File name: Pandora142s1_MexicoCity-UNAM_20210318_L2Fit_fout2c19d20210215p1-8.txt File generation date: 20251127T113019.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c19p1-8 Local principal investigator: -- Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 142 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora142_OF_v2d20200821.txt Instrument calibration file used: Pandora142s1_CF_v19d20210215.txt Level 1 file used: Pandora142s1_MexicoCity-UNAM_20210318_L1_smca1c19d20210215p1-8.txt Full location name: Centro de Ciencias de la Atmosfera, UNAM Short location name: MexicoCity-UNAM Country of location: Mexico Location latitude [deg]: 19.3262 Location longitude [deg]: -99.1761 Location altitude [m]: 2280 Local noon date: 20210318 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 237 378 Nominal wavelengths inside fitting window [nm]: 305.1046 305.2458 305.3870 305.5282 305.6694 305.8105 305.9517 306.0928 306.2339 306.3750 306.5161 306.6572 306.7983 306.9393 307.0804 307.2214 307.3625 307.5035 307.6445 307.7855 307.9265 308.0674 308.2084 308.3493 308.4903 308.6312 308.7721 308.9130 309.0539 309.1948 309.3356 309.4765 309.6173 309.7582 309.8990 310.0398 310.1806 310.3214 310.4622 310.6029 310.7437 310.8844 311.0252 311.1659 311.3066 311.4473 311.5880 311.7286 311.8693 312.0099 312.1506 312.2912 312.4318 312.5724 312.7130 312.8536 312.9941 313.1347 313.2752 313.4158 313.5563 313.6968 313.8373 313.9778 314.1183 314.2587 314.3992 314.5396 314.6800 314.8204 314.9608 315.1012 315.2416 315.3820 315.5223 315.6627 315.8030 315.9433 316.0836 316.2239 316.3642 316.5045 316.6447 316.7850 316.9252 317.0655 317.2057 317.3459 317.4861 317.6262 317.7664 317.9066 318.0467 318.1868 318.3269 318.4671 318.6071 318.7472 318.8873 319.0274 319.1674 319.3074 319.4475 319.5875 319.7275 319.8675 320.0074 320.1474 320.2873 320.4273 320.5672 320.7071 320.8470 320.9869 321.1268 321.2667 321.4065 321.5464 321.6862 321.8260 321.9658 322.1056 322.2454 322.3852 322.5249 322.6647 322.8044 322.9441 323.0838 323.2235 323.3632 323.5029 323.6426 323.7822 323.9218 324.0615 324.2011 324.3407 324.4803 324.6199 324.7594 324.8990 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210318T154737.0Z 7747.658067 46 1 3.94 2 47.80 109.58 94.05 69.92 0.00 1 0.00 1 0 17 9.575e-03 7.746e-03 6.118e-03 3.951e-03 1.860676e-01 2.026561e-03 2.076585e-03 -6.000000e+00 5.487147e-03 226.22 -2.00 3.11 -2.00 315.16 0.00e+00 -7.214819e-05 1.794351e-04 1.767240e-05 -6.000000e+00 2.409140e-04 280.20 -2.00 20.00 -2.00 314.60 0.00e+00 1.486 0.000 302.00 328.00 3 4.4916e+00 5.1856e-03 1.4224e-02 -6.0000e+00 1.3600e-02 2.0258e-02 5.7611e-03 8.5190e-03 -6.0000e+00 1.4754e-02 -5.9725e-04 3.3104e-03 4.2314e-03 -6.0000e+00 8.7828e-03 -2.0740e-03 1.4995e-03 1.2038e-03 -6.0000e+00 3.7800e-03 1.5548e-03 -1.3641e-04 1.1157e-04 1.6042e-05 -6.0000e+00 2.6149e-04 -8.4072e-03 4.9003e-05 12 9 1 12 1 1 999.00 23.65 0.13 -0.00841 -0.00943 2 9 1 5 0 1254.430 26.32 20.00 23.65 23.41 12.0 791.70 -1359 -871 -289 -2144 922 -2432 1133 1110 1792 -3252 -144 -106 -439 -839 -240 -762 -45 -652 149 -510 844 -712 1572 585 1784 952 510 -664 1852 2012 823 2285 1013 532 -1703 -1449 -1694 -1275 100 -900 -1270 -783 -1338 -11 -690 -50 -1303 -276 32 987 734 673 636 897 924 669 38 575 662 331 939 666 1225 734 216 440 -739 796 989 311 568 -73 351 -19 -165 107 -391 66 79 -554 -929 -2348 -1690 -1106 -1484 -580 -174 33 -578 21 819 -65 -119 1473 344 103 791 411 -628 -342 -387 24 811 -346 -810 -764 -1155 -248 5 733 -205 -228 -100 -13 754 228 -55 416 50 -391 -38 39 -166 423 399 349 3361 787 846 433 480 107 525 -291 -32 -355 440 -551 -424 -657 -717 -636 -410 -273 -90 -631 241 -639 307 332 574 -1106 -47 -36 -158 -331 -103 -345 -21 -304 71 -248 412 -349 774 301 935 515 270 -336 872 946 399 1157 537 279 -871 -745 -934 -793 69 -678 -1002 -627 -1098 -9 -557 -40 -1034 -213 24 746 573 545 533 772 802 585 34 506 578 288 840 624 1198 738 210 402 -655 697 916 310 587 -77 367 -19 -159 97 -334 55 69 -524 -940 -2510 -1846 -1242 -1753 -705 -217 42 -727 25 939 -71 -122 1498 369 118 953 517 -808 -430 -463 27 919 -411 -1014 -982 -1516 -333 7 1034 -296 -324 -137 -17 932 277 -68 528 67 -537 -52 53 -224 549 505 429 3976 961 1071 569 639 144 715 -406 -46 -522 658 -835 -641 -971 -1043 -910 SS 20210318T160348.0Z 7747.669306 55 1 48.04 2 44.23 112.23 90.55 71.21 0.00 1 0.00 1 0 17 7.285e-03 5.840e-03 1.422e-03 7.787e-04 1.705766e-01 3.952311e-04 1.896629e-03 -6.000000e+00 4.174557e-03 226.22 -2.00 3.11 -2.00 315.85 0.00e+00 2.362678e-04 4.020612e-05 2.067248e-05 -6.000000e+00 1.833058e-04 280.20 -2.00 20.00 -2.00 315.23 0.00e+00 1.394 0.000 302.00 328.00 3 3.7564e+00 1.0198e-03 1.3231e-02 -6.0000e+00 1.0347e-02 1.1282e-02 1.1363e-03 7.8257e-03 -6.0000e+00 1.1225e-02 2.0682e-03 6.5565e-04 3.8810e-03 -6.0000e+00 6.6820e-03 -4.0016e-03 3.0390e-04 1.1179e-03 -6.0000e+00 2.8755e-03 3.5969e-03 -1.3845e-04 2.2406e-05 1.4198e-05 -6.0000e+00 1.9897e-04 -8.0213e-03 3.8539e-05 10 0 0 10 0 0 98.50 23.65 0.19 -0.00802 -0.00906 141 35 1 5 0 338.230 26.32 20.00 23.65 24.50 12.0 792.26 -1385 -1420 -1092 -2183 -599 -1010 134 -182 1098 -1074 -483 -578 -95 -266 -387 -583 49 -139 547 609 328 605 877 504 869 670 459 642 1124 1554 1229 1957 567 -380 -990 -935 -1385 -560 -749 -941 -1277 -872 -1001 -659 -752 -643 -604 -545 -589 249 352 753 993 891 827 763 530 491 713 564 1032 1042 1272 437 85 -27 -83 323 948 366 446 -81 217 -72 200 -64 -16 203 -142 -548 -853 -1542 -1660 -1149 -1099 -722 -302 105 -84 71 301 362 351 955 419 712 697 296 -338 -107 -649 -474 -121 -361 -779 -687 -644 -438 6 193 160 24 -143 -102 232 269 324 260 159 -329 -53 -175 65 542 831 621 1417 912 919 449 322 3 278 14 20 -268 64 -265 -371 -474 -415 -495 -317 -343 -260 -521 -125 -205 29 -44 284 -290 -126 -154 -28 -87 -141 -225 19 -56 223 255 138 252 373 225 402 317 212 273 441 598 495 827 257 -171 -416 -395 -654 -308 -450 -642 -930 -652 -764 -500 -567 -478 -434 -376 -393 166 247 555 764 712 672 630 442 405 576 459 875 949 1237 441 82 -23 -68 258 822 359 468 -81 230 -73 186 -53 -12 161 -111 -483 -834 -1643 -1856 -1243 -1279 -892 -389 137 -108 87 334 392 350 939 444 827 826 382 -447 -136 -764 -561 -141 -418 -977 -899 -880 -620 9 278 237 35 -209 -137 283 342 389 331 220 -481 -78 -252 91 712 1034 793 1730 1156 1144 589 436 4 388 21 32 -434 99 -417 -578 -773 -655 -758 SS 20210318T160949.0Z 7747.673484 58 1 48.10 2 42.92 113.31 89.24 71.67 0.00 1 0.00 1 0 17 6.988e-03 5.684e-03 1.454e-03 8.325e-04 1.667952e-01 4.241805e-04 1.857536e-03 -6.000000e+00 4.004300e-03 226.22 -2.00 3.11 -2.00 315.68 0.00e+00 2.668697e-04 4.155210e-05 2.353918e-05 -6.000000e+00 1.758290e-04 280.20 -2.00 20.00 -2.00 315.07 0.00e+00 1.364 0.000 302.00 328.00 3 4.0298e+00 1.0918e-03 1.2947e-02 -6.0000e+00 9.9246e-03 1.2262e-02 1.2155e-03 7.6573e-03 -6.0000e+00 1.0767e-02 2.6093e-03 6.9967e-04 3.7978e-03 -6.0000e+00 6.4095e-03 -4.0166e-03 3.2191e-04 1.0997e-03 -6.0000e+00 2.7583e-03 2.8190e-03 -1.4914e-04 2.3780e-05 1.4127e-05 -6.0000e+00 1.9085e-04 -8.0661e-03 3.7880e-05 11 1 0 11 8 0 98.60 23.65 0.16 -0.00807 -0.00919 78 19 1 5 0 616.450 26.32 20.00 23.65 24.64 12.0 791.34 -1526 -502 -1630 -1498 -1127 -141 -604 934 433 181 -430 21 -767 -446 -52 -201 -160 101 445 734 454 718 979 426 788 379 514 206 1420 1168 1426 1477 1005 -729 -684 -1346 -1215 -909 -749 -1182 -1147 -973 -917 -614 -580 -754 -423 -730 -509 263 361 718 801 870 699 672 736 591 468 844 831 1111 1381 557 -157 15 -298 373 718 454 296 53 91 109 2 208 57 313 -178 -578 -798 -1451 -1623 -1063 -1094 -726 -343 -20 -65 132 335 387 574 899 656 692 798 203 -145 -274 -564 -533 116 -428 -711 -718 -536 -558 99 101 129 -76 -90 -22 57 196 365 325 172 -415 -83 -153 71 450 787 653 811 1032 740 665 195 69 161 68 -30 -90 27 -232 -404 -407 -462 -488 -401 -138 -448 -373 -248 -30 -137 232 118 50 -117 6 -236 -153 -20 -80 -65 42 189 319 199 310 431 197 378 186 245 91 575 467 592 647 468 -340 -295 -589 -590 -517 -477 -856 -837 -731 -701 -467 -438 -594 -321 -533 -359 185 267 558 651 695 568 555 611 485 399 722 705 1009 1338 561 -151 13 -254 312 620 441 309 54 96 110 2 181 45 238 -146 -533 -773 -1531 -1798 -1172 -1298 -915 -430 -26 -82 163 379 416 564 875 686 795 960 267 -185 -351 -674 -623 133 -504 -906 -955 -709 -766 142 151 190 -114 -127 -30 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