File name: Pandora142s1_MexicoCity-UNAM_20210303_L2Fit_fwvt1c19d20210215p1-8.txt File generation date: 20251127T113118.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c19p1-8 Local principal investigator: -- Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 142 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora142_OF_v2d20200821.txt Instrument calibration file used: Pandora142s1_CF_v19d20210215.txt Level 1 file used: Pandora142s1_MexicoCity-UNAM_20210303_L1_smca1c19d20210215p1-8.txt Full location name: Centro de Ciencias de la Atmosfera, UNAM Short location name: MexicoCity-UNAM Country of location: Mexico Location latitude [deg]: 19.3262 Location longitude [deg]: -99.1761 Location altitude [m]: 2280 Local noon date: 20210303 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1654 1802 Nominal wavelengths inside fitting window [nm]: 492.0967 492.2182 492.3396 492.4611 492.5825 492.7039 492.8253 492.9466 493.0680 493.1893 493.3106 493.4319 493.5532 493.6745 493.7957 493.9170 494.0382 494.1594 494.2806 494.4017 494.5229 494.6440 494.7651 494.8862 495.0073 495.1284 495.2494 495.3705 495.4915 495.6125 495.7335 495.8545 495.9754 496.0964 496.2173 496.3382 496.4591 496.5799 496.7008 496.8216 496.9425 497.0633 497.1841 497.3048 497.4256 497.5463 497.6671 497.7878 497.9085 498.0291 498.1498 498.2704 498.3911 498.5117 498.6323 498.7528 498.8734 498.9939 499.1145 499.2350 499.3555 499.4759 499.5964 499.7168 499.8373 499.9577 500.0781 500.1985 500.3188 500.4392 500.5595 500.6798 500.8001 500.9204 501.0406 501.1609 501.2811 501.4013 501.5215 501.6417 501.7619 501.8820 502.0021 502.1223 502.2424 502.3624 502.4825 502.6025 502.7226 502.8426 502.9626 503.0826 503.2025 503.3225 503.4424 503.5623 503.6822 503.8021 503.9220 504.0418 504.1616 504.2815 504.4013 504.5210 504.6408 504.7605 504.8803 505.0000 505.1197 505.2394 505.3590 505.4787 505.5983 505.7179 505.8375 505.9571 506.0767 506.1962 506.3158 506.4353 506.5548 506.6742 506.7937 506.9132 507.0326 507.1520 507.2714 507.3908 507.5101 507.6295 507.7488 507.8681 507.9874 508.1067 508.2260 508.3452 508.4645 508.5837 508.7029 508.8221 508.9412 509.0604 509.1795 509.2986 509.4177 509.5368 509.6559 509.7749 509.8939 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-249: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 250-398: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20210303T132115.9Z 7732.556434 235 1 47.75 2 84.54 98.97 54.37 237.69 0.00 1 0.00 1 0 22 8.106e-03 7.993e-03 5.508e-04 5.484e-04 6.848194e+03 3.538880e+01 4.581811e+02 -6.000000e+00 4.510797e+02 279.87 -2.00 20.00 -2.00 505.41 0.00e+00 9.025946e-03 1.523014e-05 4.879383e-04 -6.000000e+00 2.273815e-04 279.87 -2.00 20.00 -2.00 501.09 0.00e+00 3.720201e-01 1.071539e-02 9.399764e-02 -6.000000e+00 1.623532e-01 225.15 -2.00 3.11 -2.00 502.57 0.00e+00 9.247 0.004 489.00 513.00 1 5.2939e+00 8.1851e-04 1.7313e-02 -6.0000e+00 1.2430e-02 -8.8113e-02 2.0766e-04 1.6348e-03 -6.0000e+00 3.2401e-03 3.0515e-03 1.0661e-03 5.5545e-05 1.9128e-04 -6.0000e+00 8.4822e-04 2.0689e-02 -1.3285e-04 12 8 8 10 0 0 90.68 23.75 3.82 0.02069 0.02808 56 14 1 4 0 852.450 26.41 20.00 23.75 20.15 11.8 778.26 -2335 -1648 -718 46 491 1181 1282 1274 991 612 66 -179 -651 -765 -1025 -802 -527 134 414 490 447 586 652 741 1045 809 628 226 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1002 922 469 -82 -731 -1176 -1587 -1589 -1205 -436 -134 -121 -351 -468 -708 -343 34 308 749 1257 1452 1633 1662 1779 1239 923 730 442 263 435 499 495 505 350 363 359 310 -205 -416 -839 -1019 -767 -202 -252 108 269 259 196 429 485 521 79 -171 -997 -1179 -1321 SQ 20210303T133302.3Z 7732.564610 238 1 48.57 2 81.80 100.00 56.71 239.57 0.00 1 0.00 1 0 15 4.272e-03 4.228e-03 1.567e-04 1.564e-04 5.492649e+03 9.968346e+00 3.793320e+02 -6.000000e+00 2.377434e+02 279.87 -2.00 20.00 -2.00 505.36 0.00e+00 6.013227e-03 4.333974e-06 3.272465e-04 -6.000000e+00 1.198479e-04 279.87 -2.00 20.00 -2.00 500.85 0.00e+00 3.606513e-01 3.084456e-03 6.579982e-02 -6.000000e+00 8.557968e-02 225.15 -2.00 3.11 -2.00 502.37 0.00e+00 6.595 0.001 489.00 513.00 1 3.2515e+00 2.3591e-04 1.1960e-02 -6.0000e+00 6.5518e-03 -6.5174e-02 6.0061e-05 1.2068e-03 -6.0000e+00 1.7081e-03 3.2818e-02 1.5787e-03 1.5930e-05 1.3265e-04 -6.0000e+00 4.4711e-04 -5.9624e-03 2.0720e-05 11 8 0 10 0 0 46.88 23.75 1.45 -0.00596 0.00499 526 130 1 4 0 91.280 26.41 20.00 23.75 20.51 11.8 780.74 -999 -731 -210 78 308 628 758 683 588 319 129 -47 -351 -437 -466 -431 -243 84 255 186 254 356 300 479 540 400 297 141 -401 -649 -582 -581 -241 224 205 80 119 81 -113 -44 53 149 298 431 525 481 332 144 -23 -477 -719 -872 -921 -602 -222 49 184 282 333 370 480 568 476 446 275 87 -128 -215 -365 -532 -438 -446 -297 -90 -112 -362 -512 -508 -590 -626 -528 -565 -503 -291 -275 -320 -258 -191 -166 3 108 397 496 434 406 198 -108 -370 -660 -868 -866 -711 -311 -135 -245 -278 -261 -344 -157 35 177 376 652 731 828 903 886 641 527 392 258 136 342 280 221 339 240 133 307 203 -129 -162 -286 -504 -289 -47 -155 -11 196 144 159 251 187 93 39 -166 -473 -591 -551 -920 -687 -195 75 302 627 737 667 571 318 127 -46 -338 -417 -444 -413 -237 81 247 182 249 350 296 476 540 401 296 138 -384 -609 -564 -548 -233 223 208 81 121 81 -113 -44 53 152 296 435 534 490 337 145 -22 -479 -708 -848 -898 -598 -218 49 188 290 343 382 498 592 498 465 285 89 -129 -215 -361 -522 -429 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3.4980e-04 -7.5243e-03 2.8705e-05 10 0 0 10 0 0 5.06 23.73 1.05 -0.00752 0.00367 694 171 1 4 0 38.300 26.32 20.00 23.73 20.91 11.9 782.85 -746 -570 -155 80 213 529 597 587 492 267 72 -51 -297 -338 -356 -324 -204 94 221 100 181 295 211 387 451 309 237 145 -342 -493 -378 -450 -146 216 151 -27 83 26 -101 -29 60 110 217 349 418 365 244 110 -34 -430 -570 -712 -754 -498 -183 18 124 182 235 266 403 268 344 367 227 46 -113 -138 -286 -421 -347 -331 -257 -22 -71 -284 -386 -334 -429 -472 -400 -422 -394 -190 -226 -261 -212 -170 -122 -42 88 297 364 291 295 122 -92 -293 -459 -650 -686 -613 -230 -153 -253 -258 -202 -280 -64 51 137 268 486 551 636 717 720 495 414 319 216 132 309 266 191 310 232 125 275 209 -101 -98 -211 -400 -200 14 -131 0 136 111 111 204 142 65 -20 -132 -372 -481 -442 -700 -524 -148 78 214 519 595 588 489 263 70 -51 -292 -329 -346 -318 -196 92 220 100 182 298 214 394 462 317 241 145 -335 -471 -358 -432 -144 219 151 -27 82 26 -103 -30 61 109 219 357 430 376 250 111 -34 -434 -562 -692 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