File name: Pandora142s1_MexicoCity-UNAM_20210304_L2Fit_fwvt1c19d20210215p1-8.txt File generation date: 20251127T113105.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c19p1-8 Local principal investigator: -- Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 142 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora142_OF_v2d20200821.txt Instrument calibration file used: Pandora142s1_CF_v19d20210215.txt Level 1 file used: Pandora142s1_MexicoCity-UNAM_20210304_L1_smca1c19d20210215p1-8.txt Full location name: Centro de Ciencias de la Atmosfera, UNAM Short location name: MexicoCity-UNAM Country of location: Mexico Location latitude [deg]: 19.3262 Location longitude [deg]: -99.1761 Location altitude [m]: 2280 Local noon date: 20210304 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1654 1802 Nominal wavelengths inside fitting window [nm]: 492.0967 492.2182 492.3396 492.4611 492.5825 492.7039 492.8253 492.9466 493.0680 493.1893 493.3106 493.4319 493.5532 493.6745 493.7957 493.9170 494.0382 494.1594 494.2806 494.4017 494.5229 494.6440 494.7651 494.8862 495.0073 495.1284 495.2494 495.3705 495.4915 495.6125 495.7335 495.8545 495.9754 496.0964 496.2173 496.3382 496.4591 496.5799 496.7008 496.8216 496.9425 497.0633 497.1841 497.3048 497.4256 497.5463 497.6671 497.7878 497.9085 498.0291 498.1498 498.2704 498.3911 498.5117 498.6323 498.7528 498.8734 498.9939 499.1145 499.2350 499.3555 499.4759 499.5964 499.7168 499.8373 499.9577 500.0781 500.1985 500.3188 500.4392 500.5595 500.6798 500.8001 500.9204 501.0406 501.1609 501.2811 501.4013 501.5215 501.6417 501.7619 501.8820 502.0021 502.1223 502.2424 502.3624 502.4825 502.6025 502.7226 502.8426 502.9626 503.0826 503.2025 503.3225 503.4424 503.5623 503.6822 503.8021 503.9220 504.0418 504.1616 504.2815 504.4013 504.5210 504.6408 504.7605 504.8803 505.0000 505.1197 505.2394 505.3590 505.4787 505.5983 505.7179 505.8375 505.9571 506.0767 506.1962 506.3158 506.4353 506.5548 506.6742 506.7937 506.9132 507.0326 507.1520 507.2714 507.3908 507.5101 507.6295 507.7488 507.8681 507.9874 508.1067 508.2260 508.3452 508.4645 508.5837 508.7029 508.8221 508.9412 509.0604 509.1795 509.2986 509.4177 509.5368 509.6559 509.7749 509.8939 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-249: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 250-398: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20210304T131148.3Z 7733.549865 231 1 24.65 2 86.57 97.82 46.86 219.74 0.00 1 0.00 1 0 15 7.202e-03 7.097e-03 7.335e-04 7.307e-04 8.449926e+03 4.819327e+01 5.684339e+02 -6.000000e+00 4.008210e+02 279.89 -2.00 20.00 -2.00 505.40 0.00e+00 7.352999e-03 2.026242e-05 3.983729e-04 -6.000000e+00 2.020345e-04 279.89 -2.00 20.00 -2.00 501.05 0.00e+00 6.349314e-01 1.427547e-02 8.946387e-02 -6.000000e+00 1.442576e-01 225.22 -2.00 3.11 -2.00 502.53 0.00e+00 12.704 0.009 489.00 513.00 1 4.9272e+00 1.0904e-03 1.8475e-02 -6.0000e+00 1.1044e-02 -7.7974e-02 2.7658e-04 1.8467e-03 -6.0000e+00 2.8789e-03 3.0240e-03 1.3564e-03 7.3541e-05 1.6541e-04 -6.0000e+00 7.5365e-04 2.2315e-02 -1.4085e-04 12 9 9 12 1 1 93.08 23.75 3.04 0.02232 0.03172 28 14 1 4 0 843.880 26.41 20.00 23.75 19.49 11.9 778.12 -1922 -1529 -531 26 523 824 1181 1099 965 301 290 -101 -543 -797 -875 -640 -411 195 570 500 529 490 543 758 882 838 522 82 -652 -1327 -1165 -912 -450 421 434 312 196 100 -115 -73 174 234 542 753 933 863 702 262 136 -782 -1080 -1410 -1401 -866 -188 306 470 535 711 579 906 213 752 788 455 208 -181 -484 -515 -741 -653 -673 -418 -79 -218 -675 -868 -970 -970 -1016 -815 -775 -709 -421 -474 -450 -486 -454 -339 38 359 700 907 787 705 472 -53 -641 -1271 -1434 -1530 -1083 -462 -72 -111 -453 -512 -540 -345 66 