File name: Pandora142s1_MexicoCity-UNAM_20210330_L2Fit_fout2c19d20210215p1-8.txt File generation date: 20251127T113257.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c19p1-8 Local principal investigator: -- Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 142 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora142_OF_v2d20200821.txt Instrument calibration file used: Pandora142s1_CF_v19d20210215.txt Level 1 file used: Pandora142s1_MexicoCity-UNAM_20210330_L1_smca1c19d20210215p1-8.txt Full location name: Centro de Ciencias de la Atmosfera, UNAM Short location name: MexicoCity-UNAM Country of location: Mexico Location latitude [deg]: 19.3262 Location longitude [deg]: -99.1761 Location altitude [m]: 2280 Local noon date: 20210330 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 237 378 Nominal wavelengths inside fitting window [nm]: 305.1046 305.2458 305.3870 305.5282 305.6694 305.8105 305.9517 306.0928 306.2339 306.3750 306.5161 306.6572 306.7983 306.9393 307.0804 307.2214 307.3625 307.5035 307.6445 307.7855 307.9265 308.0674 308.2084 308.3493 308.4903 308.6312 308.7721 308.9130 309.0539 309.1948 309.3356 309.4765 309.6173 309.7582 309.8990 310.0398 310.1806 310.3214 310.4622 310.6029 310.7437 310.8844 311.0252 311.1659 311.3066 311.4473 311.5880 311.7286 311.8693 312.0099 312.1506 312.2912 312.4318 312.5724 312.7130 312.8536 312.9941 313.1347 313.2752 313.4158 313.5563 313.6968 313.8373 313.9778 314.1183 314.2587 314.3992 314.5396 314.6800 314.8204 314.9608 315.1012 315.2416 315.3820 315.5223 315.6627 315.8030 315.9433 316.0836 316.2239 316.3642 316.5045 316.6447 316.7850 316.9252 317.0655 317.2057 317.3459 317.4861 317.6262 317.7664 317.9066 318.0467 318.1868 318.3269 318.4671 318.6071 318.7472 318.8873 319.0274 319.1674 319.3074 319.4475 319.5875 319.7275 319.8675 320.0074 320.1474 320.2873 320.4273 320.5672 320.7071 320.8470 320.9869 321.1268 321.2667 321.4065 321.5464 321.6862 321.8260 321.9658 322.1056 322.2454 322.3852 322.5249 322.6647 322.8044 322.9441 323.0838 323.2235 323.3632 323.5029 323.6426 323.7822 323.9218 324.0615 324.2011 324.3407 324.4803 324.6199 324.7594 324.8990 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210330T130927.5Z 7759.548235 228 1 49.09 2 82.00 88.56 78.52 254.40 0.00 1 0.00 1 0 17 5.595e-01 2.340e-02 4.488e-01 1.913e-02 7.633700e-01 1.124672e-02 7.806951e-03 -6.000000e+00 3.277304e-01 227.06 -2.00 3.11 -2.00 321.93 0.00e+00 1.692313e-02 6.144061e-03 2.019603e-03 -6.000000e+00 1.584602e-02 280.47 -2.00 20.00 -2.00 321.47 0.00e+00 6.742 0.001 302.00 328.00 3 3.6758e+00 4.1921e-02 6.9064e-02 -6.0000e+00 8.1912e-01 3.7890e-01 5.8286e-02 5.7972e-02 -6.0000e+00 8.9442e-01 -6.4072e-01 5.7103e-02 2.1085e-02 -6.0000e+00 5.2486e-01 2.6090e-01 2.6514e-02 2.0141e-02 -6.0000e+00 2.2723e-01 3.3642e-05 -2.0473e-03 5.6291e-04 2.1348e-04 -6.0000e+00 1.6142e-02 -7.5756e-03 -5.6425e-06 12 8 8 10 0 0 27.77 23.76 0.63 -0.00758 -0.02296 20 5 1 5 0 2453.680 26.41 20.00 23.76 19.43 12.0 780.17 900000 900000 -178480 900000 -249134 -89064 88647 900000 -215821 900000 -173983 -141038 -47631 900000 -14179 -31360 -70892 248455 24482 -82820 -74203 31442 20053 2172 71346 -78539 900000 10080 15434 -123066 900000 -6015 900000 -35766 900000 7958 45488 -26894 94973 57520 19174 1120 143416 -7618 40425 10287 57096 71486 71797 66914 39407 43240 63350 34385 15095 42594 -10701 43609 8399 5114 -6050 17777 13634 24987 21118 20905 -3576 14599 -2968 2339 -9499 8918 3532 7449 5294 16510 -6790 19732 6402 4851 1339 5554 770 -1259 43 1937 44 3177 -3192 -5044 -542 130 -307 -5061 1449 -2312 -278 -1724 372 -2140 -2884 -2491 4168 -985 -2458 -1367 1767 -6047 -379 -2146 -1776 339 -850 505 -126 -1135 196 1090 22 209 1669 2423 1037 1768 2896 3186 -2549 1690 -647 500 462 902 -97 1154 -219 380 323 -678 -933 -406 -486 -502 900000 900000 -3507 900000 -8245 -1658 1650 900000 -5199 900000 -3239 -2626 -887 900000 -264 -584 -1708 4625 456 -2721 -2194 585 373 40 1328 -2322 900000 188 287 -7008 900000 -175 900000 -1567 900000 222 953 -1266 1768 1673 840 63 2670 -509 1834 620 2391 2745 2924 3114 2546 2983 3885 3012 1653 3591 -1535 3534 938 594 -841 2219 2060 3803 3469 3388 -748 2686 -694 590 -2898 2296 920 1819 1183 2983 -1509 3630 1598 1405 471 2125 334 -589 21 990 24 1702 -1799 -2749 -263 60 -141 -2643 829 -1628 -226 -1628 366 -2100 -2613 -1994 2910 -751 -2044 -1185 1590 -6435 -430 -2825 -2579 504 -1270 716 -172 -1536 271 1582 34 327 2486 3420 1437 2343 3669 3889 -3301 2330 -1057 914 925 1914 -222 2778 -570 1015 877 -1877 -2527 -1029 -1147 -1117 SS 20210330T132425.0Z 7759.558623 233 1 48.02 2 78.47 89.79 81.84 255.70 0.00 1 0.00 1 0 25 2.013e-01 4.704e-03 1.546e-01 2.671e-03 5.829738e-01 1.437565e-03 5.979499e-03 -6.000000e+00 1.157260e-01 227.06 -2.00 3.11 -2.00 321.01 0.00e+00 1.033368e-02 6.466860e-04 2.723614e-03 -6.000000e+00 5.070754e-03 280.47 -2.00 20.00 -2.00 320.48 0.00e+00 4.848 0.000 302.00 328.00 3 2.3631e+00 4.6725e-03 5.1009e-02 -6.0000e+00 2.8736e-01 -7.5791e-02 6.3219e-03 4.1250e-02 -6.0000e+00 3.1155e-01 7.9736e-03 6.5686e-03 1.6629e-02 -6.0000e+00 1.8536e-01 -9.8137e-03 3.1952e-03 1.5500e-02 -6.0000e+00 7.9654e-02 6.3707e-04 -9.1279e-04 7.7310e-05 1.0258e-04 -6.0000e+00 5.4987e-03 -8.6325e-03 4.1887e-05 10 0 0 10 0 0 12.17 23.75 0.26 -0.00863 -0.01549 138 34 1 5 0 343.480 26.41 20.00 23.75 21.03 12.1 788.00 -97479 -62153 6764 -92527 -60987 -66435 -60397 -91055 -41411 -27355 -62609 -61934 14534 14148 -5714 -14905 -4988 -10178 -10195 -11061 5977 -6839 -6379 -14924 -2535 -13179 -17480 -1406 -13826 -11501 -4157 6216 572 -2318 -7686 -473 -7979 -1010 -788 -2169 -2230 -1067 177 1824 677 -945 -765 3042 -618 -360 1537 938 219 147 626 793 2097 -966 1473 -1335 441 294 1677 589 865 456 1696 -110 300 465 994 -261 65 1382 -171 605 -938 -291 -661 -1271 -981 -1314 -2033 -927 -843 -401 407 1131 902 985 859 1267 340 586 485 545 440 464 -135 440 -281 -311 -234 -223 -1071 -687 -771 -783 -151 123 -262 217 57 151 196 192 66 -418 -318 -717 -372 -399 -35 502 654 405 934 564 376 402 262 -99 338 -96 89 -272 34 -42 -227 -117 -63 -73 -669 -353 21 -745 -332 -378 -343 -776 -235 -143 -489 -572 83 107 -68 -233 -80 -177 -193 -223 113 -135 -130 -350 -55 -332 -467 -35 -366 -340 -139 224 25 -109 -364 -21 -435 -61 -58 -173 -197 -100 17 183 71 -105 -88 351 -78 -49 228 155 40 29 126 164 435 -204 298 -282 98 74 476 187 278 142 519 -36 110 193 443 -121 29 571 -65 207 -312 -101 -266 -610 -542 -818 -1366 -653 -636 -320 337 948 749 775 627 862 227 415 391 510 476 524 -161 503 -320 -318 -228 -229 -1189 -799 -953 -967 -205 184 -427 359 92 232 283 270 95 -645 -521 -1206 -609 -631 -53 729 983 585 1329 814 613 726 510 -202 721 -218 215 -639 81 -102 -539 -284 -145 -159 SS 20210330T133025.6Z 7759.562796 236 1 47.23 2 77.05 90.28 83.18 256.21 0.00 1 0.00 1 0 25 6.492e-02 4.300e-03 7.134e-02 1.697e-03 5.256157e-01 8.946841e-04 5.427596e-03 -6.000000e+00 3.732441e-02 227.06 -2.00 3.11 -2.00 320.65 0.00e+00 8.692494e-03 3.563047e-04 2.029588e-03 -6.000000e+00 1.635308e-03 280.47 -2.00 20.00 -2.00 320.09 0.00e+00 4.353 0.000 302.00 328.00 3 2.0749e+00 2.7463e-03 4.4393e-02 -6.0000e+00 9.2680e-02 -7.2240e-02 3.5449e-03 3.4093e-02 -6.0000e+00 1.0048e-01 1.3379e-02 3.4833e-03 1.4303e-02 -6.0000e+00 5.9783e-02 -1.2132e-02 1.7459e-03 1.2564e-02 -6.0000e+00 2.5691e-02 1.2948e-03 -6.4721e-04 4.9258e-05 8.4907e-05 -6.0000e+00 1.7733e-03 -8.7711e-03 5.4199e-05 11 1 0 11 8 0 -0.71 23.75 0.16 -0.00877 -0.01363 210 52 1 5 0 224.880 26.41 20.00 23.75 21.71 12.1 790.57 10711 -28862 -7351 -20276 -7083 -33797 -21165 -8721 -13978 -7033 -37316 -17726 -9660 -10347 -10143 -6596 -2755 -4852 1162 -6775 -714 -4984 57 -475 -57 -1410 -1627 -6902 -1834 -199 1744 -554 3270 1780 363 -3743 -2169 -3169 -1602 -752 -2633 -2848 -2058 -382 52 -879 -311 -158 619 373 654 786 172 -24 -252 1011 860 671 262 742 329 583 1328 445 424 892 99 186 483 423 270 148 682 363 -19 -119 -431 -568 -707 -1074 -784 -1585 -1323 -1286 -893 -361 253 779 645 1155 1038 1090 924 846 889 541 671 324 -20 -20 -238 -110 -127 -696 -955 -588 -703 -584 6 -49 -21 17 94 126 125 216 -40 -274 -442 -730 -360 -376 -153 435 562 479 640 720 444 350 295 232 87 -95 -51 -160 103 -72 -158 -111 -214 -23 51 -217 -52 -158 -45 -274 -161 -65 -120 -59 -404 -184 -119 -167 -204 -152 -68 -136 33 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