File name: Pandora142s1_MexicoCity-UNAM_20200517_L2Fit_fout2c15d20190823p1-8.txt File generation date: 20251127T111129.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Michel de Grutter Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 142 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora142_of_v3d20171226.txt Instrument calibration file used: Pandora142s1_CF_v15d20190823.txt Level 1 file used: Pandora142s1_MexicoCity-UNAM_20200517_L1_smca1c15d20190823p1-8.txt Full location name: Centro de Ciencias de la Atmosfera, UNAM Short location name: MexicoCity-UNAM Country of location: Mexico Location latitude [deg]: 19.3262 Location longitude [deg]: -99.1761 Location altitude [m]: 2280 Local noon date: 20200517 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 237 378 Nominal wavelengths inside fitting window [nm]: 305.1232 305.2643 305.4054 305.5465 305.6875 305.8286 305.9696 306.1107 306.2517 306.3927 306.5337 306.6747 306.8157 306.9567 307.0976 307.2386 307.3795 307.5205 307.6614 307.8023 307.9432 308.0841 308.2249 308.3658 308.5067 308.6475 308.7883 308.9292 309.0700 309.2108 309.3516 309.4923 309.6331 309.7738 309.9146 310.0553 310.1960 310.3368 310.4775 310.6181 310.7588 310.8995 311.0402 311.1808 311.3214 311.4621 311.6027 311.7433 311.8839 312.0244 312.1650 312.3056 312.4461 312.5866 312.7272 312.8677 313.0082 313.1487 313.2891 313.4296 313.5701 313.7105 313.8509 313.9914 314.1318 314.2722 314.4126 314.5529 314.6933 314.8337 314.9740 315.1143 315.2547 315.3950 315.5353 315.6755 315.8158 315.9561 316.0963 316.2366 316.3768 316.5170 316.6572 316.7974 316.9376 317.0778 317.2179 317.3581 317.4982 317.6383 317.7785 317.9186 318.0587 318.1987 318.3388 318.4789 318.6189 318.7589 318.8990 319.0390 319.1790 319.3189 319.4589 319.5989 319.7388 319.8788 320.0187 320.1586 320.2985 320.4384 320.5783 320.7182 320.8580 320.9979 321.1377 321.2775 321.4173 321.5571 321.6969 321.8367 321.9765 322.1162 322.2560 322.3957 322.5354 322.6751 322.8148 322.9545 323.0941 323.2338 323.3734 323.5131 323.6527 323.7923 323.9319 324.0715 324.2111 324.3506 324.4902 324.6297 324.7693 324.9088 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200517T125939.9Z 7442.541434 338 1 29.81 2 77.69 73.40 39.01 125.93 0.00 1 0.00 1 0 17 9.136e-02 4.856e-03 1.072e-01 3.130e-03 5.147136e-01 1.635815e-03 5.252802e-03 -6.000000e+00 5.242082e-02 228.61 -2.00 3.11 -2.00 320.39 0.00e+00 2.223964e-03 6.012102e-04 4.002077e-04 -6.000000e+00 2.302268e-03 281.90 -2.00 20.00 -2.00 319.78 0.00e+00 4.562 0.000 302.00 328.00 3 2.7708e+00 4.9589e-03 4.2449e-02 -6.0000e+00 1.3056e-01 -1.0438e-02 6.2224e-03 2.4698e-02 -6.0000e+00 1.4158e-01 9.3305e-03 5.7601e-03 1.2374e-02 -6.0000e+00 8.4196e-02 -1.4595e-02 2.9164e-03 4.7244e-03 -6.0000e+00 