File name: Pandora142s1_MexicoCity-UNAM_20200607_L2Fit_fout2c15d20190823p1-8.txt File generation date: 20251127T111110.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Michel de Grutter Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 142 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora142_of_v3d20171226.txt Instrument calibration file used: Pandora142s1_CF_v15d20190823.txt Level 1 file used: Pandora142s1_MexicoCity-UNAM_20200607_L1_smca1c15d20190823p1-8.txt Full location name: Centro de Ciencias de la Atmosfera, UNAM Short location name: MexicoCity-UNAM Country of location: Mexico Location latitude [deg]: 19.3262 Location longitude [deg]: -99.1761 Location altitude [m]: 2280 Local noon date: 20200607 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 237 378 Nominal wavelengths inside fitting window [nm]: 305.1232 305.2643 305.4054 305.5465 305.6875 305.8286 305.9696 306.1107 306.2517 306.3927 306.5337 306.6747 306.8157 306.9567 307.0976 307.2386 307.3795 307.5205 307.6614 307.8023 307.9432 308.0841 308.2249 308.3658 308.5067 308.6475 308.7883 308.9292 309.0700 309.2108 309.3516 309.4923 309.6331 309.7738 309.9146 310.0553 310.1960 310.3368 310.4775 310.6181 310.7588 310.8995 311.0402 311.1808 311.3214 311.4621 311.6027 311.7433 311.8839 312.0244 312.1650 312.3056 312.4461 312.5866 312.7272 312.8677 313.0082 313.1487 313.2891 313.4296 313.5701 313.7105 313.8509 313.9914 314.1318 314.2722 314.4126 314.5529 314.6933 314.8337 314.9740 315.1143 315.2547 315.3950 315.5353 315.6755 315.8158 315.9561 316.0963 316.2366 316.3768 316.5170 316.6572 316.7974 316.9376 317.0778 317.2179 317.3581 317.4982 317.6383 317.7785 317.9186 318.0587 318.1987 318.3388 318.4789 318.6189 318.7589 318.8990 319.0390 319.1790 319.3189 319.4589 319.5989 319.7388 319.8788 320.0187 320.1586 320.2985 320.4384 320.5783 320.7182 320.8580 320.9979 321.1377 321.2775 321.4173 321.5571 321.6969 321.8367 321.9765 322.1162 322.2560 322.3957 322.5354 322.6751 322.8148 322.9545 323.0941 323.2338 323.3734 323.5131 323.6527 323.7923 323.9319 324.0715 324.2111 324.3506 324.4902 324.6297 324.7693 324.9088 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200607T125444.3Z 7463.538012 218 1 50.54 2 78.43 69.65 81.78 240.39 0.00 1 0.00 1 0 25 9.823e-02 4.315e-03 6.251e-02 1.385e-03 5.772620e-01 7.350512e-04 5.873272e-03 -6.000000e+00 5.632855e-02 227.85 -2.00 3.11 -2.00 320.74 0.00e+00 9.813315e-04 3.044045e-04 9.050714e-04 -6.000000e+00 2.483581e-03 282.56 -2.00 20.00 -2.00 320.15 0.00e+00 4.833 0.000 302.00 328.00 3 1.2110e+00 2.3290e-03 4.6074e-02 -6.0000e+00 1.4002e-01 -3.5495e-03 3.0543e-03 2.8356e-02 -6.0000e+00 1.5178e-01 3.0320e-03 3.0027e-03 1.4037e-02 -6.0000e+00 9.0350e-02 -1.1931e-02 1.4848e-03 4.7502e-03 -6.0000e+00 