -4448 425 -2074 -347 -1964 -545 -2245 -4459 -2835 -1258 231 -4324 -417 -2350 664 -5209 2471 -1521 3548 -1983 2258 -4889 -2212 -2788 726 -1954 -745 -2389 -423 -2058 -15 -563 -188 -681 -490 -611 -300 932 535 906 505 875 472 338 -104 734 -395 1664 615 1756 550 1232 -525 243 583 954 151 613 -63 561 456 416 -169 31 19 -551 -436 -1160 -1347 -1364 -1051 -831 19 -202 331 397 1138 513 939 708 984 215 638 420 430 102 -522 -689 14 -22 -636 -687 -1171 -1002 -389 57 -93 134 67 55 -112 504 50 489 -59 -217 -712 -402 -347 287 642 404 363 1454 725 663 56 -86 -88 275 -57 -263 58 -186 48 55 -95 -452 -47 185 -159 88 -260 210 -387 99 -489 28 -325 267 -314 -107 -160 17 -91 -16 -100 -29 -127 -260 -165 -77 15 -314 -30 -171 44 -364 173 -127 319 -208 225 -498 -229 -334 102 -341 -148 -523 -95 -487 -4 -134 -45 -164 -119 -152 -79 267 167 303 181 324 181 131 -40 273 -150 661 273 856 288 625 -255 115 287 530 90 388 -41 350 283 234 -86 15 10 -315 -288 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