3.5998e-02 5.5423e-04 -5.2469e-04 9.0432e-05 4.4946e-05 -6.0000e+00 2.4713e-03 8.9664e-03 -3.2727e-05 12 1 1 12 9 1 99.71 18.36 0.07 0.00897 0.00502 48 16 1 5 0 604.703 21.06 15.00 18.36 23.20 47.3 781.04 45140 -14050 38590 -34960 24815 -1629 1922 -29601 -12104 -31911 -30983 -10543 10590 -11212 -18993 16271 -12216 7349 -12829 12843 -12179 3439 -3323 5915 -6235 14846 -10330 8885 -5832 14793 -5606 6686 -3016 8376 -4427 519 686 -3023 -1730 -2208 -1316 -4109 -1570 -3169 -215 -2609 1499 -2410 366 -7 855 -275 2446 849 2817 547 909 -439 826 542 1422 347 1453 1042 1213 935 -491 983 586 677 -329 601 -250 -1 -399 88 -1007 -317 -445 -306 -1278 -1262 -1617 -729 -881 312 -44 680 390 1219 448 601 -287 175 433 369 422 302 115 -550 -285 -615 328 -731 -538 -718 -831 -62 56 51 499 21 268 -219 426 281 565 -57 -219 -609 -438 -379 329 834 -79 260 592 798 271 -148 -343 -148 116 -252 -150 184 -129 201 149 -302 -83 21 248 -140 252 -400 163 -14 18 -395 -153 -499 -505 -166 170 -261 -560 397 -414 227 -502 419 -501 125 -138 244 -305 624 -539 377 -285 664 -350 424 -231 576 -329 39 59 -322 -220 -323 -207 -699 -270 -561 -38 -477 266 -456 70 -1 194 -69 644 242 817 168 281 -135 247 165 460 126 582 447 511 378 -200 418 283 365 -190 348 -142 0 -193 39 -433 -142 -229 -181 -863 -935 -1270 -600 -775 286 -42 650 367 1076 372 469 -221 144 396 381 487 381 148 -682 -326 -649 338 -810 -631 -881 -1073 -84 82 81 829 35 434 -337 620 406 838 -90 -362 -1019 -720 -606 510 1238 -114 361 822 1193 445 -261 -637 -284 231 -528 -329 410 -294 460 334 -652 -173 41 SS 20200517T130525.2Z 7442.545431 341 1 4.45 2 76.39 73.79 37.92 127.38 0.00 1 0.00 1 0 17 1.327e-01 8.826e-03 1.246e-01 6.512e-03 4.757249e-01 3.333084e-03 4.942449e-03 -6.000000e+00 7.616401e-02 228.61 -2.00 3.11 -2.00 319.50 0.00e+00 1.243916e-03 9.287984e-04 5.323208e-04 -6.000000e+00 3.344976e-03 281.90 -2.00 20.00 -2.00 318.84 0.00e+00 4.154 0.000 302.00 328.00 3 3.1055e+00 9.4335e-03 3.8763e-02 -6.0000e+00 1.8970e-01 1.4929e-02 1.1143e-02 2.2552e-02 -6.0000e+00 2.0571e-01 -2.8317e-02 9.0489e-03 1.0932e-02 -6.0000e+00 1.2233e-01 6.2101e-03 4.7647e-03 3.5376e-03 -6.0000e+00 5.2299e-02 5.5699e-04 -5.5552e-04 1.8265e-04 3.4509e-05 -6.0000e+00 3.5906e-03 1.0037e-02 5.2645e-06 12 9 1 12 1 1 -139.33 18.36 0.19 0.01004 0.00586 4 12 1 5 0 854.537 21.06 15.00 18.36 23.63 47.2 782.05 91406 -57872 16673 -53728 14248 -38454 42220 -6986 -22595 -1288 16246 31674 4350 20411 -2119 18417 -8367 16651 -12984 19803 -10131 17454 -11062 13102 -13690 6893 -17842 15519 -1802 8443 -5643 7213 -5534 2392 -3775 4198 -1561 -2315 -3361 -2249 1781 -1031 2684 -1271 -688 -1233 3519 -3406 5170 -1457 3933 -1320 1837 -181 2756 -807 2903 -1293 890 -845 3034 -111 2144 -983 -672 -1136 -775 436 1324 1428 239 611 -1302 2350 -1127 