3.8819e-02 2.0028e-03 -3.7766e-04 3.9714e-05 4.8379e-05 -6.0000e+00 2.6558e-03 -5.5906e-03 7.4158e-05 11 1 0 11 8 0 22.86 18.70 0.16 -0.00559 -0.00843 317 62 1 5 0 157.903 21.27 15.00 18.70 24.27 54.0 780.16 -53686 -17363 -32909 -28812 -47424 -17927 -49014 -1332 -15686 -7219 -36415 7058 -18389 -4495 -14924 7794 -13659 3020 -9376 456 -8498 333 -6806 -2420 -6945 -6542 -5790 -23 -805 1087 1144 1390 2919 -579 2242 -2658 -588 -3541 -1390 -3109 -16 -2467 51 -1952 -101 -2348 364 -883 -986 -1150 343 965 659 506 589 445 544 51 -80 237 951 1471 1515 1708 956 380 257 1090 367 686 423 258 32 611 -114 262 -829 -24 -811 -506 -1216 -1389 -1389 -1294 -915 -146 -20 161 796 1047 818 729 774 607 725 353 614 452 312 -456 -586 -120 187 -632 -656 -1090 -950 -241 51 -16 69 160 47 64 173 255 269 59 -318 -495 -451 -233 432 739 114 439 -266 902 527 196 -224 -120 234 -125 -312 31 -92 31 186 -95 -249 55 -376 -99 -224 -181 -330 -100 -400 -8 -122 -56 -384 59 -235 -62 -273 133 -310 64 -238 11 -229 8 -198 -74 -238 -234 -206 -1 -27 39 48 67 155 -32 117 -152 -38 -280 -131 -345 -2 -316 7 -263 -14 -329 51 -129 -150 -190 62 192 142 118 144 113 141 13 -20 59 252 433 501 614 345 133 90 400 154 323 214 134 16 286 -49 101 -313 -9 -370 -268 -739 -940 -1000 -983 -741 -124 -18 143 693 859 628 528 552 462 620 345 677 550 390 -554 -658 -123 184 -665 -734 -1279 -1177 -318 72 -25 114 268 77 100 255 370 402 93 -526 -834 -742 -372 668 1093 165 607 -369 1343 870 351 -428 -236 480 -271 -715 73 -218 74 436 -214 -536 113 SS 20200607T130059.3Z 7463.542353 221 1 50.61 2 77.05 70.05 83.02 240.99 0.00 1 0.00 1 0 25 5.008e-02 4.502e-03 3.098e-02 9.817e-04 5.245228e-01 5.138224e-04 5.409198e-03 -6.000000e+00 2.871769e-02 227.85 -2.00 3.11 -2.00 320.37 0.00e+00 7.606191e-04 1.882265e-04 8.431294e-04 -6.000000e+00 1.266200e-03 282.56 -2.00 20.00 -2.00 319.75 0.00e+00 4.351 0.000 302.00 328.00 3 1.0759e+00 1.5563e-03 4.1530e-02 -6.0000e+00 7.1387e-02 1.4610e-03 1.9557e-03 2.5452e-02 -6.0000e+00 7.7382e-02 3.9468e-03 1.8109e-03 1.2452e-02 -6.0000e+00 4.6063e-02 -1.2464e-02 9.1858e-04 4.0004e-03 -6.0000e+00 1.9790e-02 3.4413e-03 -4.0679e-04 2.8272e-05 4.1453e-05 -6.0000e+00 1.3540e-03 -5.5157e-03 7.2128e-05 10 0 0 10 0 0 42.46 18.69 0.20 -0.00552 -0.00857 426 84 1 5 0 117.661 21.27 15.00 18.69 24.95 53.8 780.90 -21154 -482 -11409 -12231 -24140 -13784 -19417 -13256 -2903 -22802 -10369 -14736 -1290 -9745 3997 -7390 -1544 -4934 -157 -8633 1395 -5135 2097 -5482 2759 -3643 -2875 -3406 -3237 -1251 399 -108 -679 -3867 -3216 -2337 -2522 -676 -1804 -1155 -2287 -1979 -2019 187 -1206 48 -1456 37 -990 826 7 1382 192 533 730 742 90 437 -407 309 712 1400 1400 1014 955 131 -38 745 1001 586 887 238 716 46 617 -287 -36 -419 -30 -725 -866 -1540 -1222 -1429 -902 -318 51 174 762 1010 