File name: Pandora142s1_MexicoCity-UNAM_20200531_L2Fit_fout2c15d20190823p1-8.txt File generation date: 20251127T111134.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Michel de Grutter Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 142 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora142_of_v3d20171226.txt Instrument calibration file used: Pandora142s1_CF_v15d20190823.txt Level 1 file used: Pandora142s1_MexicoCity-UNAM_20200531_L1_smca1c15d20190823p1-8.txt Full location name: Centro de Ciencias de la Atmosfera, UNAM Short location name: MexicoCity-UNAM Country of location: Mexico Location latitude [deg]: 19.3262 Location longitude [deg]: -99.1761 Location altitude [m]: 2280 Local noon date: 20200531 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 237 378 Nominal wavelengths inside fitting window [nm]: 305.1232 305.2643 305.4054 305.5465 305.6875 305.8286 305.9696 306.1107 306.2517 306.3927 306.5337 306.6747 306.8157 306.9567 307.0976 307.2386 307.3795 307.5205 307.6614 307.8023 307.9432 308.0841 308.2249 308.3658 308.5067 308.6475 308.7883 308.9292 309.0700 309.2108 309.3516 309.4923 309.6331 309.7738 309.9146 310.0553 310.1960 310.3368 310.4775 310.6181 310.7588 310.8995 311.0402 311.1808 311.3214 311.4621 311.6027 311.7433 311.8839 312.0244 312.1650 312.3056 312.4461 312.5866 312.7272 312.8677 313.0082 313.1487 313.2891 313.4296 313.5701 313.7105 313.8509 313.9914 314.1318 314.2722 314.4126 314.5529 314.6933 314.8337 314.9740 315.1143 315.2547 315.3950 315.5353 315.6755 315.8158 315.9561 316.0963 316.2366 316.3768 316.5170 316.6572 316.7974 316.9376 317.0778 317.2179 317.3581 317.4982 317.6383 317.7785 317.9186 318.0587 318.1987 318.3388 318.4789 318.6189 318.7589 318.8990 319.0390 319.1790 319.3189 319.4589 319.5989 319.7388 319.8788 320.0187 320.1586 320.2985 320.4384 320.5783 320.7182 320.8580 320.9979 321.1377 321.2775 321.4173 321.5571 321.6969 321.8367 321.9765 322.1162 322.2560 322.3957 322.5354 322.6751 322.8148 322.9545 323.0941 323.2338 323.3734 323.5131 323.6527 323.7923 323.9319 324.0715 324.2111 324.3506 324.4902 324.6297 324.7693 324.9088 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200531T125341.4Z 7456.537284 233 1 50.75 2 78.63 70.44 150.56 323.33 0.00 1 0.00 1 0 25 3.650e-01 7.372e-03 1.969e-01 5.150e-03 5.561104e-01 2.757788e-03 5.660966e-03 -6.000000e+00 2.108328e-01 228.10 -2.00 3.11 -2.00 320.78 0.00e+00 2.717740e-03 1.142240e-03 9.631679e-04 -6.000000e+00 9.805285e-03 282.34 -2.00 20.00 -2.00 320.19 0.00e+00 4.908 0.001 302.00 328.00 3 3.5255e+00 8.7584e-03 4.6174e-02 -6.0000e+00 5.2462e-01 1.5577e-02 1.1392e-02 2.8174e-02 -6.0000e+00 5.6926e-01 -2.1790e-02 1.1056e-02 1.3581e-02 -6.0000e+00 3.3730e-01 -2.0774e-03 5.4749e-03 5.8203e-03 -6.0000e+00 