2454 -2389 459 -2290 825 -1107 -636 -1803 -687 -2665 -33 -616 591 243 1336 -231 -276 180 697 592 378 1332 157 181 64 389 -1103 1196 -771 719 -1623 -556 -922 281 398 229 382 217 -167 128 -347 390 -387 -166 -686 -285 -207 406 794 68 -40 1296 882 -137 -78 -331 419 -756 111 -666 372 48 775 -320 108 -638 35 683 -1777 268 -1502 206 -913 545 -157 -640 -31 353 684 144 701 -104 838 -524 893 -960 1131 -767 1047 -915 940 -1328 573 -1834 1124 -153 708 -615 787 -745 296 -474 514 -229 -409 -718 -540 442 -275 714 -353 -192 -350 960 -1003 1448 -461 1296 -492 710 -75 1156 -360 1264 -574 382 -372 1370 -56 1166 -579 -385 -626 -423 246 824 977 174 447 -944 1567 -714 1389 -1356 265 -1509 597 -899 -556 -1658 -656 -2725 -35 -668 639 261 1351 -223 -253 161 653 607 425 1633 208 242 83 472 -1267 1338 -922 893 -2119 -750 -1304 419 627 374 624 346 -255 187 -504 576 -598 -266 -1121 -459 -326 623 1178 99 -55 1804 1306 -219 -130 -577 745 -1394 212 -1323 749 98 1584 -647 211 -1217 66 SS 20200517T131156.3Z 7442.549957 344 1 50.56 2 74.91 74.22 36.72 129.12 0.00 1 0.00 1 0 25 2.464e-02 4.746e-03 1.654e-02 1.020e-03 4.339949e-01 5.210689e-04 4.496805e-03 -6.000000e+00 1.413897e-02 228.61 -2.00 3.11 -2.00 319.77 0.00e+00 2.140594e-03 1.561553e-04 5.746096e-04 -6.000000e+00 6.210724e-04 281.90 -2.00 20.00 -2.00 319.11 0.00e+00 3.771 0.000 302.00 328.00 3 1.8205e+00 1.4955e-03 3.5364e-02 -6.0000e+00 3.5215e-02 -8.9192e-03 1.7878e-03 2.1043e-02 -6.0000e+00 3.8189e-02 -5.1954e-03 1.4889e-03 1.0088e-02 -6.0000e+00 2.2710e-02 -6.1680e-03 7.7746e-04 3.8820e-03 -6.0000e+00 9.7086e-03 2.8236e-03 -5.4789e-04 2.9714e-05 3.5353e-05 -6.0000e+00 6.6667e-04 9.0958e-03 -6.3960e-05 10 0 0 10 0 0 98.10 18.35 0.18 0.00910 0.00498 257 50 1 5 0 195.161 21.06 15.00 18.35 24.24 47.3 782.65 -7769 -2319 -13616 -3284 -15012 1056 -10241 -1645 -3956 -2164 -7954 -2551 -3481 -980 -1300 -1196 -2093 892 -1004 -861 -3477 -1472 -1814 -1722 -627 -1742 -2560 -3425 477 -1095 1931 309 976 -1777 -1069 -2967 -800 -1641 -1095 -1560 -1517 -1552 -1054 -573 -471 -388 -1029 -650 -532 68 483 1125 510 403 691 1013 258 475 -56 503 690 1886 1363 997 231 -124 83 964 724 662 265 480 208 216 191 27 -240 -115 -460 -756 -991 -1298 -1347 -1284 -674 -390 -98 51 630 898 868 680 1143 814 607 475 507 428 18 -464 -673 16 161 -654 -615 -940 -862 -323 -209 -121 -126 14 -169 -16 316 375 271 68 -307 -480 -424 -242 381 794 212 639 904 790 615 58 -88 41 267 -123 -163 44 -124 -10 106 -352 -308 -98 -137 -42 -282 -56 -269 17 -200 -33 -91 -50 -203 -71 -119 -37 -58 -59 -112 50 -61 -54 -225 -94 -124 -126 -48 -140 -203 -260 35 -88 172 32 109 -201 -114 -339 -103 -257 -206 -337 -353 -379 -264 -144 -120 -100 -266 -169 -141 19 148 372 183 153 270 406 105 190 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