File name: Pandora142s1_MexicoCity-UNAM_20200514_L2Fit_fout2c15d20190823p1-8.txt File generation date: 20251127T111125.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Michel de Grutter Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 142 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora142_of_v3d20171226.txt Instrument calibration file used: Pandora142s1_CF_v15d20190823.txt Level 1 file used: Pandora142s1_MexicoCity-UNAM_20200514_L1_smca1c15d20190823p1-8.txt Full location name: Centro de Ciencias de la Atmosfera, UNAM Short location name: MexicoCity-UNAM Country of location: Mexico Location latitude [deg]: 19.3262 Location longitude [deg]: -99.1761 Location altitude [m]: 2280 Local noon date: 20200514 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 237 378 Nominal wavelengths inside fitting window [nm]: 305.1232 305.2643 305.4054 305.5465 305.6875 305.8286 305.9696 306.1107 306.2517 306.3927 306.5337 306.6747 306.8157 306.9567 307.0976 307.2386 307.3795 307.5205 307.6614 307.8023 307.9432 308.0841 308.2249 308.3658 308.5067 308.6475 308.7883 308.9292 309.0700 309.2108 309.3516 309.4923 309.6331 309.7738 309.9146 310.0553 310.1960 310.3368 310.4775 310.6181 310.7588 310.8995 311.0402 311.1808 311.3214 311.4621 311.6027 311.7433 311.8839 312.0244 312.1650 312.3056 312.4461 312.5866 312.7272 312.8677 313.0082 313.1487 313.2891 313.4296 313.5701 313.7105 313.8509 313.9914 314.1318 314.2722 314.4126 314.5529 314.6933 314.8337 314.9740 315.1143 315.2547 315.3950 315.5353 315.6755 315.8158 315.9561 316.0963 316.2366 316.3768 316.5170 316.6572 316.7974 316.9376 317.0778 317.2179 317.3581 317.4982 317.6383 317.7785 317.9186 318.0587 318.1987 318.3388 318.4789 318.6189 318.7589 318.8990 319.0390 319.1790 319.3189 319.4589 319.5989 319.7388 319.8788 320.0187 320.1586 320.2985 320.4384 320.5783 320.7182 320.8580 320.9979 321.1377 321.2775 321.4173 321.5571 321.6969 321.8367 321.9765 322.1162 322.2560 322.3957 322.5354 322.6751 322.8148 322.9545 323.0941 323.2338 323.3734 323.5131 323.6527 323.7923 323.9319 324.0715 324.2111 324.3506 324.4902 324.6297 324.7693 324.9088 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200514T130222.8Z 7439.543319 242 1 49.51 2 77.26 74.27 37.54 182.68 0.00 1 0.00 1 0 17 2.978e-01 8.356e-03 2.149e-01 7.369e-03 4.948052e-01 3.884678e-03 5.027603e-03 -6.000000e+00 1.709486e-01 228.70 -2.00 3.11 -2.00 320.55 0.00e+00 1.266653e-03 1.472437e-03 4.092101e-04 -6.000000e+00 7.594573e-03 281.80 -2.00 20.00 -2.00 319.93 0.00e+00 4.417 0.000 302.00 328.00 3 4.5578e+00 1.1987e-02 4.0894e-02 -6.0000e+00 4.2587e-01 -2.9025e-02 1.5044e-02 2.3314e-02 -6.0000e+00 4.6180e-01 -3.6295e-03 1.3732e-02 1.1984e-02 -6.0000e+00 2.7478e-01 -1.0541e-02 6.9051e-03 3.8766e-03 -6.0000e+00 1.1806e-01 1.0813e-04 -3.6267e-04 2.1949e-04 4.3215e-05 -6.0000e+00 8.0569e-03 9.3335e-03 -2.6143e-05 11 8 0 10 0 0 -53.43 18.31 0.24 0.00933 0.00661 18 4 1 5 0 2749.950 21.06 15.00 18.31 23.35 47.3 783.10 -38959 900000 -64614 229237 -75368 -18317 -72515 6332 40773 192917 -24885 9671 -30877 -45138 -32784 2688 -23680 9172 43611 -7394 16310 -30299 -14760 -2817 -10113 -4942 4982 -21155 -5906 1415 12326 -9279 5114 -11551 3075 -5549 9174 8703 8797 -4818 2315 -5993 2722 459 2255 -3428 -2341 -1031 -349 7904 -1592 3349 -310 1483 -1451 1837 1242 3558 -128 4295 1331 464 2333 3629 1987 527 1438 1231 2010 298 -527 1614 88 -1932 -2407 -2056 -540 -2133 636 -1890 -873 -3106 -1781 -2490 38 -265 768 231 837 219 592 288 1991 1607 -121 413 1000 927 -206 -1078 -451 1253 -140 -129 -1803 -1047 -1656 61 86 126 234 497 -523 144 -416 682 -340 270 -76 156 -330 578 767 767 -171 280 293 486 138 -636 -96 -343 395 -218 202 -104 269 -230 350 -915 411 -120 -441 900000 -1033 1647 -1178 -179 -1272 63 328 1386 -393 130 -719 -1437 -1106 74 -894 279 1031 -288 518 -1500 -682 -126 -515 -248 226 -1174 -286 70 638 -663 352 -927 206 -426 703 806 985 -700 342 -1008 437 76 373 -607 -414 -183 -64 1432 -350 765 -79 398 -417 529 364 1000 -37 1197 409 160 879 1439 783 200 540 489 899 152 -288 876 47 -984 -1117 -868 -217 -915 304 -1070 -553 -2222 -1326 -1988 32 -234 699 214 756 188 470 214 1430 1231 -106 408 1112 1129 -257 -1297 -498 1247 -139 -138 -2086 -1260 -2115 81 126 200 388 823 -843 217 -597 960 -499 419 -124 260 -540 914 1177 1129 -244 382 401 721 226 -1133 -180 -661 791 -464 451 -241 629 -546 807 -2044 870 -246 SS 20200514T130814.2Z 7439.547387 245 1 50.46 2 75.92 74.66 37.62 184.92 0.00 1 0.00 1 0 25 1.161e-01 7.537e-03 9.829e-02 4.681e-03 4.598854e-01 2.435276e-03 4.742011e-03 -6.000000e+00 6.662484e-02 228.70 -2.00 3.11 -2.00 320.28 0.00e+00 1.380223e-03 8.384595e-04 7.613336e-04 -6.000000e+00 2.923707e-03 281.80 -2.00 20.00 -2.00 319.64 0.00e+00 4.025 0.000 302.00 328.00 3 4.1172e+00 7.2961e-03 3.7773e-02 -6.0000e+00 1.6598e-01 -2.7990e-02 8.9363e-03 2.2569e-02 -6.0000e+00 1.7997e-01 -1.7203e-02 7.8027e-03 1.0797e-02 -6.0000e+00 1.0701e-01 -6.2997e-04 3.9875e-03 3.7595e-03 -6.0000e+00 4.5745e-02 2.3304e-04 -2.7216e-04 1.3919e-04 3.7039e-05 -6.0000e+00 3.1397e-03 8.6334e-03 -2.0011e-05 11 8 0 10 0 0 -3.85 18.31 0.24 0.00863 0.00659 33 6 1 5 0 1528.648 21.06 15.00 18.31 24.01 47.4 783.81 -14430 -43565 16337 -18040 -66120 3465 -9858 -531 -52518 9293 -52621 15159 -13375 25859 -21329 19412 -18606 25749 -16606 22549 -15919 19878 -11712 16802 -816 2190 -3453 11330 -2800 521 4733 -1963 4191 -5955 4665 -5577 6575 -4470 3067 -3308 1473 -6013 1769 -2635 4527 -5453 3162 -3784 944 -3717 2717 81 2322 661 1727 1014 -40 -826 -779 1516 179 