197 580 1008 1185 1402 1599 1411 1099 865 532 250 284 488 429 351 495 390 373 372 139 -215 -430 -553 -778 -579 -372 -61 -4 364 268 323 290 219 314 92 -227 -684 -996 -1138 -1692 -1375 -491 24 488 783 1134 1060 926 286 272 -94 -499 -728 -799 -589 -384 185 550 486 516 480 513 722 846 806 501 78 -631 -1262 -1100 -871 -423 406 427 308 192 97 -112 -72 171 234 551 747 933 866 702 259 132 -782 -1059 -1369 -1366 -859 -184 307 479 550 731 598 939 224 789 824 472 213 -184 -488 -514 -735 -647 -671 -421 -80 -221 -680 -861 -953 -949 -993 -799 -765 -705 -421 -477 -454 -490 -455 -339 38 365 695 906 782 714 467 -52 -610 -1195 -1340 -1445 -1047 -461 -71 -111 -454 -509 -536 -345 67 204 609 1030 1222 1456 1676 1493 1166 911 554 257 291 501 445 367 520 411 393 392 146 -225 -443 -566 -801 -602 -394 -65 -5 387 287 349 315 239 342 100 -243 -721 -1038 -1187 SQ 20210304T132210.0Z 7733.557060 234 1 47.99 2 84.15 98.71 48.45 222.20 0.00 1 0.00 1 0 22 3.540e-03 3.501e-03 1.546e-04 1.543e-04 6.097381e+03 9.982678e+00 4.235917e+02 -6.000000e+00 1.970357e+02 279.89 -2.00 20.00 -2.00 505.36 0.00e+00 4.676628e-03 4.278671e-06 2.560444e-04 -6.000000e+00 9.932144e-05 279.89 -2.00 20.00 -2.00 500.81 0.00e+00 5.887577e-01 3.052922e-03 5.983458e-02 -6.000000e+00 7.092382e-02 225.22 -2.00 3.11 -2.00 502.35 0.00e+00 8.755 0.003 489.00 513.00 1 2.9592e+00 2.3343e-04 1.2426e-02 -6.0000e+00 5.4298e-03 -5.0206e-02 5.9479e-05 1.2787e-03 -6.0000e+00 1.4155e-03 3.4752e-02 1.5533e-03 1.5659e-05 1.0864e-04 -6.0000e+00 3.7050e-04 1.3770e-03 -2.2107e-05 10 0 0 10 0 0 89.17 23.75 1.12 0.00138 0.01215 646 159 1 4 0 74.280 26.41 20.00 23.75 19.78 11.9 780.75 -770 -566 -109 118 273 586 661 603 531 247 126 -53 -284 -358 -355 -321 -167 80 235 156 228 300 244 417 473 309 232 133 -363 -566 -456 -453 -172 233 139 -9 46 10 -115 -69 48 93 203 357 369 391 242 99 -69 -420 -598 -740 -747 -524 -193 24 135 208 221 293 422 319 382 355 210 49 -129 -168 -296 -425 -327 -380 -284 -66 -95 -334 -401 -435 -439 -511 -409 -445 -430 -225 -212 -271 -221 -181 -107 -42 95 350 410 337 331 156 -99 -300 -584 -734 -770 -626 -300 -162 -282 -272 -263 -305 -96 46 112 321 526 628 664 742 730 533 435 334 182 103 314 275 161 317 241 85 283 188 -112 -128 -206 -418 -195 5 -113 -3 197 147 137 204 157 56 33 -124 -357 -484 -473 -716 -515 -102 115 270 568 649 595 521 239 121 -52 -276 -346 -342 -312 -165 78 232 156 227 299 244 421 480 314 234 132 -353 -537 -430 -432 -169 235 143 -9 47 10 -116 -69 49 92 203 362 377 401 247 100 -68 -423 -588 -719 -727 -520 -189 24 138 213 228 301 436 332 398 368 216 50 -129 -166 -290 -414 -318 -372 -282 -66 -95 -330 -390 -419 -420 -489 -394 -431 -420 -221 -211 -270 -220 -180 -107 -42 96 359 406 345 333 153 -95 -282 -541 -676 -716 -598 -297 -158 -279 -268 -256 -296 -94 46 112 328 543 653 696 784 747 545 457 347 186 105 321 283 167 328 250 89 293 194 -114 -129 -206 -419 -197 5 -114 -3 205 154 144 216 167 59 35 -129 -365 -487 -475 SQ 20210304T133425.1Z 7733.565569 237 1 14.27 2 81.29 99.78 50.42 224.92 0.00 1 0.00 1 0 22 2.744e-03 2.729e-03 1.386e-04 1.385e-04 4.238647e+03 8.621484e+00 2.998124e+02 -6.000000e+00 1.527114e+02 279.89 -2.00 20.00 -2.00 505.31 0.00e+00 3.090100e-03 3.823778e-06 1.702259e-04 -6.000000e+00 7.697839e-05 279.89 -2.00 20.00 -2.00 500.66 0.00e+00 4.431041e-01 2.733046e-03 4.078496e-02 -6.000000e+00 5.496875e-02 225.22 -2.00 3.11 -2.00 502.22 0.00e+00 6.254 0.001 489.00 513.00 1 1.8955e+00 2.0908e-04 8.6583e-03 -6.0000e+00 4.2083e-03 -3.3301e-02 5.3742e-05 8.8958e-04 -6.0000e+00 1.0971e-03 1.3709e-01 1.5548e-03 1.4080e-05 7.3643e-05 -6.0000e+00 2.8716e-04 -6.9350e-03 2.8675e-05 10 0 0 10 0 0 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