File name: Pandora142s1_MexicoCity-UNAM_20200621_L2Fit_fout2c15d20190823p1-8.txt File generation date: 20251127T111134.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Michel de Grutter Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 142 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora142_of_v3d20171226.txt Instrument calibration file used: Pandora142s1_CF_v15d20190823.txt Level 1 file used: Pandora142s1_MexicoCity-UNAM_20200621_L1_smca1c15d20190823p1-8.txt Full location name: Centro de Ciencias de la Atmosfera, UNAM Short location name: MexicoCity-UNAM Country of location: Mexico Location latitude [deg]: 19.3262 Location longitude [deg]: -99.1761 Location altitude [m]: 2280 Local noon date: 20200621 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 237 378 Nominal wavelengths inside fitting window [nm]: 305.1232 305.2643 305.4054 305.5465 305.6875 305.8286 305.9696 306.1107 306.2517 306.3927 306.5337 306.6747 306.8157 306.9567 307.0976 307.2386 307.3795 307.5205 307.6614 307.8023 307.9432 308.0841 308.2249 308.3658 308.5067 308.6475 308.7883 308.9292 309.0700 309.2108 309.3516 309.4923 309.6331 309.7738 309.9146 310.0553 310.1960 310.3368 310.4775 310.6181 310.7588 310.8995 311.0402 311.1808 311.3214 311.4621 311.6027 311.7433 311.8839 312.0244 312.1650 312.3056 312.4461 312.5866 312.7272 312.8677 313.0082 313.1487 313.2891 313.4296 313.5701 313.7105 313.8509 313.9914 314.1318 314.2722 314.4126 314.5529 314.6933 314.8337 314.9740 315.1143 315.2547 315.3950 315.5353 315.6755 315.8158 315.9561 316.0963 316.2366 316.3768 316.5170 316.6572 316.7974 316.9376 317.0778 317.2179 317.3581 317.4982 317.6383 317.7785 317.9186 318.0587 318.1987 318.3388 318.4789 318.6189 318.7589 318.8990 319.0390 319.1790 319.3189 319.4589 319.5989 319.7388 319.8788 320.0187 320.1586 320.2985 320.4384 320.5783 320.7182 320.8580 320.9979 321.1377 321.2775 321.4173 321.5571 321.6969 321.8367 321.9765 322.1162 322.2560 322.3957 322.5354 322.6751 322.8148 322.9545 323.0941 323.2338 323.3734 323.5131 323.6527 323.7923 323.9319 324.0715 324.2111 324.3506 324.4902 324.6297 324.7693 324.9088 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200621T124909.2Z 7477.534135 230 1 50.46 2 80.14 68.48 83.86 67.18 0.00 1 0.00 1 0 25 4.918e-01 1.448e-02 2.636e-01 8.372e-03 6.305593e-01 4.577615e-03 6.498791e-03 -6.000000e+00 2.846309e-01 227.37 -2.00 3.11 -2.00 321.14 0.00e+00 2.835501e-03 2.103094e-03 2.706488e-03 -6.000000e+00 1.325628e-02 282.73 -2.00 20.00 -2.00 320.58 0.00e+00 5.592 0.001 302.00 328.00 3 3.6695e+00 1.5283e-02 5.4516e-02 -6.0000e+00 7.0675e-01 1.3105e-01 2.0500e-02 3.7817e-02 -6.0000e+00 7.6751e-01 -1.8285e-01 2.0024e-02 1.5769e-02 -6.0000e+00 4.5449e-01 7.2744e-02 9.6616e-03 6.6971e-03 -6.0000e+00 