File name: Pandora142s1_MexicoCity-UNAM_20200525_L2Fit_fout2c15d20190823p1-8.txt File generation date: 20251127T111203.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Michel de Grutter Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 142 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora142_of_v3d20171226.txt Instrument calibration file used: Pandora142s1_CF_v15d20190823.txt Level 1 file used: Pandora142s1_MexicoCity-UNAM_20200525_L1_smca1c15d20190823p1-8.txt Full location name: Centro de Ciencias de la Atmosfera, UNAM Short location name: MexicoCity-UNAM Country of location: Mexico Location latitude [deg]: 19.3262 Location longitude [deg]: -99.1761 Location altitude [m]: 2280 Local noon date: 20200525 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 237 378 Nominal wavelengths inside fitting window [nm]: 305.1232 305.2643 305.4054 305.5465 305.6875 305.8286 305.9696 306.1107 306.2517 306.3927 306.5337 306.6747 306.8157 306.9567 307.0976 307.2386 307.3795 307.5205 307.6614 307.8023 307.9432 308.0841 308.2249 308.3658 308.5067 308.6475 308.7883 308.9292 309.0700 309.2108 309.3516 309.4923 309.6331 309.7738 309.9146 310.0553 310.1960 310.3368 310.4775 310.6181 310.7588 310.8995 311.0402 311.1808 311.3214 311.4621 311.6027 311.7433 311.8839 312.0244 312.1650 312.3056 312.4461 312.5866 312.7272 312.8677 313.0082 313.1487 313.2891 313.4296 313.5701 313.7105 313.8509 313.9914 314.1318 314.2722 314.4126 314.5529 314.6933 314.8337 314.9740 315.1143 315.2547 315.3950 315.5353 315.6755 315.8158 315.9561 316.0963 316.2366 316.3768 316.5170 316.6572 316.7974 316.9376 317.0778 317.2179 317.3581 317.4982 317.6383 317.7785 317.9186 318.0587 318.1987 318.3388 318.4789 318.6189 318.7589 318.8990 319.0390 319.1790 319.3189 319.4589 319.5989 319.7388 319.8788 320.0187 320.1586 320.2985 320.4384 320.5783 320.7182 320.8580 320.9979 321.1377 321.2775 321.4173 321.5571 321.6969 321.8367 321.9765 322.1162 322.2560 322.3957 322.5354 322.6751 322.8148 322.9545 323.0941 323.2338 323.3734 323.5131 323.6527 323.7923 323.9319 324.0715 324.2111 324.3506 324.4902 324.6297 324.7693 324.9088 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200525T125454.3Z 7450.538128 235 1 50.57 2 78.45 71.49 108.06 55.98 0.00 1 0.00 1 0 25 1.405e-01 4.600e-03 6.325e-02 1.533e-03 5.806462e-01 8.123731e-04 5.896330e-03 -6.000000e+00 8.065227e-02 228.32 -2.00 3.11 -2.00 320.80 0.00e+00 1.670916e-03 3.419793e-04 1.006579e-03 -6.000000e+00 3.544812e-03 282.15 -2.00 20.00 -2.00 320.22 0.00e+00 4.837 0.000 302.00 328.00 3 1.3549e+00 2.5702e-03 4.6351e-02 -6.0000e+00 2.0073e-01 -4.4736e-03 3.3820e-03 2.8956e-02 -6.0000e+00 2.1758e-01 -7.6435e-03 3.3304e-03 1.4202e-02 -6.0000e+00 1.2944e-01 -7.3520e-03 1.6434e-03 5.1658e-03 -6.0000e+00 