File name: Pandora142s1_MexicoCity-UNAM_20200501_L2Fit_fout2c15d20190823p1-8.txt File generation date: 20251127T105206.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Michel de Grutter Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 142 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora142_of_v3d20171226.txt Instrument calibration file used: Pandora142s1_CF_v15d20190823.txt Level 1 file used: Pandora142s1_MexicoCity-UNAM_20200501_L1_smca1c15d20190823p1-8.txt Full location name: Centro de Ciencias de la Atmosfera, UNAM Short location name: MexicoCity-UNAM Country of location: Mexico Location latitude [deg]: 19.3262 Location longitude [deg]: -99.1761 Location altitude [m]: 2280 Local noon date: 20200501 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 237 378 Nominal wavelengths inside fitting window [nm]: 305.1232 305.2643 305.4054 305.5465 305.6875 305.8286 305.9696 306.1107 306.2517 306.3927 306.5337 306.6747 306.8157 306.9567 307.0976 307.2386 307.3795 307.5205 307.6614 307.8023 307.9432 308.0841 308.2249 308.3658 308.5067 308.6475 308.7883 308.9292 309.0700 309.2108 309.3516 309.4923 309.6331 309.7738 309.9146 310.0553 310.1960 310.3368 310.4775 310.6181 310.7588 310.8995 311.0402 311.1808 311.3214 311.4621 311.6027 311.7433 311.8839 312.0244 312.1650 312.3056 312.4461 312.5866 312.7272 312.8677 313.0082 313.1487 313.2891 313.4296 313.5701 313.7105 313.8509 313.9914 314.1318 314.2722 314.4126 314.5529 314.6933 314.8337 314.9740 315.1143 315.2547 315.3950 315.5353 315.6755 315.8158 315.9561 316.0963 316.2366 316.3768 316.5170 316.6572 316.7974 316.9376 317.0778 317.2179 317.3581 317.4982 317.6383 317.7785 317.9186 318.0587 318.1987 318.3388 318.4789 318.6189 318.7589 318.8990 319.0390 319.1790 319.3189 319.4589 319.5989 319.7388 319.8788 320.0187 320.1586 320.2985 320.4384 320.5783 320.7182 320.8580 320.9979 321.1377 321.2775 321.4173 321.5571 321.6969 321.8367 321.9765 322.1162 322.2560 322.3957 322.5354 322.6751 322.8148 322.9545 323.0941 323.2338 323.3734 323.5131 323.6527 323.7923 323.9319 324.0715 324.2111 324.3506 324.4902 324.6297 324.7693 324.9088 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200501T124631.3Z 7426.532307 374 1 50.60 2 82.07 76.48 141.14 342.64 0.00 1 0.00 1 0 25 5.884e-01 9.558e-03 2.807e-01 5.031e-03 8.035880e-01 2.861443e-03 7.866708e-03 -6.000000e+00 3.408723e-01 228.48 -2.00 3.11 -2.00 321.82 0.00e+00 6.515433e-03 1.596831e-03 1.292725e-03 -6.000000e+00 1.605701e-02 281.38 -2.00 20.00 -2.00 321.34 0.00e+00 6.789 0.001 302.00 328.00 3 1.5354e+00 1.0711e-02 6.6139e-02 -6.0000e+00 8.5190e-01 1.3833e-01 1.6447e-02 4.4815e-02 -6.0000e+00 9.2680e-01 -1.7747e-01 1.8062e-02 2.2509e-02 -6.0000e+00 5.5040e-01 6.3619e-02 8.2295e-03 1.0977e-02 -6.0000e+00 