3631 530 2239 -595 1738 -1826 3237 -171 1896 -301 1093 -234 2149 -513 907 -1446 2514 -1880 615 -2308 -973 -1744 -1419 -1363 787 -150 -478 74 1144 1283 288 865 196 1531 -417 1302 115 335 -773 215 -1032 -311 -1093 -180 -1475 133 -524 248 -92 -21 5 -179 46 38 67 3 -651 -544 -41 -355 219 185 1198 204 981 -150 1053 124 489 -284 392 8 238 -299 535 -326 166 110 -245 -634 -263 -194 -827 185 -259 -1365 40 -141 -8 -1366 145 -1480 265 -362 591 -871 610 -890 881 -884 873 -887 811 -680 808 -49 132 -216 592 -167 33 326 -162 358 -555 375 -521 625 -569 437 -573 263 -1211 343 -538 871 -1171 627 -815 199 -876 662 22 664 204 547 335 -14 -276 -256 493 63 1374 228 1005 -267 726 -779 1379 -85 1041 -179 650 -137 1155 -257 406 -636 1114 -989 364 -1584 -722 -1377 -1185 -1218 727 -145 -471 71 1025 1066 226 658 159 1375 -430 1484 144 427 -952 242 -1084 -321 -1219 -212 -1830 172 -723 367 -148 -35 8 -288 70 55 95 5 -1014 -895 -68 -585 349 287 1767 293 1337 -207 1553 201 850 -522 739 15 494 -654 1193 -747 381 248 -531 -1324 -532 SS 20200514T131428.2Z 7439.551716 248 1 50.47 2 74.50 75.08 37.75 187.29 0.00 1 0.00 1 0 17 1.096e-01 6.300e-03 5.694e-02 3.014e-03 4.265843e-01 1.554563e-03 4.446129e-03 -6.000000e+00 6.291383e-02 228.70 -2.00 3.11 -2.00 319.95 0.00e+00 8.942050e-04 4.823314e-04 6.549559e-04 -6.000000e+00 2.761162e-03 281.80 -2.00 20.00 -2.00 319.29 0.00e+00 3.678 0.000 302.00 328.00 3 3.7530e+00 4.5273e-03 3.4610e-02 -6.0000e+00 1.5673e-01 -3.5301e-02 5.4327e-03 2.0594e-02 -6.0000e+00 1.6995e-01 -3.2428e-03 4.5248e-03 9.9332e-03 -6.0000e+00 1.0106e-01 -6.1021e-03 2.3446e-03 3.1395e-03 -6.0000e+00 4.3195e-02 4.5034e-04 -4.3236e-04 8.9347e-05 3.2563e-05 -6.0000e+00 2.9651e-03 8.7110e-03 -4.0263e-05 10 0 0 10 0 0 -15.90 18.31 0.18 0.00871 0.00546 53 10 1 5 0 952.015 20.96 15.00 18.31 24.75 47.5 784.22 -36618 24574 -47054 40390 -33899 49936 -16136 56543 -32991 22936 -26023 3012 -11036 10341 -5562 4890 -3202 115 2900 4650 6555 -1729 7310 -377 4957 -6065 5603 -8034 5517 -4114 9043 -4227 6080 -4141 8316 -6969 2744 -3056 497 -4356 -390 -1983 -358 -450 6 630 -908 -1785 -948 1715 -1878 951 -251 2572 -462 2249 -1678 1511 -1919 1777 -1406 3192 1053 2132 -630 673 -1271 1656 19 851 477 338 -54 1263 634 -52 -163 -60 -382 -1051 -951 -1483 -946 -1845 -15 -619 411 -675 953 623 1181 63 1106 641 866 602 619 332 276 -607 -641 -89 -165 -182 -868 -792 -1102 -56 -330 154 -237 374 -138 330 -157 358 -199 109 -547 -219 -815 99 269 770 264 498 1016 824 752 -83 -214 -78 323 -259 57 -14 122 -60 311 -481 -314 -185 -818 347 -1270 467 -710 514 -329 687 -969 425 -771 77 -383 351 -254 225 -170 6 164 269 376 -109 451 -27 358 -502 408 -632 378 -333 730 -434 620 -459 783 -795 327 -464 88 -917 -85 -461 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