5.5494e-02 1.7279e-03 -5.5491e-04 4.3843e-05 4.9716e-05 -6.0000e+00 3.7990e-03 -1.8188e-03 3.6636e-05 10 0 0 10 0 0 5.25 18.45 0.11 -0.00182 -0.00599 299 59 1 5 0 167.428 21.17 14.99 18.45 23.39 47.0 781.04 -14481 -45991 -5465 -63657 -64212 -50919 -50348 -29674 -49290 -24668 -44355 -28500 -41202 11479 -26050 97 -18496 -2179 -20176 3281 -13900 3551 -13050 10744 -4151 -311 -9412 5351 -13666 -4064 -1082 405 -3134 -1207 -5147 -5495 -3281 -3807 -10 -2222 -1280 -2953 1099 -2134 911 -1858 2414 -1062 1817 -921 2433 849 1642 176 1837 876 402 -240 318 -202 1171 1717 1964 1135 761 169 45 1248 543 925 109 631 133 573 -296 406 -677 396 -831 -168 -1227 -1130 -1428 -982 -745 -281 -315 313 647 1017 916 837 911 650 455 203 477 349 352 -505 -506 -26 -70 -1057 -573 -1225 -884 -349 79 -116 181 152 193 -56 326 187 382 -56 -250 -528 -395 -247 328 686 121 460 609 753 466 157 -177 -14 219 -197 -297 46 -152 55 129 -166 -324 138 -75 -338 -30 -547 -520 -374 -414 -229 -522 -218 -508 -330 -635 143 -536 2 -423 -50 -554 75 -383 84 -393 280 -135 -10 -338 159 -498 -151 -46 20 -169 -65 -275 -308 -207 -295 -1 -243 -152 -380 141 -288 121 -260 330 -155 270 -153 437 160 336 39 422 212 99 -59 75 -48 295 482 623 394 264 57 15 439 219 423 54 315 65 257 -121 149 -258 158 -364 -86 -729 -748 -1012 -736 -598 -238 -277 277 560 823 687 590 632 485 388 200 535 437 427 -628 -575 -27 -69 -1122 -648 -1462 -1117 -472 111 -180 300 255 314 -86 470 266 559 -87 -412 -886 -644 -387 495 1047 179 649 855 1160 762 282 -341 -29 463 -421 -674 108 -361 132 300 -367 -718 292 SS 20200525T130111.0Z 7450.542489 238 1 50.10 2 77.04 71.91 106.88 56.71 0.00 1 0.00 1 0 25 8.473e-02 4.648e-03 3.548e-02 1.102e-03 5.293815e-01 5.816770e-04 5.492417e-03 -6.000000e+00 4.865049e-02 228.32 -2.00 3.11 -2.00 320.43 0.00e+00 8.287378e-04 2.179451e-04 1.077610e-03 -6.000000e+00 2.138295e-03 282.15 -2.00 20.00 -2.00 319.83 0.00e+00 4.348 0.000 302.00 328.00 3 1.2570e+00 1.7799e-03 4.1912e-02 -6.0000e+00 1.2109e-01 -1.0353e-02 2.2464e-03 2.6302e-02 -6.0000e+00 1.3125e-01 1.7784e-03 2.0910e-03 1.2668e-02 -6.0000e+00 7.8080e-02 -1.1493e-02 1.0537e-03 4.1086e-03 -6.0000e+00 3.3474e-02 2.8865e-03 -4.9021e-04 3.1819e-05 4.3344e-05 -6.0000e+00 2.2917e-03 -1.7883e-03 3.2234e-05 10 0 0 10 0 0 10.35 18.45 0.19 -0.00179 -0.00547 392 77 1 5 0 127.771 21.17 15.00 18.45 24.42 46.8 781.89 -13361 -34680 -22916 -45078 5427 -46934 -3223 -36518 -48 -35438 -6782 -20580 112 -12634 4125 -9124 -705 1523 3096 -299 349 -3140 2053 -1704 -309 -2017 -4314 -2584 -4077 947 -2386 2405 -2526 -1542 -4737 -2098 -3295 -218 -3566 -1373 -2566 -1001 -833 433 -821 343 -104 -262 30 -133 437 1554 561 731 1114 439 110 -466 191 -221 1061 740 1693 601 526 -478 439 438 734 435 856 248 401 99 520 -5 206 -162 -154 -445 -1073 -1283 -1417 -1283 -852 -67 -69 197 525 1223 771 858 583 942 391 556 498 626 81 -216 -682 -40 -46 -750 -809 -1129 -977 -428 -17 -2 15 179 165 -61 340 142 336 -142 -365 -616 -391 -403 454 682 273 418 968 743 642 120 -112 -138 251 -157 -154 -39 -45 -12 143 -204 -362 80 -104 -345 -228 -480 36 -492 -27 -448 0 -514 -78 -315 2 -276 92 -247 -19 44 95 -10 12 -111 74 -70 -13 -93 -203 -114 -182 44 -135 150 -186 -113 -342 -154 -282 -22 -424 -186 -384 -156 -134 70 -136 57 -18 -45 5 -26 93 360 143 199 315 130 33 -139 55 -65 326 254 646 250 216 -190 171 179 341 230 482 143 223 52 243 -2 84 -69 -75 -255 -708 -942 -1109 -1065 -756 -62 -67 193 503 1093 639 665 442 757 358 581 553 771 103 -263 -763 -43 -48 -847 -913 -1339 -1227 -572 -24 -3 26 308 275 -95 496 204 496 -224 -611 -1051 -651 -648 700 1002 386 565 1295 1085 1049 215 -213 -256 487 -327 -340 -89 -105 -28 325 -442 -746 156 SS 20200525T130655.3Z 7450.546473 241 1 50.54 2 75.75 72.28 105.79 57.36 0.00 1 0.00 1 0 25 5.031e-02 4.833e-03 1.973e-02 8.611e-04 4.885484e-01 4.451396e-04 5.049918e-03 -6.000000e+00 2.888763e-02 228.32 -2.00 3.11 -2.00 320.13 0.00e+00 9.043628e-04 1.497937e-04 6.210906e-04 -6.000000e+00 1.269648e-03 282.15 -2.00 20.00 -2.00 319.49 0.00e+00 3.979 0.000 302.00 328.00 3 1.1656e+00 1.3115e-03 3.8158e-02 -6.0000e+00 7.1898e-02 -5.8100e-03 1.6095e-03 2.3378e-02 -6.0000e+00 7.7931e-02 -2.2506e-03 1.4339e-03 1.1503e-02 -6.0000e+00 4.6362e-02 -9.0415e-03 7.3839e-04 3.6579e-03 -6.0000e+00 1.9877e-02 4.3315e-03 -4.6456e-04 2.4910e-05 3.7709e-05 -6.0000e+00 1.3607e-03 -1.9705e-03 3.9325e-05 11 1 0 11 8 0 8.14 18.45 0.17 -0.00197 -0.00546 494 97 1 5 0 101.249 21.17 15.00 18.45 25.46 46.8 782.26 -15340 -19755 -9806 -21276 -10758 -21816 -452 -17910 5810 -26850 1916 -14821 2636 -9415 1877 -7203 1920 -4321 -938 -5651 -525 -3587 -108 -2429 -531 -2313 -3817 -1331 -2638 -1189 1254 2291 -1419 232 -3160 -1670 -3929 -208 -2388 -958 -2656 -653 -1853 137 -1682 223 -1096 -280 -854 612 196 1073 734 748 726 853 305 166 184 128 837 1131 1614 888 1278 -433 452 640 1125 382 635 25 630 109 552 -15 -143 -319 -425 -849 -1086 -1473 -1247 -1348 -807 -227 -225 274 553 1157 778 878 722 1046 434 602 323 597 -19 -316 -838 32 -29 -751 -766 -1011 -1078 -288 14 9 19 144 0 27 308 260 389 -59 -265 -612 -323 -421 440 623 418 315 853 735 679 92 -60 -95 346 -181 -159 3 -126 -51 38 -268 -270 56 -185 -276 -128 -289 -122 -284 -5 -288 83 -515 31 -302 55 -274 58 -279 74 -178 -40 -262 -23 -167 -5 -131 -30 -139 -230 -74 -148 -72 85 176 -126 20 -272 -147 -407 -25 -360 -165 -507 -129 -383 28 -354 47 -234 -60 -190 144 51 303 225 244 247 300 109 59 63 44 307 459 727 432 608 -199 203 299 593 215 380 15 372 65 295 -7 -66 -153 -233 -544 -742 -1118 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