2.3576e-01 2.6899e-04 -1.2060e-03 1.4011e-04 1.1360e-04 -6.0000e+00 1.6071e-02 1.0307e-02 -7.1912e-05 12 9 8 11 8 0 1.82 18.22 0.14 0.01031 0.00124 104 20 1 5 0 481.773 20.96 15.00 18.22 19.01 45.7 778.01 900000 -242477 -19348 -204158 -187966 -180622 -241280 -80961 -214528 900000 -217527 900000 -187060 -48033 -128547 900000 -132188 900000 -124872 209 -62472 29444 -88260 40095 -66895 -9019 -82417 11726 -41049 13966 -26509 19172 20894 -26270 16761 -16507 13111 -6936 21397 -11779 25400 -2732 33042 -15913 31745 -6642 28050 -4361 13824 7298 15536 1890 11310 5506 10589 5274 4699 2834 191 8646 6031 7201 2709 6384 2293 6240 776 7240 776 7783 -1267 3597 749 4478 -2531 2775 -6792 848 -1834 282 -1753 -1516 -2243 -948 -1816 558 242 511 832 436 745 -331 1342 -1966 438 -876 817 -541 493 -1042 -117 -1231 657 -1898 -1085 -1987 -1228 -523 -67 329 228 51 318 3 109 93 189 424 -320 149 -226 519 347 1164 -447 963 -82 847 232 461 2 -48 -316 -75 -376 181 -60 201 104 -196 -321 -87 900000 -2100 -95 -1242 -954 -885 -2247 -397 -1994 900000 -2417 900000 -2632 -262 -1768 900000 -2551 900000 -2735 2 -827 176 -1619 255 -1153 -98 -1746 107 -637 158 -536 310 382 -732 312 -425 301 -224 639 -541 915 -136 1248 -951 1290 -391 1302 -284 815 516 1159 177 1064 580 1116 609 552 331 22 962 729 990 443 1121 428 1115 152 1446 191 2028 -376 1047 213 1123 -608 581 -1570 202 -541 98 -708 -689 -1102 -489 -1009 319 144 305 482 239 380 -169 686 -1134 290 -694 744 -548 512 -1074 -108 -1017 511 -1603 -968 -1881 -1240 -577 -82 453 344 80 487 5 153 131 274 649 -515 236 -344 767 497 1588 -599 1228 -108 1260 392 872 4 -105 -724 -183 -980 479 -161 542 271 -476 -745 -192 SS 20200501T130213.3Z 7426.543210 379 1 50.66 2 78.46 77.64 142.06 348.14 0.00 1 0.00 1 0 25 1.650e-01 4.522e-03 6.519e-02 1.336e-03 6.081629e-01 7.114743e-04 6.159141e-03 -6.000000e+00 9.459278e-02 228.48 -2.00 3.11 -2.00 320.86 0.00e+00 2.184347e-03 3.031902e-04 1.390449e-03 -6.000000e+00 4.148972e-03 281.38 -2.00 20.00 -2.00 320.29 0.00e+00 4.842 0.000 302.00 328.00 3 1.0831e+00 2.2720e-03 4.7611e-02 -6.0000e+00 2.3556e-01 2.5336e-02 3.0170e-03 3.1382e-02 -6.0000e+00 2.5551e-01 -1.4347e-02 3.0323e-03 1.4888e-02 -6.0000e+00 1.5192e-01 -6.8736e-03 1.4878e-03 5.8115e-03 -6.0000e+00 6.4924e-02 2.1443e-03 -7.4827e-04 3.7787e-05 5.2790e-05 -6.0000e+00 4.4629e-03 1.0094e-02 -6.1754e-05 11 1 0 11 8 0 13.87 18.21 0.18 0.01009 0.00447 361 71 1 5 0 138.757 20.96 15.00 18.21 20.50 46.0 783.46 -45238 -45994 12821 -93427 -34482 -83367 -44350 -73970 -28336 -43702 -24861 -53150 -9194 -25745 2479 -16640 -5407 -9588 -8332 -136 -4661 -3033 -9590 1187 -9463 7255 -13567 891 -10785 1045 -3627 3027 -4187 1813 -5206 -559 -4503 -1590 -4020 -448 -2292 -784 -583 994 -1989 -239 120 -1228 41 -47 1555 1080 1558 704 