791 750 633 782 527 494 343 531 101 -268 -713 78 -102 -634 -818 -903 -1165 -265 36 62 31 142 -8 5 260 203 244 -35 -371 -518 -329 -422 391 713 283 350 842 645 584 87 -33 -145 316 -173 -105 -25 -57 -36 181 -274 -254 -37 -183 -4 -105 -107 -220 -118 -194 -143 -32 -316 -135 -228 -21 -213 92 -213 -46 -164 -5 -331 50 -197 81 -247 123 -181 -141 -161 -152 -63 23 -7 -50 -298 -235 -176 -217 -69 -226 -167 -364 -332 -352 32 -213 9 -266 7 -190 168 2 338 51 152 218 229 28 135 -124 94 230 498 555 434 407 54 -16 315 478 315 510 140 407 25 301 -128 -15 -187 -15 -426 -578 -1139 -956 -1184 -793 -292 48 169 721 902 660 589 486 634 477 504 394 668 131 -335 -831 83 -106 -698 -959 -1103 -1501 -359 52 98 51 239 -13 7 382 294 362 -55 -612 -870 -541 -676 606 1063 409 487 1159 955 945 152 -61 -277 624 -359 -229 -55 -129 -82 407 -595 -529 -75 SS 20200607T130648.3Z 7463.546392 224 1 50.57 2 75.76 70.42 84.18 241.54 0.00 1 0.00 1 0 25 4.219e-02 4.675e-03 1.640e-02 7.400e-04 4.831120e-01 3.853199e-04 5.027733e-03 -6.000000e+00 2.419198e-02 227.85 -2.00 3.11 -2.00 320.07 0.00e+00 8.652330e-04 1.281095e-04 6.480840e-04 -6.000000e+00 1.066673e-03 282.56 -2.00 20.00 -2.00 319.44 0.00e+00 3.981 0.000 302.00 328.00 3 9.1804e-01 1.1390e-03 3.8012e-02 -6.0000e+00 6.0137e-02 2.2695e-03 1.3881e-03 2.3144e-02 -6.0000e+00 6.5188e-02 1.6520e-03 1.2072e-03 1.1284e-02 -6.0000e+00 3.8805e-02 -1.0042e-02 6.2226e-04 3.6161e-03 -6.0000e+00 1.6671e-02 5.5405e-03 -3.7078e-04 2.1386e-05 3.7182e-05 -6.0000e+00 1.1407e-03 -5.3923e-03 6.2960e-05 10 0 0 10 0 0 22.39 18.68 0.17 -0.00539 -0.00818 577 113 1 5 0 86.719 21.27 15.00 18.68 25.65 53.9 781.40 -19500 -6829 -15697 -7671 -26639 -6868 -14974 -8977 -12533 -9102 -8280 -7828 -6124 -5306 -4836 -4261 -1978 -3627 -1327 -2323 -393 -1401 -24 -2305 -1608 -3183 -820 -2562 -276 -1580 2845 846 385 -1999 -1365 -3175 -1490 -1539 -1067 -1683 -1455 -1392 -1338 -842 -851 -293 -694 -643 -817 202 355 1090 624 703 834 938 431 345 -161 480 562 1660 1542 1295 741 25 -25 913 778 552 434 134 314 168 401 144 -288 -101 -322 -599 -913 -1396 -1292 -1478 -840 -436 44 124 716 983 919 718 944 767 618 413 481 472 188 -380 -728 -153 -73 -591 -786 -1044 -1094 -332 45 17 -44 120 -14 -22 237 268 293 58 -296 -480 -407 -300 328 779 323 349 792 801 569 210 -77 -128 308 -197 -128 1 -34 -10 143 -289 -294 -90 -250 -86 -222 -93 -362 -78 -207 -134 -218 -161 -151 -163 -154 -149 -162 -162 -80 -161 -61 -113 -19 -69 -1 -134 -99 -209 -52 -157 -16 -103 204 71 36 -192 -124 -305 -161 -202 -170 -290 -273 -275 -274 -173 -177 -66 -158 -148 -194 47 91 303 188 226 279 325 152 120 -55 163 203 658 683 617 349 11 -11 417 402 324 273 86 195 98 211 69 -130 -47 -172 -372 -648 -1104 -1084 -1317 -800 -438 43 131 737 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