File name: Pandora142s1_MexicoCity-UNAM_20200608_L2Fit_fwvt1c15d20190823p1-8.txt File generation date: 20251127T111147.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c15p1-8 Local principal investigator: Michel de Grutter Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 142 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora142_of_v3d20171226.txt Instrument calibration file used: Pandora142s1_CF_v15d20190823.txt Level 1 file used: Pandora142s1_MexicoCity-UNAM_20200608_L1_smca1c15d20190823p1-8.txt Full location name: Centro de Ciencias de la Atmosfera, UNAM Short location name: MexicoCity-UNAM Country of location: Mexico Location latitude [deg]: 19.3262 Location longitude [deg]: -99.1761 Location altitude [m]: 2280 Local noon date: 20200608 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1654 1803 Nominal wavelengths inside fitting window [nm]: 492.0475 492.1689 492.2903 492.4117 492.5330 492.6544 492.7757 492.8970 493.0183 493.1396 493.2608 493.3821 493.5033 493.6245 493.7457 493.8668 493.9880 494.1091 494.2303 494.3514 494.4725 494.5935 494.7146 494.8357 494.9567 495.0777 495.1987 495.3197 495.4406 495.5616 495.6825 495.8034 495.9243 496.0452 496.1661 496.2869 496.4077 496.5286 496.6494 496.7701 496.8909 497.0117 497.1324 497.2531 497.3738 497.4945 497.6152 497.7358 497.8565 497.9771 498.0977 498.2183 498.3388 498.4594 498.5799 498.7005 498.8210 498.9415 499.0619 499.1824 499.3028 499.4233 499.5437 499.6641 499.7844 499.9048 500.0251 500.1455 500.2658 500.3861 500.5064 500.6266 500.7469 500.8671 500.9873 501.1075 501.2277 501.3478 501.4680 501.5881 501.7082 501.8283 501.9484 502.0685 502.1885 502.3086 502.4286 502.5486 502.6686 502.7885 502.9085 503.0284 503.1483 503.2682 503.3881 503.5080 503.6279 503.7477 503.8675 503.9873 504.1071 504.2269 504.3466 504.4664 504.5861 504.7058 504.8255 504.9452 505.0648 505.1845 505.3041 505.4237 505.5433 505.6629 505.7824 505.9019 506.0215 506.1410 506.2605 506.3799 506.4994 506.6189 506.7383 506.8577 506.9771 507.0965 507.2158 507.3352 507.4545 507.5738 507.6931 507.8124 507.9316 508.0509 508.1701 508.2893 508.4085 508.5277 508.6469 508.7660 508.8851 509.0042 509.1233 509.2424 509.3615 509.4805 509.5996 509.7186 509.8376 509.9566 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20200608T122545.7Z 7464.517890 210 1 19.36 2 84.81 67.52 65.26 230.34 0.00 1 0.00 1 0 22 3.801e-03 3.763e-03 1.294e-03 1.292e-03 1.012985e+04 9.081467e+01 6.918623e+02 -6.000000e+00 2.187550e+02 282.59 -2.00 20.00 -2.00 505.35 0.00e+00 2.662435e-03 3.634216e-05 1.479481e-04 -6.000000e+00 1.081855e-04 282.59 -2.00 20.00 -2.00 500.71 0.00e+00 6.799116e-01 2.574017e-02 7.049278e-02 -6.000000e+00 7.650443e-02 227.82 -2.00 3.11 -2.00 502.26 0.00e+00 9.611 0.004 489.00 513.00 1 5.9936e+00 1.9761e-03 1.2623e-02 -6.0000e+00 5.8812e-03 -3.7827e-02 4.9272e-04 1.7799e-03 -6.0000e+00 1.5018e-03 1.5424e-03 1.6330e-03 1.3578e-04 8.9720e-05 -6.0000e+00 4.2690e-04 -2.4184e-03 6.8055e-05 12 1 1 12 1 1 97.82 18.61 1.08 -0.00242 0.00891 6 4 1 4 0 2741.117 21.27 15.00 18.61 24.16 53.7 778.54 -815 -537 -407 -10 69 398 608 449 275 366 380 1 -257 -276 -533 -560 -173 407 143 5 51 185 401 305 456 247 88 215 -193 -526 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336 635 808 426 260 275 270 194 464 391 258 -29 -15 66 108 436 -64 -227 -97 -538 129 283 -200 -435 105 324 142 0 134 20 385 19 -199 -328 -615 -490 SQ 20200608T123749.3Z 7464.526265 213 1 50.59 2 82.18 68.39 67.40 232.09 0.00 1 0.00 1 0 22 3.049e-03 3.020e-03 1.553e-04 1.551e-04 7.508176e+03 1.056788e+01 5.169123e+02 -6.000000e+00 1.754622e+02 282.59 -2.00 20.00 -2.00 505.34 0.00e+00 2.053074e-03 4.352762e-06 