1.9480e-01 9.1045e-05 -8.8406e-04 2.4322e-04 5.7893e-05 -6.0000e+00 1.3579e-02 -1.5770e-03 5.8150e-05 12 9 8 11 8 0 92.22 18.59 0.46 -0.00158 -0.00822 19 4 1 5 0 2655.124 21.27 15.01 18.59 25.85 52.9 786.13 -99242 20837 490 -115646 900000 -175220 900000 -142193 120994 -191996 900000 -131262 96240 -93308 900000 -58624 354444 23076 41432 -41697 -20857 -52482 13775 -42000 72871 -31803 -4910 -13853 621 8306 -11168 29437 -15434 19972 -26125 24979 -14998 55142 8916 24711 -5028 25152 -767 22169 -519 35794 -10710 16844 -9249 10884 4839 12327 1299 8166 5464 6254 6935 1678 9813 -370 1923 1315 3052 -2436 4374 -4118 9070 -2780 3911 -1899 3939 632 3371 -4313 1938 -2932 5474 -1335 187 -552 1346 -2359 -1600 -1187 -1903 -913 -36 811 467 2182 -1168 1226 -2648 1835 -1678 762 -1313 729 -908 1620 -1373 1411 -2976 -40 -1903 365 -1374 570 -746 -297 -330 122 -33 -15 926 566 -117 -1358 203 -855 -327 -466 1422 324 1998 333 2179 -436 1672 522 601 -549 657 -212 -5 -220 90 -23 -45 -302 -783 -230 -957 170 4 -1415 900000 -3531 900000 -2622 987 -6509 900000 -3169 785 -2504 900000 -1602 2891 359 579 -1301 -541 -1840 281 -1540 990 -1174 -141 -417 17 232 -443 929 -829 782 -1493 924 -910 2090 625 1731 -506 2021 -82 1926 -57 2848 -1350 1698 -1247 1316 692 1813 230 1457 1047 1233 1376 343 1811 -75 409 315 814 -748 1263 -1252 2447 -888 1332 -775 1624 273 1369 -1752 670 -968 1614 -447 72 -250 689 -1398 -1006 -788 -1360 -681 -28 628 357 1546 -797 773 -1717 1229 -1325 677 -1362 827 -1078 1803 -1447 1308 -2770 -38 -1987 391 -1587 695 -1017 -446 -533 200 -53 -22 1330 802 -173 -2134 332 -1420 -527 -727 2112 468 2740 446 2886 -650 2730 945 1159 -1119 1388 -480 -12 -536 222 -59 -108 -700 -1728 -484 SS 20200621T125634.7Z 7477.539290 234 1 51.32 2 78.51 68.98 82.30 67.68 0.00 1 0.00 1 0 25 2.206e-01 6.624e-03 1.824e-01 4.155e-03 5.565416e-01 2.195764e-03 5.684967e-03 -6.000000e+00 1.262093e-01 227.37 -2.00 3.11 -2.00 320.75 0.00e+00 3.974098e-03 9.070632e-04 1.044366e-03 -6.000000e+00 5.580219e-03 282.73 -2.00 20.00 -2.00 320.16 0.00e+00 4.861 0.000 302.00 328.00 3 3.1912e+00 6.9400e-03 4.6042e-02 -6.0000e+00 3.1335e-01 1.4817e-02 9.0169e-03 2.8845e-02 -6.0000e+00 3.3986e-01 -1.4927e-02 8.7075e-03 1.3742e-02 -6.0000e+00 2.0241e-01 -3.5521e-03 4.3188e-03 7.0255e-03 -6.0000e+00 8.6998e-02 2.7502e-04 -5.4608e-04 1.1999e-04 5.7503e-05 -6.0000e+00 5.9648e-03 -1.4306e-03 4.0870e-05 11 9 0 11 8 0 59.14 18.59 0.19 -0.00143 -0.00553 45 9 1 5 0 1126.558 21.27 15.00 18.59 26.36 53.1 788.26 -60608 143124 -55483 72378 -54001 -80525 19573 -58712 -58979 -56428 -32311 -73546 -9395 -43788 24608 -12338 -6787 -22157 1165 -39924 7837 -4641 1552 6747 20828 -9676 6445 9300 18379 -14070 9620 -8687 10905 -942 -6390 -2012 -7268 2211 -6552 -1647 -4459 -1820 -3949 -1515 -3452 