1.4528e-01 1.9164e-04 -4.8921e-04 1.5120e-04 5.1872e-05 -6.0000e+00 9.9525e-03 -1.8929e-04 6.0975e-05 11 8 0 10 0 0 69.04 18.37 0.31 -0.00019 -0.00387 34 7 1 5 0 1492.410 21.06 15.00 18.37 23.91 46.8 781.84 -35077 900000 -129109 -33508 -125846 900000 -42041 347909 -15653 900000 32400 -36992 -37915 74969 -31036 3645 703 34444 5465 -12317 16405 -9728 25618 -12642 39193 -19142 12101 -1207 17549 -12430 35473 -16488 11769 -14044 2858 -15849 1545 -6675 5655 -8268 -1591 -2098 -2242 -1198 1117 -458 1230 -943 385 3658 781 4955 3 3989 -1454 388 649 2237 -2904 3220 -2650 2187 -759 3677 -875 2703 -673 2683 440 1127 2020 302 -328 -1601 215 1346 744 -1143 1340 -2110 46 -1587 -911 -2550 -341 8 931 -552 1956 120 844 427 1087 213 939 -296 748 -47 229 -442 -636 65 117 -935 -1144 -677 -1496 -182 -344 353 184 538 -421 201 -40 380 -505 516 -831 -353 -451 192 424 1168 -91 895 278 715 530 29 -140 -178 501 -217 -39 35 230 -258 196 -479 0 -254 -233 900000 -2346 -242 -1977 900000 -352 1746 -130 900000 192 -484 -622 544 -711 70 15 598 131 -364 380 -289 591 -445 923 -797 378 -41 512 -526 1137 -977 602 -917 153 -1055 99 -559 509 -979 -193 -271 -302 -162 151 -64 173 -139 58 580 141 948 1 894 -358 97 165 552 -737 776 -724 637 -255 1279 -316 908 -233 950 180 517 982 152 -161 -743 89 502 268 -443 583 -1105 27 -1046 -636 -1912 -268 6 795 -484 1646 97 630 301 749 158 782 -284 807 -56 281 -523 -695 65 112 -967 -1263 -781 -1838 -236 -487 544 301 887 -680 305 -57 539 -745 795 -1368 -587 -736 301 644 1699 -129 1210 377 1050 865 52 -264 -350 1020 -469 -88 82 546 -622 459 -1080 0 -525 SS 20200531T125958.1Z 7456.541645 236 1 50.27 2 77.23 70.85 151.40 325.86 0.00 1 0.00 1 0 25 1.010e-01 5.225e-03 8.691e-02 2.946e-03 5.089001e-01 1.545676e-03 5.285302e-03 -6.000000e+00 5.792548e-02 228.10 -2.00 3.11 -2.00 320.42 0.00e+00 9.431918e-04 5.721811e-04 1.109044e-03 -6.000000e+00 2.550242e-03 282.34 -2.00 20.00 -2.00 319.80 0.00e+00 4.408 0.000 302.00 328.00 3 3.0331e+00 4.7196e-03 4.1686e-02 -6.0000e+00 1.4408e-01 -1.9900e-03 5.9216e-03 2.5475e-02 -6.0000e+00 1.5621e-01 4.8465e-03 5.4349e-03 1.2154e-02 -6.0000e+00 9.2958e-02 -1.5811e-02 2.7471e-03 3.9832e-03 -6.0000e+00 3.9868e-02 4.7952e-04 -5.4901e-04 8.6306e-05 4.1791e-05 -6.0000e+00 2.7313e-03 -3.4366e-04 2.5643e-05 11 1 0 11 8 0 2.85 18.37 0.22 -0.00034 -0.00447 69 14 1 5 0 728.419 21.06 15.01 18.37 24.35 46.7 782.21 -40522 -32771 34756 2987 -23913 -40540 -53533 -22581 -55595 -2263 -14719 -6344 11393 13158 -1888 -1203 -2768 5641 9 -922 -8939 14443 2192 3118 -1883 1792 -7356 685 -6842 -1075 -5127 1192 -344 1819 -2599 -1482 -1025 488 -665 -4314 -1413 -1751 9 -2026 -326 -1958 -51 -402 1187 -417 769 -157 1922 363 1130 -1090 1990 -796 -525 -641 1727 307 1014 22 433 -475 83 1671 1679 1103 1214 482 