1.154412e-04 -6.000000e+00 8.678225e-05 282.59 -2.00 20.00 -2.00 500.65 0.00e+00 4.790012e-01 3.099306e-03 5.460541e-02 -6.000000e+00 6.137931e-02 227.82 -2.00 3.11 -2.00 502.22 0.00e+00 6.870 0.001 489.00 513.00 1 3.1463e+00 2.3792e-04 9.2465e-03 -6.0000e+00 4.7183e-03 -3.2878e-02 5.9547e-05 1.3481e-03 -6.0000e+00 1.2052e-03 3.6884e-02 2.0034e-03 1.6583e-05 6.9056e-05 -6.0000e+00 3.4244e-04 3.6161e-04 3.3607e-05 12 1 1 12 1 1 99.63 18.60 0.90 0.00036 0.01426 381 75 1 4 0 130.588 21.27 15.00 18.60 24.54 53.7 779.29 -725 -475 -139 4 30 378 572 500 430 288 144 14 -170 -232 -322 -368 -256 163 226 -11 72 212 192 393 438 199 167 256 -130 -421 -412 -487 -88 378 177 -120 -8 30 -68 -74 50 74 144 246 314 321 269 121 27 -224 -403 -571 -715 -475 -132 -20 -63 0 38 140 306 372 280 352 258 107 7 -14 -57 -200 -278 -339 -234 62 3 -375 -506 -397 -355 -405 -418 -529 -446 -195 -158 -213 -159 14 58 -5 170 409 465 277 307 105 -92 -88 -235 -551 -746 -673 -208 -61 -275 -352 -340 -306 -53 86 65 199 359 393 416 545 651 478 319 259 71 78 385 356 173 286 92 -26 206 270 -34 -139 -183 -354 21 225 -61 -104 130 136 99 187 154 118 102 -7 -245 -436 -465 -448 -692 -459 -133 4 31 376 578 510 439 291 144 14 -165 -232 -321 -369 -252 163 231 -12 75 221 200 397 444 202 168 264 -131 -417 -403 -479 -88 389 180 -123 -9 31 -68 -74 50 74 147 254 326 335 279 124 27 -221 -402 -560 -698 -469 -129 -20 -64 0 39 144 315 385 291 365 265 109 7 -14 -56 -194 -269 -330 -230 61 3 -371 -494 -382 -339 -386 -400 -509 -433 -191 -156 -212 -159 14 58 -5 171 402 458 272 306 102 -88 -82 -223 -519 -708 -632 -202 -59 -271 -349 -335 -300 -52 84 65 201 367 404 430 548 659 485 322 266 72 79 384 357 175 289 93 -26 208 272 -34 -137 -178 -346 20 224 -60 -104 131 140 103 194 161 123 106 -7 -248 -435 -461 -446 SQ 20200608T124921.0Z 7464.534271 215 1 6.07 2 79.64 69.19 69.50 233.67 0.00 1 0.00 1 0 22 2.530e-03 2.514e-03 1.371e-04 1.370e-04 5.876340e+03 9.102502e+00 4.074343e+02 -6.000000e+00 1.455998e+02 282.59 -2.00 20.00 -2.00 505.30 0.00e+00 1.730614e-03 3.833122e-06 9.725481e-05 -6.000000e+00 7.201138e-05 282.59 -2.00 20.00 -2.00 500.58 0.00e+00 3.850397e-01 2.739774e-03 4.365566e-02 -6.000000e+00 5.093001e-02 227.82 -2.00 3.11 -2.00 502.15 0.00e+00 5.348 0.001 489.00 513.00 1 9.3124e-01 2.1042e-04 7.2961e-03 -6.0000e+00 3.9151e-03 -2.2862e-02 5.2935e-05 1.0622e-03 -6.0000e+00 9.9994e-04 4.0475e-01 1.7692e-03 1.4726e-05 5.5657e-05 -6.0000e+00 2.8415e-04 -3.0147e-03 5.8114e-05 10 0 0 10 0 0 -2.86 18.57 0.80 -0.00301 0.00926 522 102 1 4 0 11.134 21.17 15.00 18.57 25.15 53.8 780.24 -558 -369 -102 -30 -9 307 446 430 357 210 88 -13 -156 -218 -290 -384 -226 157 235 -30 51 150 153 347 375 164 156 256 -109 -313 -304 -358 -65 394 135 -187 -13 53 -65 -53 66 52 137 208 275 237 201 121 59 -177 -311 -451 -610 -406 -112 -19 -79 -78 -19 109 254 214 220 254 187 74 -15 42 3 -127 -174 -323 -181 101 27 -329 -428 -286 -206 -289 -336 -455 -392 -148 -153 -227 -137 10 45 17 118 378 388 202 216 87 -80 -87 -188 -424 -646 -563 -168 -50 -313 -349 -283 -236 -9 121 38 134 268 283 297 450 538 409 251 236 77 84 353 345 131 252 140 -27 241 264 -4 -63 -129 -292 74 235 -84 -179 73 87 41 135 157 39 61 -24 -231 -368 -360 -307 -540 -348 -99 -30 -9 310 457 445 369 215 89 -13 -153 -220 -292 -376 -224 159 243 -31 54 157 161 367 383 168 159 266 -111 -311 -299 -354 -66 407 138 -193 -13 54 -66 -53 66 53 140 214 287 247 208 124 59 -181 -309 -440 -593 -399 -113 -19 -80 -80 -20 112 261 220 228 262 191 75 -15 41 3 -127 -173 -312 -176 99 27 -322 -413 -283 -202 -282 -329 -435 -378 -143 -150 -224 -136 9 44 16 118 381 394 204 215 85 -76 -84 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