3701 -2726 2834 -2822 4751 523 4538 967 1401 1510 2884 668 245 -141 3214 -187 855 2070 1181 1581 -345 424 782 491 -64 1651 7 1226 -1304 1670 -385 -955 -1345 542 -1115 -320 -1990 -1170 -1547 -1328 80 116 295 1593 531 1400 1204 273 982 35 825 261 195 -143 -58 -1237 689 -535 -911 -1411 -1162 -1197 206 -25 256 -242 402 74 -44 411 307 -124 -157 -292 -461 -328 -359 714 751 -71 -140 1987 155 683 -57 164 -178 610 -10 -41 -358 -229 74 135 -233 -82 -221 -531 580 -541 293 -462 -892 97 -663 -734 -723 -352 -1347 -122 -947 352 -278 -161 -653 30 -1540 200 -134 45 201 582 -368 213 292 540 -616 397 -490 572 -56 -381 -120 -516 173 -667 -186 -562 -236 -546 -210 -495 507 -406 412 -453 764 97 893 213 330 369 720 173 62 -36 791 -51 257 692 432 572 -123 149 288 206 -30 824 4 605 -615 696 -149 -358 -534 243 -593 -193 -1349 -834 -1174 -1074 68 102 261 1370 436 1065 864 194 736 30 798 288 237 -179 -70 -1390 692 -528 -957 -1587 -1366 -1488 269 -35 401 -402 674 120 -68 600 442 -185 -247 -482 -775 -541 -572 1095 1112 -101 -194 2691 232 1124 -102 313 -351 1253 -21 -94 -844 -549 178 318 -527 -176 -459 SS 20200621T130249.2Z 7477.543625 237 1 50.35 2 77.13 69.38 80.98 68.08 0.00 1 0.00 1 0 25 1.445e-01 5.628e-03 1.143e-01 2.924e-03 5.111362e-01 1.526867e-03 5.279835e-03 -6.000000e+00 8.270347e-02 227.37 -2.00 3.11 -2.00 320.42 0.00e+00 3.286331e-03 5.691663e-04 1.084210e-03 -6.000000e+00 3.656408e-03 282.73 -2.00 20.00 -2.00 319.80 0.00e+00 4.376 0.000 302.00 328.00 3 3.0198e+00 4.6477e-03 4.1722e-02 -6.0000e+00 2.0534e-01 6.4592e-03 5.8441e-03 2.6419e-02 -6.0000e+00 2.2269e-01 5.3419e-03 5.4033e-03 1.2270e-02 -6.0000e+00 1.3263e-01 -1.3858e-02 2.7375e-03 5.9893e-03 -6.0000e+00 5.7015e-02 4.8837e-04 -4.0202e-04 8.4872e-05 4.7823e-05 -6.0000e+00 3.9080e-03 -2.2261e-03 5.1717e-05 10 0 0 10 0 0 60.64 18.58 0.13 -0.00223 -0.00525 67 13 1 5 0 751.361 21.27 15.00 18.58 26.74 53.0 789.63 -53011 -11744 -28698 -6618 -39597 101700 -54618 47630 -30498 47940 -27227 21758 -26117 30871 -15767 -1164 -16257 6331 2314 1948 -5171 -55 -10575 -1712 -600 -2120 -8776 -864 3864 -2839 5366 347 6208 -2131 8829 -7192 4179 -2051 798 -4013 823 -2233 2216 -3121 774 -3059 791 -2543 1006 -579 418 -231 217 -801 187 975 225 -10 -367 1642 -109 2325 1057 1004 568 1879 -1056 2281 -542 775 -602 836 110 1349 -302 516 -745 2 -908 -727 -1136 -1143 -1253 -1582 -936 -9 315 140 974 1308 1426 557 1335 324 531 233 853 501 509 -865 -397 -225 55 -920 -1014 -1195 -954 -390 -154 148 23 239 -35 -109 162 136 -80 18 -544 -380 -527 -38 122 1138 -76 824 405 960 478 262 -133 82 305 -13 -191 31 29 51 115 -512 -417 94 -653 -113 -329 -60 -444 339 -781 315 -438 365 -416 249 -554 485 -444 -32 -567 196 79 70 -200 -2 -461 -74 -27 -101 -444 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