834 1162 -170 390 -1653 347 -418 -572 -1601 -1294 -1511 -1242 -1013 -74 31 71 656 1209 747 969 513 761 538 475 320 514 395 -248 -797 -21 14 -997 -820 -1170 -658 -274 118 0 61 159 -83 -286 607 -78 222 -108 -431 -531 -483 -419 330 840 349 422 1399 619 443 135 -324 73 217 -117 -39 23 -79 52 34 -59 -343 -183 -458 -383 228 23 -229 -474 -750 -285 -1028 -28 -214 -98 183 241 -48 -33 -84 172 0 -33 -356 464 86 132 -90 86 -383 31 -336 -55 -317 80 -26 135 -192 -113 -90 48 -82 -637 -221 -290 1 -353 -57 -350 -9 -73 219 -84 170 -38 498 102 330 -337 605 -245 -157 -194 543 109 400 9 182 -191 33 685 781 584 687 279 466 605 -81 167 -690 148 -206 -329 -1062 -948 -1180 -1027 -898 -69 29 70 626 1078 617 746 386 607 486 490 357 632 499 -301 -889 -22 15 -1114 -928 -1391 -825 -365 172 0 103 270 -137 -442 871 -111 324 -168 -714 -898 -798 -670 505 1223 491 598 1951 897 717 238 -611 143 441 -242 -85 53 -183 120 78 -127 -707 -379 SS 20200531T130557.3Z 7456.545802 239 1 50.52 2 75.89 71.24 152.15 328.41 0.00 1 0.00 1 0 25 6.165e-02 5.395e-03 5.212e-02 2.632e-03 4.627200e-01 1.360642e-03 4.809069e-03 -6.000000e+00 3.535995e-02 228.10 -2.00 3.11 -2.00 320.05 0.00e+00 1.352306e-03 4.441381e-04 5.609121e-04 -6.000000e+00 1.556852e-03 282.34 -2.00 20.00 -2.00 319.40 0.00e+00 4.017 0.000 302.00 328.00 3 3.2700e+00 3.9964e-03 3.7635e-02 -6.0000e+00 8.7955e-02 1.1301e-02 4.8547e-03 2.2199e-02 -6.0000e+00 9.5360e-02 -1.3317e-02 4.1712e-03 1.0822e-02 -6.0000e+00 5.6747e-02 -3.9568e-03 2.1537e-03 3.6327e-03 -6.0000e+00 2.4335e-02 5.2956e-04 -4.7621e-04 7.6787e-05 3.6665e-05 -6.0000e+00 1.6674e-03 2.1560e-04 1.9447e-05 10 0 0 10 0 0 70.15 18.37 0.20 0.00022 -0.00336 59 12 1 5 0 856.072 21.06 15.00 18.37 24.79 46.8 782.44 15725 -12287 16091 -23694 -2698 -33983 -28432 -21697 -20711 -19002 3411 -18519 -368 -6590 -8085 -2930 -2178 -2063 -111 625 -2045 -868 7124 2944 -1058 -579 -1751 1968 -1890 -1383 17 415 2217 -2265 -2466 -3896 -3005 -2405 -1970 -3182 -2238 -1718 -1654 -1073 69 -668 -691 -210 541 460 695 1305 1071 1234 1150 1373 554 502 924 90 1103 1668 1167 714 542 -46 -472 1573 1085 635 109 114 417 -55 276 -536 -263 -164 -29 -819 -1221 -1360 -1941 -1583 -716 -130 276 311 239 1410 866 1163 487 897 598 614 563 367 263 -433 -854 -320 -303 -913 -609 -1558 -883 -242 152 130 234 57 161 -46 250 239 310 -309 -410 -646 -128 -92 315 621 326 334 787 805 728 132 -233 -30 372 -159 -268 -109 -10 165 251 -362 -390 -96 175 -191 199 -392 -35 -588 -518 -420 -438 -414 63 -470 -10 -216 -317 -122 -98 -99 -6 32 -110 -47 380 175 -70 -39 -119 123 -122 -96 1 36 212 -225 -233 -390 -340 -325 -320 -600 -453 -364 -362 -236 15 -150 -155 -48 125 113 187 381 336 411 398 489 202 180 324 32 413 689 534 350 261 -21 -214 730 567 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