1186 725 1079 -725 1011 317 1641 1123 1853 669 1114 -380 337 681 959 798 548 340 305 -103 -243 -373 -723 -145 -730 -361 -1335 -1412 -1719 -1046 -954 -118 -169 535 723 1476 683 994 697 779 329 419 318 693 213 -206 -633 76 -222 -709 -635 -1141 -902 -398 0 -17 125 111 -38 -91 433 120 421 -171 -175 -500 -380 -253 429 609 242 400 700 580 439 -24 -168 -70 244 -143 -264 61 -137 116 120 -270 -203 113 -244 -280 47 -851 -176 -690 -290 -717 -204 -382 -197 -643 -94 -378 34 -311 -101 -203 -187 -3 -107 -70 -254 31 -290 200 -448 25 -347 34 -146 133 -219 90 -265 -29 -276 -115 -359 -45 -253 -90 -70 119 -250 -30 16 -167 6 -7 263 203 317 155 271 173 260 -175 234 75 410 316 585 231 380 -127 113 243 390 365 267 168 145 -46 -98 -138 -262 -56 -328 -188 -802 -941 -1218 -780 -756 -98 -145 460 609 1160 505 697 487 588 283 411 353 840 264 -247 -698 76 -217 -741 -705 -1325 -1108 -522 0 -26 207 185 -62 -140 636 175 634 -271 -291 -839 -621 -401 655 893 345 547 965 877 735 -44 -325 -141 509 -316 -610 145 -330 280 282 -607 -435 234 SS 20200501T130833.3Z 7426.547608 382 1 50.60 2 77.00 78.09 142.34 350.42 0.00 1 0.00 1 0 25 1.009e-01 4.603e-03 3.387e-02 9.327e-04 5.503684e-01 4.896828e-04 5.621838e-03 -6.000000e+00 5.785866e-02 228.48 -2.00 3.11 -2.00 320.49 0.00e+00 1.637161e-03 1.856232e-04 8.965996e-04 -6.000000e+00 2.537691e-03 281.38 -2.00 20.00 -2.00 319.89 0.00e+00 4.335 0.000 302.00 328.00 3 9.5042e-01 1.4966e-03 4.2339e-02 -6.0000e+00 1.4409e-01 1.6469e-02 1.9004e-03 2.7034e-02 -6.0000e+00 1.5629e-01 -7.9397e-03 1.8029e-03 1.3133e-02 -6.0000e+00 9.2923e-02 -8.6317e-03 9.0731e-04 4.6610e-03 -6.0000e+00 3.9712e-02 3.7918e-03 -6.0646e-04 2.6649e-05 4.4926e-05 -6.0000e+00 2.7297e-03 9.9979e-03 -6.0000e-05 10 0 0 10 0 0 1.43 18.21 0.17 0.01000 0.00544 493 97 1 5 0 101.588 20.96 15.00 18.21 21.02 45.9 785.36 -4159 -46035 -1268 -47841 -2698 -57891 21966 -46137 8642 -37664 7950 -32288 676 -15908 1838 -11796 4447 -5919 882 -3816 -2430 -1752 -1480 -1679 -2386 -1242 -3647 -881 -9048 1707 -2398 3630 -2912 2141 -6493 -804 -4788 -283 -3397 -381 -2568 -1405 -2097 638 -1547 536 -794 -259 -409 458 405 929 1077 926 1301 665 623 -645 662 -390 1628 972 2060 662 1126 -327 410 413 1044 414 469 63 400 8 405 -344 -38 -382 -397 -498 -1173 -1238 -1443 -1186 -828 -190 -161 384 591 1093 718 1034 606 920 299 693 321 547 118 -338 -640 111 -111 -769 -772 -1000 -939 -203 66 -89 -19 42 138 -72 439 73 454 -101 -205 -599 -328 -311 495 651 294 333 763 598 594 -79 -110 -170 227 -181 -174 51 -95 107 144 -291 -324 112 -27 -476 -9 -485 -17 -634 133 -576 74 -507 76 -513 10 -329 39 -316 112 -178 27 -125 -80 -58 -53 -65 -99 -53 -158 -36 -405 77 -131 215 -203 142 -449 -56 -394 -27 -404 -51 -378 -215 -335 101 -254 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